New N,N‐Diisopropylcarbamato Complexes of Ruthenium(II) as Catalytic Precursors for Olefin Hydrogenation
Identifieur interne : 002D29 ( Istex/Curation ); précédent : 002D28; suivant : 002D30New N,N‐Diisopropylcarbamato Complexes of Ruthenium(II) as Catalytic Precursors for Olefin Hydrogenation
Auteurs : Daniela Belli Dell'Amico [Italie] ; Fausto Calderazzo ; Ulli Englert [Allemagne] ; Luca Labella ; Fabio Marchetti ; Monica SpecosSource :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2004-10.
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Abstract
During the synthesis of [Ru(O2CNiPr2)2(PPh3)2] (1), the [RuCl2(PPh3)3]/NHiPr2/CO2 system produces the intermediates [NH2iPr2][Ru2Cl2(μ‐Cl)3(PPh3)4] (2) and [RuCl(O2CNiPr2)(PPh3)3] (3) which have been isolated and fully characterised. Compound 2 contains the dinuclear anionic triply chloride‐bridged ruthenium(II) species. Compound 3 is mononuclear, the octahedral ruthenium centre being coordinated to the bidentate carbamato ligand. The reactions of compounds 1 and 3 with dihydrogen have been studied at room temperature and atmospheric pressure with respect to their catalytic hydrogenation of 1‐octene. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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DOI: 10.1002/ejic.200400014
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Daniela Belli Dell'Amico<affiliation><mods:affiliation>Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: belli@dcci.unipi.it</mods:affiliation><country wicri:rule="url">Italie</country></affiliation><affiliation><mods:affiliation>Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation><affiliation><mods:affiliation>Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation><affiliation><mods:affiliation>Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation><affiliation><mods:affiliation>Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation>Le document en format XML
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Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: belli@dcci.unipi.it</mods:affiliation><country wicri:rule="url">Italie</country></affiliation></author><author><name sortKey="Calderazzo, Fausto" sort="Calderazzo, Fausto" uniqKey="Calderazzo F" first="Fausto" last="Calderazzo">Fausto Calderazzo</name><affiliation><mods:affiliation>Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56126 Pisa, Italy, Fax: (internat.) + 39‐050‐2219‐246</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 39‐050‐2219‐246</wicri:noCountry></affiliation></author><author><name sortKey="Englert, Ulli" sort="Englert, Ulli" uniqKey="Englert U" first="Ulli" last="Englert">Ulli Englert</name><affiliation wicri:level="1"><mods:affiliation>Institut 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J. Inorg. Chem.</title><idno type="ISSN">1434-1948</idno><idno type="eISSN">1099-0682</idno><imprint><publisher>WILEY‐VCH Verlag</publisher><pubPlace>Weinheim</pubPlace><date type="published" when="2004-10">2004-10</date><biblScope unit="volume">2004</biblScope><biblScope unit="issue">19</biblScope><biblScope unit="page" from="3938">3938</biblScope><biblScope unit="page" to="3945">3945</biblScope></imprint><idno type="ISSN">1434-1948</idno></series><idno type="istex">53C5F318B12589E77F6F0CA00823C3944CD81D8C</idno><idno type="DOI">10.1002/ejic.200400014</idno><idno type="ArticleID">EJIC200400014</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1434-1948</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Hydrogenation</term><term>N,N‐Dialkylcarbamato complexes</term><term>Ruthenium</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">During the synthesis of [Ru(O2CNiPr2)2(PPh3)2] (1), the [RuCl2(PPh3)3]/NHiPr2/CO2 system produces the intermediates [NH2iPr2][Ru2Cl2(μ‐Cl)3(PPh3)4] (2) and [RuCl(O2CNiPr2)(PPh3)3] (3) which have been isolated and fully characterised. Compound 2 contains the dinuclear anionic triply chloride‐bridged ruthenium(II) species. Compound 3 is mononuclear, the octahedral ruthenium centre being coordinated to the bidentate carbamato ligand. The reactions of compounds 1 and 3 with dihydrogen have been studied at room temperature and atmospheric pressure with respect to their catalytic hydrogenation of 1‐octene. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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