Adventures in Vanadocene Chemistry
Identifieur interne : 000187 ( France/Analysis ); précédent : 000186; suivant : 000188Adventures in Vanadocene Chemistry
Auteurs : Robert Choukroun [France] ; Christian Lorber [France]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2005-12.
Descripteurs français
English descriptors
Abstract
This review surveys some aspects of the chemistry of [VCp2]. The high potential of vanadocene [VCp2] (and [V(CO)Cp2]) in organometallic chemistry is illustrated by new organometallic architectures. The rich redox chemistry of [VCp2] is shown by incorporation of this fragment into various C≡C and C≡N bonds. This molecular approach allows the connection of two (or more) paramagnetic centers through an organic linker in order to build magnetic nanoscopic organometallic wires. [VCp2] has also been studied in the field of materials such as vanadium carbide (VC) ceramics and in its role as a reducing agent toward elements of groups 8–10 to prepare Fe, Rh, and Pd colloids. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Url:
DOI: 10.1002/ejic.200500371
Affiliations:
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