Selective HOESY experiments for stereochemical determinations
Identifieur interne : 002408 ( Istex/Corpus ); précédent : 002407; suivant : 002409Selective HOESY experiments for stereochemical determinations
Auteurs : Mehdi Yemloul ; Sabine Bouguet-Bonnet ; Lalla Aïcha Ba ; Gilbert Kirsch ; Daniel CanetSource :
- Magnetic Resonance in Chemistry [ 0749-1581 ] ; 2008-10.
English descriptors
- Teeft :
- Actual isomer, Chem, Continuous proton decoupling, Dante pulse train, Dipolar interactions, Equilibrium magnetization, Experimental data, Experimental methods, Heteronuclear overhauser effect spectroscopy, Hoesy, Independent measurements, Initial slope, Interatomic, Interatomic distances, Isomer, John wiley sons, Magn, Nuclear overhauser effect, Phase cycle, Phase cycling, Proton, Relaxation rates, Relevant part, Remote carbons, Reson, Selective experiment, Selective hoesy experiments, Sensitivity reasons, Single experiment, Solomon equations, Systematic error.
Abstract
Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, 1H and 13C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.
Url:
DOI: 10.1002/mrc.2283
Links to Exploration step
ISTEX:9A859BC5C921B33DC30B5E2EF39231149069D04BLe document en format XML
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slope</term><term>Interatomic</term><term>Interatomic distances</term><term>Isomer</term><term>John wiley sons</term><term>Magn</term><term>Nuclear overhauser effect</term><term>Phase cycle</term><term>Phase cycling</term><term>Proton</term><term>Relaxation rates</term><term>Relevant part</term><term>Remote carbons</term><term>Reson</term><term>Selective experiment</term><term>Selective hoesy experiments</term><term>Sensitivity reasons</term><term>Single experiment</term><term>Solomon equations</term><term>Systematic error</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, 1H and 13C, as this will be the case here). 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The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. 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key="FR"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Gilbert</forename><surname>Kirsch</surname></persName><affiliation><address><addrLine>LIMBP (EA3472)</addrLine><addrLine>Université de Metz</addrLine><addrLine>1</addrLine><addrLine>Bd Arago</addrLine><addrLine>57078 Metz‐Technopôle (cedex)</addrLine><country key="FR">FRANCE</country><country key="FR"></country></address></affiliation></author><author xml:id="author-0004" role="corresp"><persName><forename type="first">Daniel</forename><surname>Canet</surname></persName><email>Daniel.Canet@rmn.uhp‐nancy.fr</email><affiliation><address><addrLine>Méthodologie RMN (UMR CNRS‐UHP 7565)</addrLine><addrLine>Nancy‐Université</addrLine><addrLine>Faculté des Sciences et Techniques</addrLine><addrLine>B.P. 239</addrLine><addrLine>54506 Vandoeuvre‐lès‐Nancy (cedex)</addrLine><country key="FR">FRANCE</country><country key="FR"></country></address></affiliation><affiliation>Méthodologie 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The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</p></abstract><textClass><keywords xml:lang="en"><term xml:id="kwd1">carbon‐13 NMR</term><term xml:id="kwd2">nuclear Overhauser effect</term><term xml:id="kwd3">selective HOESY</term><term xml:id="kwd4">Solomon equations</term><term xml:id="kwd5">build‐up curves</term><term xml:id="kwd6">heterocyclic chemistry</term></keywords><keywords rend="articleCategory"><term>Research Article</term></keywords><keywords rend="tocHeading1"><term>Research Articles</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-7XXCC81J-5/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>John Wiley & Sons, Ltd.</publisherName><publisherLoc>Chichester, UK</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1097-458Xa</doi><issn type="print">0749-1581</issn><issn type="electronic">1097-458X</issn><idGroup><id type="product" value="MRC"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="MAGNETIC RESONANCE IN CHEMISTRY">Magnetic Resonance in Chemistry</title><title type="short">Magn. Reson. Chem.</title></titleGroup></publicationMeta><publicationMeta level="part" position="100"><doi origin="wiley" registered="yes">10.1002/mrc.v46:10</doi><numberingGroup><numbering type="journalVolume" number="46">46</numbering><numbering type="journalIssue">10</numbering></numberingGroup><coverDate startDate="2008-10">October 2008</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="60" status="forIssue"><doi origin="wiley" registered="yes">10.1002/mrc.2283</doi><idGroup><id type="unit" value="MRC2283"></id></idGroup><countGroup><count type="pageTotal" number="4"></count></countGroup><titleGroup><title type="articleCategory">Research Article</title><title type="tocHeading1">Research Articles</title></titleGroup><copyright ownership="publisher">Copyright © 2008 John Wiley & Sons, Ltd.</copyright><eventGroup><event type="manuscriptReceived" date="2008-05-14"></event><event type="manuscriptRevised" date="2008-06-03"></event><event type="manuscriptAccepted" date="2008-06-11"></event><event type="publishedOnlineEarlyUnpaginated" date="2008-08-05"></event><event type="firstOnline" date="2008-08-05"></event><event type="publishedOnlineFinalForm" date="2008-08-28"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.2 mode:FullText source:HeaderRef result:HeaderRef" date="2010-03-09"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:4.0.1" date="2014-03-20"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-31"></event></eventGroup><numberingGroup><numbering type="pageFirst">939</numbering><numbering type="pageLast">942</numbering></numberingGroup><correspondenceTo>Méthodologie RMN (UMR CNRS‐UHP 7565), Nancy‐Université, Faculté des Sciences et Techniques, B.P. 239, 54506 Vandoeuvre‐lès‐Nancy (cedex), France.===</correspondenceTo><linkGroup><link type="toTypesetVersion" href="file:MRC.MRC2283.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="6"></count><count type="tableTotal" number="1"></count><count type="referenceTotal" number="15"></count></countGroup><titleGroup><title type="main" xml:lang="en">Selective HOESY experiments for stereochemical determinations</title><title type="short" xml:lang="en">Selective HOESY</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Mehdi</givenNames><familyName>Yemloul</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Sabine</givenNames><familyName>Bouguet‐Bonnet</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Lalla Aïcha</givenNames><familyName>Ba</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af2"><personName><givenNames>Gilbert</givenNames><familyName>Kirsch</familyName></personName></creator><creator xml:id="au5" creatorRole="author" affiliationRef="#af1" corresponding="yes"><personName><givenNames>Daniel</givenNames><familyName>Canet</familyName></personName><contactDetails><email normalForm="Daniel.Canet@rmn.uhp-nancy.fr">Daniel.Canet@rmn.uhp‐nancy.fr</email></contactDetails></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="FR" type="organization"><unparsedAffiliation>Méthodologie RMN (UMR CNRS‐UHP 7565), Nancy‐Université, Faculté des Sciences et Techniques, B.P. 239, 54506 Vandoeuvre‐lès‐Nancy (cedex), France</unparsedAffiliation></affiliation><affiliation xml:id="af2" countryCode="FR" type="organization"><unparsedAffiliation>LIMBP (EA3472), Université de Metz, 1, Bd Arago, 57078 Metz‐Technopôle (cedex), France</unparsedAffiliation></affiliation></affiliationGroup><keywordGroup xml:lang="en" type="author"><keyword xml:id="kwd1">carbon‐13 NMR</keyword><keyword xml:id="kwd2">nuclear Overhauser effect</keyword><keyword xml:id="kwd3">selective HOESY</keyword><keyword xml:id="kwd4">Solomon equations</keyword><keyword xml:id="kwd5">build‐up curves</keyword><keyword xml:id="kwd6">heterocyclic chemistry</keyword></keywordGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, <sup>1</sup>H and <sup>13</sup>C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Selective HOESY experiments for stereochemical determinations</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Selective HOESY</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Selective HOESY experiments for stereochemical determinations</title></titleInfo><name type="personal"><namePart type="given">Mehdi</namePart><namePart type="family">Yemloul</namePart><affiliation>Méthodologie RMN (UMR CNRS‐UHP 7565), Nancy‐Université, Faculté des Sciences et Techniques, B.P. 239, 54506 Vandoeuvre‐lès‐Nancy (cedex), France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Sabine</namePart><namePart type="family">Bouguet‐Bonnet</namePart><affiliation>Méthodologie RMN (UMR CNRS‐UHP 7565), Nancy‐Université, Faculté des Sciences et Techniques, B.P. 239, 54506 Vandoeuvre‐lès‐Nancy (cedex), France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Lalla Aïcha</namePart><namePart type="family">Ba</namePart><affiliation>LIMBP (EA3472), Université de Metz, 1, Bd Arago, 57078 Metz‐Technopôle (cedex), France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Gilbert</namePart><namePart type="family">Kirsch</namePart><affiliation>LIMBP (EA3472), Université de Metz, 1, Bd Arago, 57078 Metz‐Technopôle (cedex), France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Daniel</namePart><namePart type="family">Canet</namePart><affiliation>Méthodologie RMN (UMR CNRS‐UHP 7565), Nancy‐Université, Faculté des Sciences et Techniques, B.P. 239, 54506 Vandoeuvre‐lès‐Nancy (cedex), France</affiliation><affiliation>E-mail: Daniel.Canet@rmn.uhp‐nancy.fr</affiliation><affiliation>Correspondence address: Méthodologie RMN (UMR CNRS‐UHP 7565), Nancy‐Université, Faculté des Sciences et Techniques, B.P. 239, 54506 Vandoeuvre‐lès‐Nancy (cedex), France.===</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>John Wiley & Sons, Ltd.</publisher><place><placeTerm type="text">Chichester, UK</placeTerm></place><dateIssued encoding="w3cdtf">2008-10</dateIssued><dateCaptured encoding="w3cdtf">2008-05-14</dateCaptured><dateValid encoding="w3cdtf">2008-06-11</dateValid><copyrightDate encoding="w3cdtf">2008</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">6</extent><extent unit="tables">1</extent><extent unit="references">15</extent></physicalDescription><abstract lang="en">Heteronuclear Overhauser effect spectroscopy (HOESY) is a powerful method for tracking geometrical proximities between two heteronuclei (for instance, 1H and 13C, as this will be the case here). The method is based on cross‐relaxation arising from dipolar interactions. Sensitivity permitting, it is applied in the 2D mode yielding all spatial correlations in a single experiment. Whenever sensitivity is not sufficient, it can be applied in the one‐dimensional mode by selectively inverting one particular proton. In that case, it yields, from the carbon‐13 spectrum, remote spatial correlations. The method has been employed here for the discrimination between two possible E or Z isomers in a medium‐size molecule. Copyright © 2008 John Wiley & Sons, Ltd.</abstract><subject lang="en"><genre>keywords</genre><topic>carbon‐13 NMR</topic><topic>nuclear Overhauser effect</topic><topic>selective HOESY</topic><topic>Solomon equations</topic><topic>build‐up curves</topic><topic>heterocyclic chemistry</topic></subject><relatedItem type="host"><titleInfo><title>Magnetic Resonance in Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Magn. Reson. 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