Selective HOESY experiments for stereochemical determinations
Identifieur interne : 002408 ( Istex/Corpus ); précédent : 002407; suivant : 002409Selective HOESY experiments for stereochemical determinations
Auteurs : Mehdi Yemloul ; Sabine Bouguet-Bonnet ; Lalla Aïcha Ba ; Gilbert Kirsch ; Daniel CanetSource :
- Magnetic Resonance in Chemistry [ 0749-1581 ] ; 2008-10.
English descriptors
- Teeft :
- Actual isomer, Chem, Continuous proton decoupling, Dante pulse train, Dipolar interactions, Equilibrium magnetization, Experimental data, Experimental methods, Heteronuclear overhauser effect spectroscopy, Hoesy, Independent measurements, Initial slope, Interatomic, Interatomic distances, Isomer, John wiley sons, Magn, Nuclear overhauser effect, Phase cycle, Phase cycling, Proton, Relaxation rates, Relevant part, Remote carbons, Reson, Selective experiment, Selective hoesy experiments, Sensitivity reasons, Single experiment, Solomon equations, Systematic error.
Abstract
Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, 1H and 13C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.
Url:
DOI: 10.1002/mrc.2283
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, 1H and 13C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</div>
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<profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head>
<p>Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, <hi rend="superscript">1</hi>
H and <hi rend="superscript">13</hi>
C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</p>
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<p>Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, <sup>1</sup>
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C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</p>
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<abstract lang="en">Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, 1H and 13C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</abstract>
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