Local structure and electrochemistry of LiNiyMnyCo1−2yO2 electrode materials for Li-ion batteries
Identifieur interne : 000005 ( Hal/Curation ); précédent : 000004; suivant : 000006Local structure and electrochemistry of LiNiyMnyCo1−2yO2 electrode materials for Li-ion batteries
Auteurs : K. Ben Kamel [Tunisie] ; N. Amdouni [Tunisie] ; A. Abdel-Ghany [France] ; K. Zaghib [Canada] ; A. Mauger [France] ; F. Gendron [France] ; C. M. Julien [France]Source :
- Ionics [ 0947-7047 ] ; 2008.
English descriptors
Abstract
A series of LiNixMnyCozO2 (x=y, z=1−2y) oxides have been synthesized by “chimie douce” and investigated as positive electrodes in rechargeable lithium batteries. Layered LiNiyMnyCo1−2yO2 materials with high homogeneity and crystallinity were synthesized using the wet-chemical method assisted by carboxylic acid as the polymeric agent. The long range and local structural properties are investigated with experiments including Xray diffraction, Fourier transform infrared spectroscopy, and electron paramagnetic resonance spectroscopy. The evolution of the structure is discussed as a function of the cobalt content that confers layer-like behavior on the framework. Electrochemical performance of LiNiyMnyCo1−2yO2 oxides is tested in cells using nonaqueous 1 M LiPF6 dissolved in ethylene carbonate–diethyl carbonate. Charge–discharge profiles are investigated as a function of the rate capability and the voltage window. A relation is found between the gravimetric capacity and the cation disorder of the positive electrode as indicated by structural analysis. Fast lithium extraction attributed to the larger interslab space has been observed in the cobalt-rich oxides
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DOI: 10.1007/s11581-007-0167-y
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Gendron</name><affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-101592" status="VALID"><idno type="RNSR">199712634A</idno><orgName>Institut des Nanosciences de Paris</orgName><orgName type="acronym">INSP</orgName><desc><address><addrLine>Université Pierre et Marie Curie Case 840 4 place Jussieu 75252 Paris Cedex 05</addrLine><country key="FR"></country></address><ref type="url">http://www.insp.upmc.fr</ref></desc><listRelation><relation active="#struct-93591" type="direct"></relation><relation name="UMR7588" active="#struct-441569" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-93591" type="direct"><org type="institution" xml:id="struct-93591" status="VALID"><orgName>Université Pierre et Marie Curie - Paris 6</orgName><orgName type="acronym">UPMC</orgName><desc><address><addrLine>4 place Jussieu - 75005 Paris</addrLine><country key="FR"></country></address><ref type="url">http://www.upmc.fr/</ref></desc></org></tutelle><tutelle name="UMR7588" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"> <idno type="ISNI">0000000122597504</idno> <idno type="IdRef">02636817X</idno> <orgName>Centre National de la Recherche Scientifique</orgName> <orgName type="acronym">CNRS</orgName> <date type="start">1939-10-19</date> <desc> <address> <country key="FR"></country> </address> <ref type="url">http://www.cnrs.fr/</ref> </desc></org></tutelle></tutelles></hal:affiliation><country>France</country></affiliation></author><author><name sortKey="Julien, C M" sort="Julien, C M" uniqKey="Julien C" first="C. M." last="Julien">C. M. Julien</name><affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-101592" status="VALID"><idno type="RNSR">199712634A</idno><orgName>Institut des Nanosciences de Paris</orgName><orgName type="acronym">INSP</orgName><desc><address><addrLine>Université Pierre et Marie Curie Case 840 4 place Jussieu 75252 Paris Cedex 05</addrLine><country key="FR"></country></address><ref type="url">http://www.insp.upmc.fr</ref></desc><listRelation><relation active="#struct-93591" type="direct"></relation><relation name="UMR7588" active="#struct-441569" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-93591" type="direct"><org type="institution" xml:id="struct-93591" status="VALID"><orgName>Université Pierre et Marie Curie - Paris 6</orgName><orgName type="acronym">UPMC</orgName><desc><address><addrLine>4 place Jussieu - 75005 Paris</addrLine><country key="FR"></country></address><ref type="url">http://www.upmc.fr/</ref></desc></org></tutelle><tutelle name="UMR7588" active="#struct-441569" type="direct"><org type="institution" xml:id="struct-441569" status="VALID"> <idno type="ISNI">0000000122597504</idno> <idno type="IdRef">02636817X</idno> <orgName>Centre National de la Recherche Scientifique</orgName> <orgName type="acronym">CNRS</orgName> <date type="start">1939-10-19</date> <desc> <address> <country key="FR"></country> </address> <ref type="url">http://www.cnrs.fr/</ref> </desc></org></tutelle></tutelles></hal:affiliation><country>France</country></affiliation></author></analytic><idno type="DOI">10.1007/s11581-007-0167-y</idno><series><title level="j">Ionics</title><idno type="ISSN">0947-7047</idno><imprint><date type="datePub">2008</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="mix" xml:lang="en"><term>Intercalation compounds</term><term>Layered structure</term><term>Li-ion batteries</term><term>Transition-metal oxides</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A series of LiNixMnyCozO2 (x=y, z=1−2y) oxides have been synthesized by “chimie douce” and investigated as positive electrodes in rechargeable lithium batteries. Layered LiNiyMnyCo1−2yO2 materials with high homogeneity and crystallinity were synthesized using the wet-chemical method assisted by carboxylic acid as the polymeric agent. The long range and local structural properties are investigated with experiments including Xray diffraction, Fourier transform infrared spectroscopy, and electron paramagnetic resonance spectroscopy. The evolution of the structure is discussed as a function of the cobalt content that confers layer-like behavior on the framework. Electrochemical performance of LiNiyMnyCo1−2yO2 oxides is tested in cells using nonaqueous 1 M LiPF6 dissolved in ethylene carbonate–diethyl carbonate. Charge–discharge profiles are investigated as a function of the rate capability and the voltage window. A relation is found between the gravimetric capacity and the cation disorder of the positive electrode as indicated by structural analysis. Fast lithium extraction attributed to the larger interslab space has been observed in the cobalt-rich oxides</div></front></TEI><hal api="V3"><titleStmt><title xml:lang="en">Local structure and electrochemistry of LiNiyMnyCo1−2yO2 electrode materials for Li-ion batteries</title><author role="aut"><persName><forename type="first">K.</forename><surname>Ben Kamel</surname></persName><email></email><idno type="halauthor">309648</idno><affiliation ref="#struct-84168"></affiliation></author><author role="aut"><persName><forename type="first">N.</forename><surname>Amdouni</surname></persName><email></email><idno type="halauthor">309649</idno><affiliation ref="#struct-84168"></affiliation></author><author role="aut"><persName><forename type="first">A.</forename><surname>Abdel-Ghany</surname></persName><email></email><idno type="halauthor">309650</idno><affiliation ref="#struct-101592"></affiliation></author><author role="aut"><persName><forename type="first">K.</forename><surname>Zaghib</surname></persName><email></email><idno type="halauthor">78384</idno><affiliation ref="#struct-301422"></affiliation></author><author role="aut"><persName><forename type="first">A.</forename><surname>Mauger</surname></persName><email></email><idno type="halauthor">78585</idno><affiliation ref="#struct-3204"></affiliation></author><author role="aut"><persName><forename type="first">F.</forename><surname>Gendron</surname></persName><email></email><idno type="halauthor">52389</idno><affiliation ref="#struct-101592"></affiliation></author><author role="aut"><persName><forename type="first">C.M.</forename><surname>Julien</surname></persName><email></email><idno type="halauthor">88007</idno><affiliation ref="#struct-101592"></affiliation></author><editor role="depositor"><persName><forename>Danielle</forename><surname>Thomas</surname></persName><email>Danielle.Thomas@impmc.jussieu.fr</email></editor></titleStmt><editionStmt><edition n="v1" type="current"><date type="whenSubmitted">2008-12-05 14:52:47</date><date type="whenModified">2016-10-11 14:39:11</date><date type="whenReleased">2008-12-05 14:52:47</date><date type="whenProduced">2008</date></edition><respStmt><resp>contributor</resp><name key="113613"><persName><forename>Danielle</forename><surname>Thomas</surname></persName><email>Danielle.Thomas@impmc.jussieu.fr</email></name></respStmt></editionStmt><publicationStmt><distributor>CCSD</distributor><idno type="halId">hal-00344702</idno><idno type="halUri">https://hal.archives-ouvertes.fr/hal-00344702</idno><idno type="halBibtex">benkamel:hal-00344702</idno><idno type="halRefHtml">Ionics, Springer Verlag, 2008, 14, pp.89-97. <10.1007/s11581-007-0167-y></idno><idno type="halRef">Ionics, Springer Verlag, 2008, 14, pp.89-97. <10.1007/s11581-007-0167-y></idno></publicationStmt><seriesStmt><idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno><idno type="stamp" n="UNIV-PARIS7">Université Denis Diderot - Paris VII</idno><idno type="stamp" n="IMPMC" p="UPMC">Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie</idno><idno type="stamp" n="INSP" p="UPMC">Institut des Nanosciences de Paris</idno><idno type="stamp" n="ALLINSP">Tout INSP</idno><idno type="stamp" n="UPMC">Université Pierre et Marie Curie</idno><idno type="stamp" n="INSP-E9" p="INSP">Oxydes en basses dimensions</idno><idno type="stamp" n="USPC">Université Sorbonne Paris Cité</idno></seriesStmt><notesStmt><note type="audience" n="2">International</note><note type="popular" n="0">No</note><note type="peer" n="1">Yes</note></notesStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Local structure and electrochemistry of LiNiyMnyCo1−2yO2 electrode materials for Li-ion batteries</title><author role="aut"><persName><forename type="first">K.</forename><surname>Ben Kamel</surname></persName><idno type="halAuthorId">309648</idno><affiliation ref="#struct-84168"></affiliation></author><author role="aut"><persName><forename type="first">N.</forename><surname>Amdouni</surname></persName><idno type="halAuthorId">309649</idno><affiliation ref="#struct-84168"></affiliation></author><author role="aut"><persName><forename type="first">A.</forename><surname>Abdel-Ghany</surname></persName><idno type="halAuthorId">309650</idno><affiliation ref="#struct-101592"></affiliation></author><author role="aut"><persName><forename type="first">K.</forename><surname>Zaghib</surname></persName><idno type="halAuthorId">78384</idno><affiliation ref="#struct-301422"></affiliation></author><author role="aut"><persName><forename type="first">A.</forename><surname>Mauger</surname></persName><idno type="halAuthorId">78585</idno><affiliation ref="#struct-3204"></affiliation></author><author role="aut"><persName><forename type="first">F.</forename><surname>Gendron</surname></persName><idno type="halAuthorId">52389</idno><affiliation ref="#struct-101592"></affiliation></author><author role="aut"><persName><forename type="first">C.M.</forename><surname>Julien</surname></persName><idno type="halAuthorId">88007</idno><affiliation ref="#struct-101592"></affiliation></author></analytic><monogr><idno type="halJournalId" status="VALID">14855</idno><idno type="issn">0947-7047</idno><idno type="eissn">1862-0760</idno><title level="j">Ionics</title><imprint><publisher>Springer Verlag</publisher><biblScope unit="volume">14</biblScope><biblScope unit="pp">89-97</biblScope><date type="datePub">2008</date></imprint></monogr><idno type="doi">10.1007/s11581-007-0167-y</idno></biblStruct></sourceDesc><profileDesc><langUsage><language ident="en">English</language></langUsage><textClass><keywords scheme="author"><term xml:lang="en">Transition-metal oxides</term><term xml:lang="en">Layered structure</term><term xml:lang="en">Intercalation compounds</term><term xml:lang="en">Li-ion batteries</term></keywords><classCode scheme="halDomain" n="phys.qphy">Physics [physics]/Quantum Physics [quant-ph]</classCode><classCode scheme="halTypology" n="ART">Journal articles</classCode></textClass><abstract xml:lang="en">A series of LiNixMnyCozO2 (x=y, z=1−2y) oxides have been synthesized by “chimie douce” and investigated as positive electrodes in rechargeable lithium batteries. Layered LiNiyMnyCo1−2yO2 materials with high homogeneity and crystallinity were synthesized using the wet-chemical method assisted by carboxylic acid as the polymeric agent. The long range and local structural properties are investigated with experiments including Xray diffraction, Fourier transform infrared spectroscopy, and electron paramagnetic resonance spectroscopy. The evolution of the structure is discussed as a function of the cobalt content that confers layer-like behavior on the framework. Electrochemical performance of LiNiyMnyCo1−2yO2 oxides is tested in cells using nonaqueous 1 M LiPF6 dissolved in ethylene carbonate–diethyl carbonate. Charge–discharge profiles are investigated as a function of the rate capability and the voltage window. A relation is found between the gravimetric capacity and the cation disorder of the positive electrode as indicated by structural analysis. Fast lithium extraction attributed to the larger interslab space has been observed in the cobalt-rich oxides</abstract></profileDesc></hal></record>Pour manipuler ce document sous Unix (Dilib)
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