Serveur d'exploration sur le cobalt au Maghreb

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Gold and platinum group elements in cobaltarsenide ores: Hydrothermal concentration from a serpentinite source-rock (Bou Azzer, Morocco)

Identifieur interne : 000294 ( Istex/Corpus ); précédent : 000293; suivant : 000295

Gold and platinum group elements in cobaltarsenide ores: Hydrothermal concentration from a serpentinite source-rock (Bou Azzer, Morocco)

Auteurs : M. Leblanc ; W. Fischer

Source :

RBID : ISTEX:59864FA774B591DBCD9FC3C017A4BB438FCA3FDE

Abstract

Summary: The cobalt-arsenide ores of Bou Azzer are located along the borders of serpentinite massifs (Upper Proterozoic ophiolite complex) in carbonate-quartz lenses resulting from hydrothermal carbonate alteration of serpentinite. The cobalt ores contain an average gold content of 5–20 ppm; gold is mainly located in skutterudite (120 ppm av.), whereas the Fe-arsenide (loellingite) contains < 1 ppm Au. Similarly the highest PGE contents are found in skutterudite (up to 2 ppm total PGE). All the arsenide ores of Bou Azzer exhibit the same chondrite normalized PGE pattern displaying positive Rh and negative Pt anomalies, and a slight positive slope (Pd/Ir = 1 to 2). This uncommon PGE pattern closely resembles to that of sulphides of komatiites. In serpentinite, the PGE patterns are typical of slightly depleted mantle rocks, and the associated podiform chromitites are within the range of ophiolitic chromitites, except for Pd and Au enrichment. Horizons of sulphide-bearing serpentinites show relatively high contents of noble metals and display PGE patterns which closely resemble those of the Co-arsenide ores, although an order of magnitude lower. These sulphides probably correspond to the remobilization during serpentinization of primary magmatic sulphides. The sulphiderich horizons are a possible source-rock for the noble metals of the Bou Azzer cobaltarsenide ores.

Url:
DOI: 10.1007/BF01162691

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ISTEX:59864FA774B591DBCD9FC3C017A4BB438FCA3FDE

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<div type="abstract" xml:lang="en">Summary: The cobalt-arsenide ores of Bou Azzer are located along the borders of serpentinite massifs (Upper Proterozoic ophiolite complex) in carbonate-quartz lenses resulting from hydrothermal carbonate alteration of serpentinite. The cobalt ores contain an average gold content of 5–20 ppm; gold is mainly located in skutterudite (120 ppm av.), whereas the Fe-arsenide (loellingite) contains < 1 ppm Au. Similarly the highest PGE contents are found in skutterudite (up to 2 ppm total PGE). All the arsenide ores of Bou Azzer exhibit the same chondrite normalized PGE pattern displaying positive Rh and negative Pt anomalies, and a slight positive slope (Pd/Ir = 1 to 2). This uncommon PGE pattern closely resembles to that of sulphides of komatiites. In serpentinite, the PGE patterns are typical of slightly depleted mantle rocks, and the associated podiform chromitites are within the range of ophiolitic chromitites, except for Pd and Au enrichment. Horizons of sulphide-bearing serpentinites show relatively high contents of noble metals and display PGE patterns which closely resemble those of the Co-arsenide ores, although an order of magnitude lower. These sulphides probably correspond to the remobilization during serpentinization of primary magmatic sulphides. The sulphiderich horizons are a possible source-rock for the noble metals of the Bou Azzer cobaltarsenide ores.</div>
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<p>Summary: The cobalt-arsenide ores of Bou Azzer are located along the borders of serpentinite massifs (Upper Proterozoic ophiolite complex) in carbonate-quartz lenses resulting from hydrothermal carbonate alteration of serpentinite. The cobalt ores contain an average gold content of 5–20 ppm; gold is mainly located in skutterudite (120 ppm av.), whereas the Fe-arsenide (loellingite) contains < 1 ppm Au. Similarly the highest PGE contents are found in skutterudite (up to 2 ppm total PGE). All the arsenide ores of Bou Azzer exhibit the same chondrite normalized PGE pattern displaying positive Rh and negative Pt anomalies, and a slight positive slope (Pd/Ir = 1 to 2). This uncommon PGE pattern closely resembles to that of sulphides of komatiites. In serpentinite, the PGE patterns are typical of slightly depleted mantle rocks, and the associated podiform chromitites are within the range of ophiolitic chromitites, except for Pd and Au enrichment. Horizons of sulphide-bearing serpentinites show relatively high contents of noble metals and display PGE patterns which closely resemble those of the Co-arsenide ores, although an order of magnitude lower. These sulphides probably correspond to the remobilization during serpentinization of primary magmatic sulphides. The sulphiderich horizons are a possible source-rock for the noble metals of the Bou Azzer cobaltarsenide ores.</p>
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<p>Zusammenfassung: Die Kobalt-Arsenid Erze von Bou Azzer kommen entlang den Grenzen eines Serpentinit-Massifs (Oberproterozoischer Ophiolit-Komplex) in Karbonat-Quarz-Linsen vor, die auf hydrothermale Umwandlung des Serpentinits zurückgehen. Die Kobalt-Erze enthalten 5–20 ppm Gold; dieses kommt hauptsächlich in Skutterudit (120 ppm) vor, während die Fe-Arsenide (Loellingit) weniger als 1 ppm Gold enthalten. Die höchsten PGE Gehalte kommen ebenso in Skutterudit vor (bis zu 2 ppm PGE). Alle Arsenid-Erze zeigen das gleiche Verteilungsbild mit positiven Rh und negativen Pt Anomalien, und eine leicht positive Neigung (Pd/Ir = 1 bis 2). Diese ungewöhnlichen PGE Verteilungsbilder erinnern an die von Sulfiden aus Komatiiten. Die PGE Verteilung in Serpentiniten ist typisch für leicht verarmte Mantelgesteine, und die assoziierten podiformen Chromitite liegen innerhalb des Bereiches für ophiolitische Chromitite, mit Ausnahme der Anreicherung in Pd und Au. Lagen von Sulfid-führenden Serpentiniten zeigen relativ hohe Gehalte an Edelmetallen, und PGE-Verteilungsmuster die denen von Co-Arseniderzen sehr ähnlich sind, obwohl sie um eine Größenordnung niedriger liegen. Diese Sulfide dürften Produkte der Remobilisierung primärer magmatischer Sulfide während der Serpentinisierung sein. Die Sulfid-reichen Lagen sind als ein mögliches Ursprungsgestein für die Edelmetalle der Kobalt-Arsenid-Erze von Bou Azzer zu sehen.</p>
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<Para>The cobalt-arsenide ores of Bou Azzer are located along the borders of serpentinite massifs (Upper Proterozoic ophiolite complex) in carbonate-quartz lenses resulting from hydrothermal carbonate alteration of serpentinite. The cobalt ores contain an average gold content of 5–20 ppm; gold is mainly located in skutterudite (120 ppm av.), whereas the Fe-arsenide (loellingite) contains < 1 ppm Au. Similarly the highest PGE contents are found in skutterudite (up to 2 ppm total PGE). All the arsenide ores of Bou Azzer exhibit the same chondrite normalized PGE pattern displaying positive Rh and negative Pt anomalies, and a slight positive slope (Pd/Ir = 1 to 2). This uncommon PGE pattern closely resembles to that of sulphides of komatiites.</Para>
<Para>In serpentinite, the PGE patterns are typical of slightly depleted mantle rocks, and the associated podiform chromitites are within the range of ophiolitic chromitites, except for Pd and Au enrichment.</Para>
<Para>Horizons of sulphide-bearing serpentinites show relatively high contents of noble metals and display PGE patterns which closely resemble those of the Co-arsenide ores, although an order of magnitude lower. These sulphides probably correspond to the remobilization during serpentinization of primary magmatic sulphides. The sulphiderich horizons are a possible source-rock for the noble metals of the Bou Azzer cobaltarsenide ores.</Para>
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<Para>Die Kobalt-Arsenid Erze von Bou Azzer kommen entlang den Grenzen eines Serpentinit-Massifs (Oberproterozoischer Ophiolit-Komplex) in Karbonat-Quarz-Linsen vor, die auf hydrothermale Umwandlung des Serpentinits zurückgehen.</Para>
<Para>Die Kobalt-Erze enthalten 5–20 ppm Gold; dieses kommt hauptsächlich in Skutterudit (120 ppm) vor, während die Fe-Arsenide (Loellingit) weniger als 1 ppm Gold enthalten. Die höchsten PGE Gehalte kommen ebenso in Skutterudit vor (bis zu 2 ppm PGE). Alle Arsenid-Erze zeigen das gleiche Verteilungsbild mit positiven Rh und negativen Pt Anomalien, und eine leicht positive Neigung (Pd/Ir = 1 bis 2). Diese ungewöhnlichen PGE Verteilungsbilder erinnern an die von Sulfiden aus Komatiiten.</Para>
<Para>Die PGE Verteilung in Serpentiniten ist typisch für leicht verarmte Mantelgesteine, und die assoziierten podiformen Chromitite liegen innerhalb des Bereiches für ophiolitische Chromitite, mit Ausnahme der Anreicherung in Pd und Au.</Para>
<Para>Lagen von Sulfid-führenden Serpentiniten zeigen relativ hohe Gehalte an Edelmetallen, und PGE-Verteilungsmuster die denen von Co-Arseniderzen sehr ähnlich sind, obwohl sie um eine Größenordnung niedriger liegen. Diese Sulfide dürften Produkte der Remobilisierung primärer magmatischer Sulfide während der Serpentinisierung sein. Die Sulfid-reichen Lagen sind als ein mögliches Ursprungsgestein für die Edelmetalle der Kobalt-Arsenid-Erze von Bou Azzer zu sehen.</Para>
</Abstract>
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<SimplePara>With 8 Figures</SimplePara>
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<title>Gold and platinum group elements in cobaltarsenide ores: Hydrothermal concentration from a serpentinite source-rock (Bou Azzer, Morocco)</title>
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<titleInfo type="alternative" contentType="CDATA" lang="en">
<title>Gold and platinum group elements in cobaltarsenide ores: Hydrothermal concentration from a serpentinite source-rock (Bou Azzer, Morocco)</title>
</titleInfo>
<titleInfo lang="de">
<title>Gold und Platingruppen-Elemente in Kobalt-Arsenid Erzen: Hydrothermale Anreicherung aus einem Serpentinit (Bou Azzer, Marokko)</title>
</titleInfo>
<titleInfo type="alternative" contentType="CDATA" lang="de">
<title>Gold und Platingruppen-Elemente in Kobalt-Arsenid Erzen: Hydrothermale Anreicherung aus einem Serpentinit (Bou Azzer, Marokko)</title>
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<name type="personal">
<namePart type="given">M.</namePart>
<namePart type="family">Leblanc</namePart>
<affiliation>Centre Géologique et Géophysique, C.N.R.S, Université Montpellier II, F-34095, Montpellier Cedex2, France</affiliation>
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<roleTerm type="text">author</roleTerm>
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</name>
<name type="personal">
<namePart type="given">W.</namePart>
<namePart type="family">Fischer</namePart>
<affiliation>UA 69, Institut Dolomieu, F-38031, Grenoble, France</affiliation>
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<placeTerm type="text">Vienna</placeTerm>
</place>
<dateCreated encoding="w3cdtf">1989-08-03</dateCreated>
<dateIssued encoding="w3cdtf">1990-05-01</dateIssued>
<copyrightDate encoding="w3cdtf">1990</copyrightDate>
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<abstract lang="en">Summary: The cobalt-arsenide ores of Bou Azzer are located along the borders of serpentinite massifs (Upper Proterozoic ophiolite complex) in carbonate-quartz lenses resulting from hydrothermal carbonate alteration of serpentinite. The cobalt ores contain an average gold content of 5–20 ppm; gold is mainly located in skutterudite (120 ppm av.), whereas the Fe-arsenide (loellingite) contains < 1 ppm Au. Similarly the highest PGE contents are found in skutterudite (up to 2 ppm total PGE). All the arsenide ores of Bou Azzer exhibit the same chondrite normalized PGE pattern displaying positive Rh and negative Pt anomalies, and a slight positive slope (Pd/Ir = 1 to 2). This uncommon PGE pattern closely resembles to that of sulphides of komatiites. In serpentinite, the PGE patterns are typical of slightly depleted mantle rocks, and the associated podiform chromitites are within the range of ophiolitic chromitites, except for Pd and Au enrichment. Horizons of sulphide-bearing serpentinites show relatively high contents of noble metals and display PGE patterns which closely resemble those of the Co-arsenide ores, although an order of magnitude lower. These sulphides probably correspond to the remobilization during serpentinization of primary magmatic sulphides. The sulphiderich horizons are a possible source-rock for the noble metals of the Bou Azzer cobaltarsenide ores.</abstract>
<abstract lang="de">Zusammenfassung: Die Kobalt-Arsenid Erze von Bou Azzer kommen entlang den Grenzen eines Serpentinit-Massifs (Oberproterozoischer Ophiolit-Komplex) in Karbonat-Quarz-Linsen vor, die auf hydrothermale Umwandlung des Serpentinits zurückgehen. Die Kobalt-Erze enthalten 5–20 ppm Gold; dieses kommt hauptsächlich in Skutterudit (120 ppm) vor, während die Fe-Arsenide (Loellingit) weniger als 1 ppm Gold enthalten. Die höchsten PGE Gehalte kommen ebenso in Skutterudit vor (bis zu 2 ppm PGE). Alle Arsenid-Erze zeigen das gleiche Verteilungsbild mit positiven Rh und negativen Pt Anomalien, und eine leicht positive Neigung (Pd/Ir = 1 bis 2). Diese ungewöhnlichen PGE Verteilungsbilder erinnern an die von Sulfiden aus Komatiiten. Die PGE Verteilung in Serpentiniten ist typisch für leicht verarmte Mantelgesteine, und die assoziierten podiformen Chromitite liegen innerhalb des Bereiches für ophiolitische Chromitite, mit Ausnahme der Anreicherung in Pd und Au. Lagen von Sulfid-führenden Serpentiniten zeigen relativ hohe Gehalte an Edelmetallen, und PGE-Verteilungsmuster die denen von Co-Arseniderzen sehr ähnlich sind, obwohl sie um eine Größenordnung niedriger liegen. Diese Sulfide dürften Produkte der Remobilisierung primärer magmatischer Sulfide während der Serpentinisierung sein. Die Sulfid-reichen Lagen sind als ein mögliches Ursprungsgestein für die Edelmetalle der Kobalt-Arsenid-Erze von Bou Azzer zu sehen.</abstract>
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<titleInfo>
<title>Mineralogy and Petrology</title>
</titleInfo>
<titleInfo type="abbreviated">
<title>Mineralogy and Petrology</title>
</titleInfo>
<genre type="journal" displayLabel="Archive Journal"></genre>
<originInfo>
<dateIssued encoding="w3cdtf">1990-05-01</dateIssued>
<copyrightDate encoding="w3cdtf">1990</copyrightDate>
</originInfo>
<subject>
<genre>Geosciences</genre>
<topic>Geochemistry</topic>
<topic>Mineralogy</topic>
</subject>
<identifier type="ISSN">0930-0708</identifier>
<identifier type="eISSN">1438-1168</identifier>
<identifier type="JournalID">710</identifier>
<identifier type="IssueArticleCount">19</identifier>
<identifier type="VolumeIssueCount">4</identifier>
<part>
<date>1990</date>
<detail type="volume">
<number>42</number>
<caption>vol.</caption>
</detail>
<detail type="issue">
<number>1-4</number>
<caption>no.</caption>
</detail>
<extent unit="pages">
<start>197</start>
<end>209</end>
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<recordOrigin>Springer-Verlag, 1990</recordOrigin>
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<identifier type="DOI">10.1007/BF01162691</identifier>
<identifier type="ArticleID">BF01162691</identifier>
<identifier type="ArticleID">Art12</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Springer-Verlag 1990, 1990</accessCondition>
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<recordOrigin>Springer-Verlag 1990, 1990</recordOrigin>
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