Structure cristalline et investigation par spectrométrie de vibration IR des cyclotétraphosphates pentahydratés M IIK2P4O12 · 5H2O ( M II = NI, Co)
Identifieur interne : 000593 ( Istex/Corpus ); précédent : 000592; suivant : 000594Structure cristalline et investigation par spectrométrie de vibration IR des cyclotétraphosphates pentahydratés M IIK2P4O12 · 5H2O ( M II = NI, Co)
Auteurs : A. Jouini ; M. Soua ; M. DabbabiSource :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1987.
Abstract
Abstract: To determine the reorganization occurring during the dehydration of nickel dipotassium cyclotetraphosphate heptahydrate, NiK2P4O12 · 7H2O (A. Jouini, M. Dabbabi, and A. Durif, J. Solid State Chem. 60, 6 (1985)), leading to the pentahydrate, we studied the crystal structure of the corresponding isotypic cobalt salt CoK2P4O12 · 5H2O because of the lack of NiK2P4O12 · 5H12O single crystals. The symmetry is monoclinic, P21 c, a = 12.995(2), b = 16.294(2), c = 7.432(2) Å, β = 92.17(1)°, Z = 4, and R = 0.033 for 3122 independent reflections. H atoms have been located and refined. A detailed IR study of both NiK2P4O12 · 5H2O and CoK2P4O12 · 5H2O is reported and a tentative explanation for the dehydration and reorganization is proposed.
Url:
DOI: 10.1016/0022-4596(87)90019-3
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Jouini</name><affiliation><mods:affiliation>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</mods:affiliation></affiliation></author><author><name sortKey="Soua, M" sort="Soua, M" uniqKey="Soua M" first="M." last="Soua">M. Soua</name><affiliation><mods:affiliation>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</mods:affiliation></affiliation></author><author><name sortKey="Dabbabi, M" sort="Dabbabi, M" uniqKey="Dabbabi M" first="M." last="Dabbabi">M. Dabbabi</name><affiliation><mods:affiliation>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Solid State Chemistry</title><title level="j" type="abbrev">YJSSC</title><idno type="ISSN">0022-4596</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1987">1987</date><biblScope unit="volume">69</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="135">135</biblScope><biblScope unit="page" to="144">144</biblScope></imprint><idno type="ISSN">0022-4596</idno></series><idno type="istex">517C77945118F240E02A22690748F57B7D414633</idno><idno type="DOI">10.1016/0022-4596(87)90019-3</idno><idno type="PII">0022-4596(87)90019-3</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0022-4596</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="fr">fr</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: To determine the reorganization occurring during the dehydration of nickel dipotassium cyclotetraphosphate heptahydrate, NiK2P4O12 · 7H2O (A. Jouini, M. Dabbabi, and A. Durif, J. Solid State Chem. 60, 6 (1985)), leading to the pentahydrate, we studied the crystal structure of the corresponding isotypic cobalt salt CoK2P4O12 · 5H2O because of the lack of NiK2P4O12 · 5H12O single crystals. The symmetry is monoclinic, P21 c, a = 12.995(2), b = 16.294(2), c = 7.432(2) Å, β = 92.17(1)°, Z = 4, and R = 0.033 for 3122 independent reflections. H atoms have been located and refined. A detailed IR study of both NiK2P4O12 · 5H2O and CoK2P4O12 · 5H2O is reported and a tentative explanation for the dehydration and reorganization is proposed.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>A. Jouini</name><affiliations><json:string>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</json:string></affiliations></json:item><json:item><name>M. 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The symmetry is monoclinic, P21 c, a = 12.995(2), b = 16.294(2), c = 7.432(2) Å, β = 92.17(1)°, Z = 4, and R = 0.033 for 3122 independent reflections. H atoms have been located and refined. 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Jouini, M. Dabbabi, and A. Durif, J. Solid State Chem. 60, 6 (1985)), leading to the pentahydrate, we studied the crystal structure of the corresponding isotypic cobalt salt CoK2P4O12 · 5H2O because of the lack of NiK2P4O12 · 5H12O single crystals. The symmetry is monoclinic, P21 c, a = 12.995(2), b = 16.294(2), c = 7.432(2) Å, β = 92.17(1)°, Z = 4, and R = 0.033 for 3122 independent reflections. H atoms have been located and refined. A detailed IR study of both NiK2P4O12 · 5H2O and CoK2P4O12 · 5H2O is reported and a tentative explanation for the dehydration and reorganization is proposed.</p></abstract></profileDesc><revisionDesc><change when="1986-10-20">Modified</change><change when="1987">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/517C77945118F240E02A22690748F57B7D414633/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla" xml:lang="fr"><item-info><jid>YJSSC</jid><aid>87900193</aid><ce:pii>0022-4596(87)90019-3</ce:pii><ce:doi>10.1016/0022-4596(87)90019-3</ce:doi><ce:copyright type="unknown" year="1987"></ce:copyright></item-info><head><ce:title>Structure cristalline et investigation par spectrométrie de vibration IR des cyclotétraphosphates pentahydratés <ce:italic>M</ce:italic><ce:sup>II</ce:sup>K<ce:inf>2</ce:inf>P<ce:inf>4</ce:inf>O<ce:inf>12</ce:inf> · 5H<ce:inf>2</ce:inf>O (<ce:italic>M</ce:italic><ce:sup>II</ce:sup> = NI, Co)</ce:title><ce:author-group><ce:author><ce:given-name>A.</ce:given-name><ce:surname>Jouini</ce:surname></ce:author><ce:author><ce:given-name>M.</ce:given-name><ce:surname>Soua</ce:surname></ce:author><ce:author><ce:given-name>M.</ce:given-name><ce:surname>Dabbabi</ce:surname></ce:author><ce:affiliation><ce:textfn>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</ce:textfn></ce:affiliation></ce:author-group><ce:date-received day="6" month="7" year="1986"></ce:date-received><ce:date-revised day="20" month="10" year="1986"></ce:date-revised><ce:abstract xml:lang="en"><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>To determine the reorganization occurring during the dehydration of nickel dipotassium cyclotetraphosphate heptahydrate, NiK<ce:inf>2</ce:inf>P<ce:inf>4</ce:inf>O<ce:inf>12</ce:inf> · 7H<ce:inf>2</ce:inf>O (A. Jouini, M. Dabbabi, and A. Durif, <ce:italic>J. Solid State Chem.</ce:italic> <ce:bold>60,</ce:bold> 6 (1985)), leading to the pentahydrate, we studied the crystal structure of the corresponding isotypic cobalt salt CoK<ce:inf>2</ce:inf>P<ce:inf>4</ce:inf>O<ce:inf>12</ce:inf> · 5H<ce:inf>2</ce:inf>O because of the lack of NiK<ce:inf>2</ce:inf>P<ce:inf>4</ce:inf>O<ce:inf>12</ce:inf> · 5H<ce:inf>12</ce:inf>O single crystals. The symmetry is monoclinic, <math altimg="si1.gif"><fr shape="sol"><nu>P2<inf>1</inf></nu><de>c</de></fr>, a = 12.995(2), b = 16.294(2), c = 7.432(2)</math> Å, β = 92.17(1)°, <ce:italic>Z</ce:italic> = 4, and <ce:italic>R</ce:italic> = 0.033 for 3122 independent reflections. H atoms have been located and refined. A detailed IR study of both NiK<ce:inf>2</ce:inf>P<ce:inf>4</ce:inf>O<ce:inf>12</ce:inf> · 5H<ce:inf>2</ce:inf>O and CoK<ce:inf>2</ce:inf>P<ce:inf>4</ce:inf>O<ce:inf>12</ce:inf> · 5H<ce:inf>2</ce:inf>O is reported and a tentative explanation for the dehydration and reorganization is proposed.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="fr"><title>Structure cristalline et investigation par spectrométrie de vibration IR des cyclotétraphosphates pentahydratés M IIK2P4O12 · 5H2O ( M II = NI, Co)</title></titleInfo><titleInfo type="alternative" lang="fr" contentType="CDATA"><title>Structure cristalline et investigation par spectrométrie de vibration IR des cyclotétraphosphates pentahydratés</title></titleInfo><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Jouini</namePart><affiliation>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Soua</namePart><affiliation>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Dabbabi</namePart><affiliation>Laboratoire de Chimie Minérale, Département de Chimie, Faculté des Sciences et Techniques de Monastir, 5000 Monastir, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1987</dateIssued><dateModified encoding="w3cdtf">1986-10-20</dateModified><copyrightDate encoding="w3cdtf">1987</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">fre</languageTerm><languageTerm type="code" authority="rfc3066">fr</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">Abstract: To determine the reorganization occurring during the dehydration of nickel dipotassium cyclotetraphosphate heptahydrate, NiK2P4O12 · 7H2O (A. Jouini, M. Dabbabi, and A. Durif, J. Solid State Chem. 60, 6 (1985)), leading to the pentahydrate, we studied the crystal structure of the corresponding isotypic cobalt salt CoK2P4O12 · 5H2O because of the lack of NiK2P4O12 · 5H12O single crystals. The symmetry is monoclinic, P21 c, a = 12.995(2), b = 16.294(2), c = 7.432(2) Å, β = 92.17(1)°, Z = 4, and R = 0.033 for 3122 independent reflections. H atoms have been located and refined. 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