A (Tetrasilacyclobutadiene)tricarbonyliron Complex [{η4‐(tBu2MeSi)4Si4}Fe(CO)3]: The Silicon Cousin of Pettit's (Cyclobutadiene)tricarbonyliron Complex [(η4‐H4C4)Fe(CO)3]
Identifieur interne : 004E01 ( Istex/Curation ); précédent : 004E00; suivant : 004E02A (Tetrasilacyclobutadiene)tricarbonyliron Complex [{η4‐(tBu2MeSi)4Si4}Fe(CO)3]: The Silicon Cousin of Pettit's (Cyclobutadiene)tricarbonyliron Complex [(η4‐H4C4)Fe(CO)3]
Auteurs : Kazunori Takanashi [Japon] ; Vladimir Ya. Lee [Japon] ; Masaaki Ichinohe [Japon] ; Akira Sekiguchi [Japon]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2006-05-12.
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Abstract
All in the family: [(η4‐R4Si4)Fe(CO)3] 2 (R=SiMetBu2) represents a neutral silicon congener of a (cyclobutadiene)tricarbonyliron complex and was synthesized by the reaction of the dibromocyclotetrasilene R4Si4Br2 1 with Na2[Fe(CO)4]. The tetrasilacyclobutadiene ligand in 2 has stronger π‐donating properties than the cyclobutadiene ligand in the parent complex [(η4‐H4C4)Fe(CO)3].
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DOI: 10.1002/anie.200600338
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Akira Sekiguchi<affiliation><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan, Fax: (+81) 29‐853‐4314</mods:affiliation><wicri:noCountry code="subField">Fax: (+81) 29‐853‐4314</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: sekiguch@staff.chem.tsukuba.ac.jp</mods:affiliation><country wicri:rule="url">Japon</country></affiliation>Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">A (Tetrasilacyclobutadiene)tricarbonyliron Complex [{η4‐(tBu2MeSi)4Si4}Fe(CO)3]: The Silicon Cousin of Pettit's (Cyclobutadiene)tricarbonyliron Complex [(η4‐H4C4)Fe(CO)3]</title><author><name sortKey="Takanashi, Kazunori" sort="Takanashi, Kazunori" uniqKey="Takanashi K" first="Kazunori" last="Takanashi">Kazunori Takanashi</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571</wicri:regionArea></affiliation></author><author><name sortKey="Lee, Vladimir Ya" sort="Lee, Vladimir Ya" uniqKey="Lee V" first="Vladimir Ya." last="Lee">Vladimir Ya. Lee</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571</wicri:regionArea></affiliation></author><author><name sortKey="Ichinohe, Masaaki" sort="Ichinohe, Masaaki" uniqKey="Ichinohe M" first="Masaaki" last="Ichinohe">Masaaki Ichinohe</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571</wicri:regionArea></affiliation></author><author><name sortKey="Sekiguchi, Akira" sort="Sekiguchi, Akira" uniqKey="Sekiguchi A" first="Akira" last="Sekiguchi">Akira Sekiguchi</name><affiliation><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan, Fax: (+81) 29‐853‐4314</mods:affiliation><wicri:noCountry code="subField">Fax: (+81) 29‐853‐4314</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: sekiguch@staff.chem.tsukuba.ac.jp</mods:affiliation><country wicri:rule="url">Japon</country></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:AAE17EA8B66D03FD4D5709DF736473D9E3DA342E</idno><date when="2006" year="2006">2006</date><idno type="doi">10.1002/anie.200600338</idno><idno type="url">https://api.istex.fr/document/AAE17EA8B66D03FD4D5709DF736473D9E3DA342E/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">004E01</idno><idno type="wicri:Area/Istex/Curation">004E01</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">A (Tetrasilacyclobutadiene)tricarbonyliron Complex [{η4‐(tBu2MeSi)4Si4}Fe(CO)3]: The Silicon Cousin of Pettit's (Cyclobutadiene)tricarbonyliron Complex [(η4‐H4C4)Fe(CO)3]</title><author><name sortKey="Takanashi, Kazunori" sort="Takanashi, Kazunori" uniqKey="Takanashi K" first="Kazunori" last="Takanashi">Kazunori Takanashi</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571</wicri:regionArea></affiliation></author><author><name sortKey="Lee, Vladimir Ya" sort="Lee, Vladimir Ya" uniqKey="Lee V" first="Vladimir Ya." last="Lee">Vladimir Ya. Lee</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571</wicri:regionArea></affiliation></author><author><name sortKey="Ichinohe, Masaaki" sort="Ichinohe, Masaaki" uniqKey="Ichinohe M" first="Masaaki" last="Ichinohe">Masaaki Ichinohe</name><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan</mods:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571</wicri:regionArea></affiliation></author><author><name sortKey="Sekiguchi, Akira" sort="Sekiguchi, Akira" uniqKey="Sekiguchi A" first="Akira" last="Sekiguchi">Akira Sekiguchi</name><affiliation><mods:affiliation>Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305‐8571, Japan, Fax: (+81) 29‐853‐4314</mods:affiliation><wicri:noCountry code="subField">Fax: (+81) 29‐853‐4314</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: sekiguch@staff.chem.tsukuba.ac.jp</mods:affiliation><country wicri:rule="url">Japon</country></affiliation></author></analytic><monogr></monogr><series><title level="j">Angewandte Chemie International Edition</title><title level="j" type="abbrev">Angewandte Chemie International Edition</title><idno type="ISSN">1433-7851</idno><idno type="eISSN">1521-3773</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2006-05-12">2006-05-12</date><biblScope unit="volume">45</biblScope><biblScope unit="issue">20</biblScope><biblScope unit="page" from="3269">3269</biblScope><biblScope unit="page" to="3272">3272</biblScope></imprint><idno type="ISSN">1433-7851</idno></series><idno type="istex">AAE17EA8B66D03FD4D5709DF736473D9E3DA342E</idno><idno type="DOI">10.1002/anie.200600338</idno><idno type="ArticleID">ANIE200600338</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1433-7851</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>aromaticity</term><term>iron</term><term>silicon</term><term>small ring systems</term><term>structure elucidation</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">All in the family: [(η4‐R4Si4)Fe(CO)3] 2 (R=SiMetBu2) represents a neutral silicon congener of a (cyclobutadiene)tricarbonyliron complex and was synthesized by the reaction of the dibromocyclotetrasilene R4Si4Br2 1 with Na2[Fe(CO)4]. The tetrasilacyclobutadiene ligand in 2 has stronger π‐donating properties than the cyclobutadiene ligand in the parent complex [(η4‐H4C4)Fe(CO)3].</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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