Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads
Identifieur interne : 002095 ( Istex/Corpus ); précédent : 002094; suivant : 002096Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads
Auteurs : Josef Seidl ; Alois Mat Jí Ek ; Emil Krejcar ; Jaroslav HorkSource :
- Journal of Applied Polymer Science [ 0021-8995 ] ; 1985-04.
English descriptors
- Teeft :
- Absorption bands, Activation energy, Active groups, Alkaline hydrolysis, Amide, Amide groups, Amide groups hydrolysis, Aqueous solution, Average values, Bead form, Bead size, Carboxyl groups, Coefficient, Confidence interval, Consecutive reaction, Copolymer, Copolymer hydrolysis, Copolymer particles, Correlation coefficient, Crosslinked, Crosslinked copolymer, Crosslinked copolymers, Diffusion coefficient, Diffusion coefficients, Diffusion time, Diffusion times, Empirical equation, Empirical equations, Empirical relations, Ester, Ester groups, Ester groups hydrolysis, Ethyl acrylate, Ethyl copolymer beads, Experimental data, Experimental results, First phase, Further course, Hydrolysis, Hydrolysis course, Hydrolytic, Hydrolytic agent, Hydrolytic agent concentration, Hydroxide, Infrared spectroscopy, Infrared spectrum, Liquid reaction medium, Middle particle size, Nitrile, Nitrile groups, Nonsteady diffusion, Rate constants, Reaction kinetics, Reaction rate, Reaction rate constants, Reaction temperature, Reaction time, Relative absorbance, Research institute, Residual dispersion variance, Semilogarithmic transformation, Sodium hydroxide, Statistical characteristics, Straight line, Synthetic resins, Time dependence, Total weight exchange capacity, Variable parameters.
Abstract
This article deals with the alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads. Chemical changes during hydrolysis were evaluated by means of determination of total weight exchange capacity and of infrared spectroscopy. The influence of reaction temperature, concentration of the hydrolytic agent, degree of copolymers crosslinking as well as the influence of particle size upon the rate of hydrolysis were studied as a function of time. The mathematical and statistical calculations of experimental data were carried out. With respect to time dependence of hydrolysis of the copolymer functional groups, the average values of reaction rate constants as well as the values of assumed diffusion coefficients were calculated. The analysis is based on partial linearization of experimental results by means of semilogarithmic transformation. The empirical relations expressing dependences of reaction rate constants and of diffusion coefficients on conditions of hydrolysis were determined.
Url:
DOI: 10.1002/app.1985.070300438
Links to Exploration step
ISTEX:8E0AB1E8D2783A8A98A230B02A3CAEE1B68CFA28Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads</title><author><name sortKey="Seidl, Josef" sort="Seidl, Josef" uniqKey="Seidl J" first="Josef" last="Seidl">Josef Seidl</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author><author><name sortKey="Mat Ji Ek, Alois" sort="Mat Ji Ek, Alois" uniqKey="Mat Ji Ek A" first="Alois" last="Mat Jí Ek">Alois Mat Jí Ek</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author><author><name sortKey="Krejcar, Emil" sort="Krejcar, Emil" uniqKey="Krejcar E" first="Emil" last="Krejcar">Emil Krejcar</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author><author><name sortKey="Hork, Jaroslav" sort="Hork, Jaroslav" uniqKey="Hork J" first="Jaroslav" last="Hork">Jaroslav Hork</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:8E0AB1E8D2783A8A98A230B02A3CAEE1B68CFA28</idno><date when="1985" year="1985">1985</date><idno type="doi">10.1002/app.1985.070300438</idno><idno type="url">https://api.istex.fr/ark:/67375/WNG-ZFZZDPPB-M/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">002095</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">002095</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads<ref type="note" target="#fn1"></ref></title><author><name sortKey="Seidl, Josef" sort="Seidl, Josef" uniqKey="Seidl J" first="Josef" last="Seidl">Josef Seidl</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author><author><name sortKey="Mat Ji Ek, Alois" sort="Mat Ji Ek, Alois" uniqKey="Mat Ji Ek A" first="Alois" last="Mat Jí Ek">Alois Mat Jí Ek</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author><author><name sortKey="Krejcar, Emil" sort="Krejcar, Emil" uniqKey="Krejcar E" first="Emil" last="Krejcar">Emil Krejcar</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author><author><name sortKey="Hork, Jaroslav" sort="Hork, Jaroslav" uniqKey="Hork J" first="Jaroslav" last="Hork">Jaroslav Hork</name><affiliation><mods:affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j" type="main">Journal of Applied Polymer Science</title><title level="j" type="alt">JOURNAL OF APPLIED POLYMER SCIENCE</title><idno type="ISSN">0021-8995</idno><idno type="eISSN">1097-4628</idno><imprint><biblScope unit="vol">30</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="1741">1741</biblScope><biblScope unit="page" to="1752">1752</biblScope><biblScope unit="page-count">12</biblScope><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>New York</pubPlace><date type="published" when="1985-04">1985-04</date></imprint><idno type="ISSN">0021-8995</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0021-8995</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Absorption bands</term><term>Activation energy</term><term>Active groups</term><term>Alkaline hydrolysis</term><term>Amide</term><term>Amide groups</term><term>Amide groups hydrolysis</term><term>Aqueous solution</term><term>Average values</term><term>Bead form</term><term>Bead size</term><term>Carboxyl groups</term><term>Coefficient</term><term>Confidence interval</term><term>Consecutive reaction</term><term>Copolymer</term><term>Copolymer hydrolysis</term><term>Copolymer particles</term><term>Correlation coefficient</term><term>Crosslinked</term><term>Crosslinked copolymer</term><term>Crosslinked copolymers</term><term>Diffusion coefficient</term><term>Diffusion coefficients</term><term>Diffusion time</term><term>Diffusion times</term><term>Empirical equation</term><term>Empirical equations</term><term>Empirical relations</term><term>Ester</term><term>Ester groups</term><term>Ester groups hydrolysis</term><term>Ethyl acrylate</term><term>Ethyl copolymer beads</term><term>Experimental data</term><term>Experimental results</term><term>First phase</term><term>Further course</term><term>Hydrolysis</term><term>Hydrolysis course</term><term>Hydrolytic</term><term>Hydrolytic agent</term><term>Hydrolytic agent concentration</term><term>Hydroxide</term><term>Infrared spectroscopy</term><term>Infrared spectrum</term><term>Liquid reaction medium</term><term>Middle particle size</term><term>Nitrile</term><term>Nitrile groups</term><term>Nonsteady diffusion</term><term>Rate constants</term><term>Reaction kinetics</term><term>Reaction rate</term><term>Reaction rate constants</term><term>Reaction temperature</term><term>Reaction time</term><term>Relative absorbance</term><term>Research institute</term><term>Residual dispersion variance</term><term>Semilogarithmic transformation</term><term>Sodium hydroxide</term><term>Statistical characteristics</term><term>Straight line</term><term>Synthetic resins</term><term>Time dependence</term><term>Total weight exchange capacity</term><term>Variable parameters</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">This article deals with the alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads. Chemical changes during hydrolysis were evaluated by means of determination of total weight exchange capacity and of infrared spectroscopy. The influence of reaction temperature, concentration of the hydrolytic agent, degree of copolymers crosslinking as well as the influence of particle size upon the rate of hydrolysis were studied as a function of time. The mathematical and statistical calculations of experimental data were carried out. With respect to time dependence of hydrolysis of the copolymer functional groups, the average values of reaction rate constants as well as the values of assumed diffusion coefficients were calculated. The analysis is based on partial linearization of experimental results by means of semilogarithmic transformation. The empirical relations expressing dependences of reaction rate constants and of diffusion coefficients on conditions of hydrolysis were determined.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>copolymer</json:string><json:string>nitrile</json:string><json:string>ester</json:string><json:string>hydrolytic</json:string><json:string>hydroxide</json:string><json:string>nitrile groups</json:string><json:string>rate constants</json:string><json:string>reaction temperature</json:string><json:string>hydrolytic agent</json:string><json:string>sodium hydroxide</json:string><json:string>hydrolytic agent concentration</json:string><json:string>diffusion coefficients</json:string><json:string>ester groups</json:string><json:string>crosslinked</json:string><json:string>time dependence</json:string><json:string>amide groups</json:string><json:string>aqueous solution</json:string><json:string>ethyl copolymer beads</json:string><json:string>diffusion time</json:string><json:string>alkaline hydrolysis</json:string><json:string>amide</json:string><json:string>empirical relations</json:string><json:string>carboxyl groups</json:string><json:string>crosslinked copolymers</json:string><json:string>hydrolysis</json:string><json:string>active groups</json:string><json:string>activation energy</json:string><json:string>straight line</json:string><json:string>copolymer particles</json:string><json:string>reaction kinetics</json:string><json:string>copolymer hydrolysis</json:string><json:string>correlation coefficient</json:string><json:string>first phase</json:string><json:string>reaction time</json:string><json:string>ester groups hydrolysis</json:string><json:string>experimental data</json:string><json:string>diffusion coefficient</json:string><json:string>empirical equations</json:string><json:string>residual dispersion variance</json:string><json:string>coefficient</json:string><json:string>liquid reaction medium</json:string><json:string>synthetic resins</json:string><json:string>infrared spectrum</json:string><json:string>absorption bands</json:string><json:string>crosslinked copolymer</json:string><json:string>experimental results</json:string><json:string>semilogarithmic transformation</json:string><json:string>bead size</json:string><json:string>reaction rate</json:string><json:string>relative absorbance</json:string><json:string>total weight exchange capacity</json:string><json:string>hydrolysis course</json:string><json:string>diffusion times</json:string><json:string>nonsteady diffusion</json:string><json:string>infrared spectroscopy</json:string><json:string>middle particle size</json:string><json:string>consecutive reaction</json:string><json:string>amide groups hydrolysis</json:string><json:string>average values</json:string><json:string>reaction rate constants</json:string><json:string>variable parameters</json:string><json:string>empirical equation</json:string><json:string>statistical characteristics</json:string><json:string>bead form</json:string><json:string>research institute</json:string><json:string>confidence interval</json:string><json:string>ethyl acrylate</json:string><json:string>further course</json:string></teeft></keywords><author><json:item><name>Josef Seidl</name><affiliations><json:string>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</json:string></affiliations></json:item><json:item><name>Alois Matějíček</name><affiliations><json:string>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</json:string></affiliations></json:item><json:item><name>Emil Krejcar</name><affiliations><json:string>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</json:string></affiliations></json:item><json:item><name>Jaroslav Horký</name><affiliations><json:string>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</json:string></affiliations></json:item></author><articleId><json:string>APP070300438</json:string></articleId><arkIstex>ark:/67375/WNG-ZFZZDPPB-M</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>article</json:string></originalGenre><abstract>This article deals with the alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads. Chemical changes during hydrolysis were evaluated by means of determination of total weight exchange capacity and of infrared spectroscopy. The influence of reaction temperature, concentration of the hydrolytic agent, degree of copolymers crosslinking as well as the influence of particle size upon the rate of hydrolysis were studied as a function of time. The mathematical and statistical calculations of experimental data were carried out. With respect to time dependence of hydrolysis of the copolymer functional groups, the average values of reaction rate constants as well as the values of assumed diffusion coefficients were calculated. The analysis is based on partial linearization of experimental results by means of semilogarithmic transformation. The empirical relations expressing dependences of reaction rate constants and of diffusion coefficients on conditions of hydrolysis were determined.</abstract><qualityIndicators><score>7.016</score><pdfWordCount>3336</pdfWordCount><pdfCharCount>20250</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>12</pdfPageCount><pdfPageSize>468 x 719.759 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>140</abstractWordCount><abstractCharCount>1019</abstractCharCount><keywordCount>0</keywordCount></qualityIndicators><title>Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads</title><genre><json:string>article</json:string></genre><host><title>Journal of Applied Polymer Science</title><language><json:string>unknown</json:string></language><doi><json:string>10.1002/(ISSN)1097-4628</json:string></doi><issn><json:string>0021-8995</json:string></issn><eissn><json:string>1097-4628</json:string></eissn><publisherId><json:string>APP</json:string></publisherId><volume>30</volume><issue>4</issue><pages><first>1741</first><last>1752</last><total>12</total></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Article</value></json:item></subject></host><namedEntities><unitex><date></date><geogName></geogName><orgName></orgName><orgName_funder></orgName_funder><orgName_provider></orgName_provider><persName></persName><placeName></placeName><ref_url></ref_url><ref_bibl></ref_bibl><bibl></bibl></unitex></namedEntities><ark><json:string>ark:/67375/WNG-ZFZZDPPB-M</json:string></ark><categories><wos><json:string>1 - science</json:string><json:string>2 - polymer science</json:string></wos><scienceMetrix><json:string>1 - natural sciences</json:string><json:string>2 - chemistry</json:string><json:string>3 - polymers</json:string></scienceMetrix><scopus><json:string>1 - Physical Sciences</json:string><json:string>2 - Materials Science</json:string><json:string>3 - Materials Chemistry</json:string><json:string>1 - Physical Sciences</json:string><json:string>2 - Materials Science</json:string><json:string>3 - Polymers and Plastics</json:string><json:string>1 - Physical Sciences</json:string><json:string>2 - Materials Science</json:string><json:string>3 - Surfaces, Coatings and Films</json:string><json:string>1 - Physical Sciences</json:string><json:string>2 - Chemistry</json:string><json:string>3 - General Chemistry</json:string></scopus><inist><json:string>1 - sciences appliquees, technologies et medecines</json:string><json:string>2 - sciences biologiques et medicales</json:string><json:string>3 - sciences biologiques fondamentales et appliquees. psychologie</json:string></inist></categories><publicationDate>1985</publicationDate><copyrightDate>1985</copyrightDate><doi><json:string>10.1002/app.1985.070300438</json:string></doi><id>8E0AB1E8D2783A8A98A230B02A3CAEE1B68CFA28</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-ZFZZDPPB-M/fulltext.pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-ZFZZDPPB-M/bundle.zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/ark:/67375/WNG-ZFZZDPPB-M/fulltext.tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads<ref type="note" target="#fn1"></ref></title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>New York</pubPlace><availability><licence>Copyright © 1985 John Wiley & Sons, Inc.</licence></availability><date type="published" when="1985-04"></date></publicationStmt><notesStmt><note type="content-type" subtype="article" source="article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</note><note type="publication-type" subtype="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note></notesStmt><sourceDesc><biblStruct type="article"><analytic><title level="a" type="main" xml:lang="en">Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads<ref type="note" target="#fn1"></ref></title><title level="a" type="short" xml:lang="en">ETHYL ACRYLATE–AN–DVB COPOLYMER BEADS</title><author xml:id="author-0000"><persName><forename type="first">Josef</forename><surname>Seidl</surname></persName><affiliation><orgName type="institution">Research Institute for Synthetic Resins and Lacquers</orgName><address><addrLine>Pardubice</addrLine><addrLine>Czechoslovakia</addrLine><country key="CZ"></country></address></affiliation></author><author xml:id="author-0001"><persName><forename type="first">Alois</forename><surname>Matějíček</surname></persName><affiliation><orgName type="institution">Research Institute for Synthetic Resins and Lacquers</orgName><address><addrLine>Pardubice</addrLine><addrLine>Czechoslovakia</addrLine><country key="CZ"></country></address></affiliation></author><author xml:id="author-0002"><persName><forename type="first">Emil</forename><surname>Krejcar</surname></persName><affiliation><orgName type="institution">Research Institute for Synthetic Resins and Lacquers</orgName><address><addrLine>Pardubice</addrLine><addrLine>Czechoslovakia</addrLine><country key="CZ"></country></address></affiliation></author><author xml:id="author-0003"><persName><forename type="first">Jaroslav</forename><surname>Horký</surname></persName><affiliation><orgName type="institution">Research Institute for Synthetic Resins and Lacquers</orgName><address><addrLine>Pardubice</addrLine><addrLine>Czechoslovakia</addrLine><country key="CZ"></country></address></affiliation></author><idno type="istex">8E0AB1E8D2783A8A98A230B02A3CAEE1B68CFA28</idno><idno type="ark">ark:/67375/WNG-ZFZZDPPB-M</idno><idno type="DOI">10.1002/app.1985.070300438</idno><idno type="unit">APP070300438</idno><idno type="toTypesetVersion">file:APP.APP070300438.pdf</idno></analytic><monogr><title level="j" type="main">Journal of Applied Polymer Science</title><title level="j" type="alt">JOURNAL OF APPLIED POLYMER SCIENCE</title><idno type="pISSN">0021-8995</idno><idno type="eISSN">1097-4628</idno><idno type="book-DOI">10.1002/(ISSN)1097-4628</idno><idno type="book-part-DOI">10.1002/app.07.v30:4</idno><idno type="product">APP</idno><imprint><biblScope unit="vol">30</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="1741">1741</biblScope><biblScope unit="page" to="1752">1752</biblScope><biblScope unit="page-count">12</biblScope><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><pubPlace>New York</pubPlace><date type="published" when="1985-04"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><abstract xml:lang="en" style="main"><head>Abstract</head><p>This article deals with the alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads. Chemical changes during hydrolysis were evaluated by means of determination of total weight exchange capacity and of infrared spectroscopy. The influence of reaction temperature, concentration of the hydrolytic agent, degree of copolymers crosslinking as well as the influence of particle size upon the rate of hydrolysis were studied as a function of time. The mathematical and statistical calculations of experimental data were carried out. With respect to time dependence of hydrolysis of the copolymer functional groups, the average values of reaction rate constants as well as the values of assumed diffusion coefficients were calculated. The analysis is based on partial linearization of experimental results by means of semilogarithmic transformation. The empirical relations expressing dependences of reaction rate constants and of diffusion coefficients on conditions of hydrolysis were determined.</p></abstract><textClass><keywords rend="articleCategory"><term>Article</term></keywords><keywords rend="tocHeading1"><term>Articles</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-ZFZZDPPB-M/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component version="2.0" type="serialArticle" xml:lang="en"><header><publicationMeta level="product"><publisherInfo><publisherName>Wiley Subscription Services, Inc., A Wiley Company</publisherName><publisherLoc>New York</publisherLoc></publisherInfo><doi registered="yes">10.1002/(ISSN)1097-4628</doi><issn type="print">0021-8995</issn><issn type="electronic">1097-4628</issn><idGroup><id type="product" value="APP"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="JOURNAL OF APPLIED POLYMER SCIENCE">Journal of Applied Polymer Science</title><title type="short">J. Appl. Polym. Sci.</title></titleGroup></publicationMeta><publicationMeta level="part" position="40"><doi origin="wiley" registered="yes">10.1002/app.07.v30:4</doi><numberingGroup><numbering type="journalVolume" number="30">30</numbering><numbering type="journalIssue">4</numbering></numberingGroup><coverDate startDate="1985-04">April 1985</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="38" status="forIssue"><doi origin="wiley" registered="yes">10.1002/app.1985.070300438</doi><idGroup><id type="unit" value="APP070300438"></id></idGroup><countGroup><count type="pageTotal" number="12"></count></countGroup><titleGroup><title type="articleCategory">Article</title><title type="tocHeading1">Articles</title></titleGroup><copyright ownership="publisher">Copyright © 1985 John Wiley & Sons, Inc.</copyright><eventGroup><event type="manuscriptReceived" date="1983-10-10"></event><event type="manuscriptAccepted" date="1984-06-01"></event><event type="firstOnline" date="2003-03-09"></event><event type="publishedOnlineFinalForm" date="2003-03-09"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.18.1 mode:FullText source:HeaderRef result:HeaderRef" date="2010-09-09"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:4.0.1" date="2014-03-24"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-24"></event></eventGroup><numberingGroup><numbering type="pageFirst">1741</numbering><numbering type="pageLast">1752</numbering></numberingGroup><linkGroup><link type="toTypesetVersion" href="file:APP.APP070300438.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="5"></count><count type="tableTotal" number="2"></count><count type="referenceTotal" number="18"></count></countGroup><titleGroup><title type="main" xml:lang="en">Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads<link href="#fn1"></link></title><title type="short" xml:lang="en">ETHYL ACRYLATE–AN–DVB COPOLYMER BEADS</title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Josef</givenNames><familyName>Seidl</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Alois</givenNames><familyName>Matějíček</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Emil</givenNames><familyName>Krejcar</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#af1"><personName><givenNames>Jaroslav</givenNames><familyName>Horký</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="af1" countryCode="CZ" type="organization"><unparsedAffiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</unparsedAffiliation></affiliation></affiliationGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>This article deals with the alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads. Chemical changes during hydrolysis were evaluated by means of determination of total weight exchange capacity and of infrared spectroscopy. The influence of reaction temperature, concentration of the hydrolytic agent, degree of copolymers crosslinking as well as the influence of particle size upon the rate of hydrolysis were studied as a function of time. The mathematical and statistical calculations of experimental data were carried out. With respect to time dependence of hydrolysis of the copolymer functional groups, the average values of reaction rate constants as well as the values of assumed diffusion coefficients were calculated. The analysis is based on partial linearization of experimental results by means of semilogarithmic transformation. The empirical relations expressing dependences of reaction rate constants and of diffusion coefficients on conditions of hydrolysis were determined.</p></abstract></abstractGroup></contentMeta><noteGroup><note xml:id="fn1"><p>Corrected proofs received January 30, 1985</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>ETHYL ACRYLATE–AN–DVB COPOLYMER BEADS</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads</title></titleInfo><name type="personal"><namePart type="given">Josef</namePart><namePart type="family">Seidl</namePart><affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Alois</namePart><namePart type="family">Matějíček</namePart><affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Emil</namePart><namePart type="family">Krejcar</namePart><affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Jaroslav</namePart><namePart type="family">Horký</namePart><affiliation>Research Institute for Synthetic Resins and Lacquers, Pardubice, Czechoslovakia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Wiley Subscription Services, Inc., A Wiley Company</publisher><place><placeTerm type="text">New York</placeTerm></place><dateIssued encoding="w3cdtf">1985-04</dateIssued><dateCaptured encoding="w3cdtf">1983-10-10</dateCaptured><dateValid encoding="w3cdtf">1984-06-01</dateValid><copyrightDate encoding="w3cdtf">1985</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">5</extent><extent unit="tables">2</extent><extent unit="references">18</extent></physicalDescription><abstract lang="en">This article deals with the alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads. Chemical changes during hydrolysis were evaluated by means of determination of total weight exchange capacity and of infrared spectroscopy. The influence of reaction temperature, concentration of the hydrolytic agent, degree of copolymers crosslinking as well as the influence of particle size upon the rate of hydrolysis were studied as a function of time. The mathematical and statistical calculations of experimental data were carried out. With respect to time dependence of hydrolysis of the copolymer functional groups, the average values of reaction rate constants as well as the values of assumed diffusion coefficients were calculated. The analysis is based on partial linearization of experimental results by means of semilogarithmic transformation. The empirical relations expressing dependences of reaction rate constants and of diffusion coefficients on conditions of hydrolysis were determined.</abstract><note type="content">*Corrected proofs received January 30, 1985</note><relatedItem type="host"><titleInfo><title>Journal of Applied Polymer Science</title></titleInfo><titleInfo type="abbreviated"><title>J. Appl. Polym. Sci.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>article-category</genre><topic>Article</topic></subject><identifier type="ISSN">0021-8995</identifier><identifier type="eISSN">1097-4628</identifier><identifier type="DOI">10.1002/(ISSN)1097-4628</identifier><identifier type="PublisherID">APP</identifier><part><date>1985</date><detail type="volume"><caption>vol.</caption><number>30</number></detail><detail type="issue"><caption>no.</caption><number>4</number></detail><extent unit="pages"><start>1741</start><end>1752</end><total>12</total></extent></part></relatedItem><identifier type="istex">8E0AB1E8D2783A8A98A230B02A3CAEE1B68CFA28</identifier><identifier type="ark">ark:/67375/WNG-ZFZZDPPB-M</identifier><identifier type="DOI">10.1002/app.1985.070300438</identifier><identifier type="ArticleID">APP070300438</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 1985 John Wiley & Sons, Inc.</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-L0C46X92-X">wiley</recordContentSource><recordOrigin>Wiley Subscription Services, Inc., A Wiley Company</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-ZFZZDPPB-M/record.json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/InforLorV4/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 002095 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 002095 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Lorraine
|area= InforLorV4
|flux= Istex
|étape= Corpus
|type= RBID
|clé= ISTEX:8E0AB1E8D2783A8A98A230B02A3CAEE1B68CFA28
|texte= Alkaline hydrolysis of ethyl acrylate–acrylonitrile–divinylbenzene copolymer beads
}}
| This area was generated with Dilib version V0.6.33. |  |