CobaltMaghrebV1, Istex, Corpus, bibRecord, 000572

Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Identifieur interne : 000572 ( Istex/Corpus ); précédent : 000571; suivant : 000573

Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Auteurs : Ouassini Benali-Baitich ; Jean-Claude Daran ; Yves Jeannin

Source :

Journal of Organometallic Chemistry [ 0022-328X ] ; 1988.

RBID : ISTEX:64DF056EEEC6EA8C67575930158C30ABBFAF243D

Abstract

Reaction of C2Ph2 with [CoRu3(CO)13](PPN) affords the violet butterfly complex [CoRu3(μ-CO)2(CO)9(μ4η2-C2Ph2)](PPN), which crystallizes in triclinic space group P1, a 9.9840(8) Å, b 15.462(2) Å, c 19.572(3) Å, α 75.08(1)°, β 75.15(1)°, γ 87.85(3)°, V 2821(1) Å3, Z = 2. This study completes the series of structures of ruthenium-cobalt closo-M4C2 clusters.

Url:

https://api.istex.fr/document/64DF056EEEC6EA8C67575930158C30ABBFAF243D/fulltext/pdf

DOI: 10.1016/0022-328X(88)80193-1

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ISTEX:64DF056EEEC6EA8C67575930158C30ABBFAF243D

Le document en format XML

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<front><div type="abstract" xml:lang="en">Reaction of C2Ph2 with [CoRu3(CO)13](PPN) affords the violet butterfly complex [CoRu3(μ-CO)2(CO)9(μ4η2-C2Ph2)](PPN), which crystallizes in triclinic space group P1, a 9.9840(8) Å, b 15.462(2) Å, c 19.572(3) Å, α 75.08(1)°, β 75.15(1)°, γ 87.85(3)°, V 2821(1) Å3, Z = 2. This study completes the series of structures of ruthenium-cobalt closo-M4C2 clusters.</div>
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Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

Synthesis and crystal structure of the [CoRu3(μ-CO)2(CO)9(μ4,η2-C2Ph2)][PPN] cluster

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