Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes†
Identifieur interne : 002707 ( Istex/Curation ); précédent : 002706; suivant : 002708Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes†
Auteurs : Chaoyang Dai ; Todd B. Marder ; Edward G. Robins ; Dmitri S. Yufit ; Judith A. K. Howard ; Todd B. Marder ; Andrew J. Scott ; William CleggSource :
- Chemical Communications [ 1359-7345 ] ; 1998.
Abstract
Reactions of [L2Rh(acac)] (L = alkene or phosphine) with B2cat3 yield the zwitterionic complexes [L2Rh(η6-catBcat)] and [(acac)Bcat] cleanly; [(dppm)Rh(η6-catBcat)], the X-ray structure of which is reported, is an excellent catalyst for the diboration of vinylarenes and unstrained internal alkenes cis- and trans-stilbene and trans-β-methylstyrene.
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DOI: 10.1039/a804710c
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<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes†</title><author wicri:is="90%"><name sortKey="Dai, Chaoyang" sort="Dai, Chaoyang" uniqKey="Dai C" first="Chaoyang" last="Dai">Chaoyang Dai</name></author><author wicri:is="90%"><name sortKey="B Marder, Todd" sort="B Marder, Todd" uniqKey="B Marder T" first="Todd" last="B. Marder">Todd B. Marder</name></author><author wicri:is="90%"><name sortKey="G Robins, Edward" sort="G Robins, Edward" uniqKey="G Robins E" first="Edward" last="G. Robins">Edward G. Robins</name></author><author wicri:is="90%"><name sortKey="S Yufit, Dmitri" sort="S Yufit, Dmitri" uniqKey="S Yufit D" first="Dmitri" last="S. Yufit">Dmitri S. Yufit</name></author><author wicri:is="90%"><name sortKey="A K Howard, Judith" sort="A K Howard, Judith" uniqKey="A K Howard J" first="Judith" last="A. K. Howard">Judith A. K. Howard</name></author><author wicri:is="90%"><name sortKey="B Marder, Todd" sort="B Marder, Todd" uniqKey="B Marder T" first="Todd" last="B. Marder">Todd B. Marder</name></author><author wicri:is="90%"><name sortKey="J Scott, Andrew" sort="J Scott, Andrew" uniqKey="J Scott A" first="Andrew" last="J. Scott">Andrew J. Scott</name></author><author wicri:is="90%"><name sortKey="Clegg, William" sort="Clegg, William" uniqKey="Clegg W" first="William" last="Clegg">William Clegg</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:E5403672F3CE834801493CB1DE86C6BE3CD3887C</idno><date when="1998" year="1998">1998</date><idno type="doi">10.1039/a804710c</idno><idno type="url">https://api.istex.fr/document/E5403672F3CE834801493CB1DE86C6BE3CD3887C/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">002707</idno><idno type="wicri:Area/Istex/Curation">002707</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes†</title><author wicri:is="90%"><name sortKey="Dai, Chaoyang" sort="Dai, Chaoyang" uniqKey="Dai C" first="Chaoyang" last="Dai">Chaoyang Dai</name></author><author wicri:is="90%"><name sortKey="B Marder, Todd" sort="B Marder, Todd" uniqKey="B Marder T" first="Todd" last="B. Marder">Todd B. Marder</name></author><author wicri:is="90%"><name sortKey="G Robins, Edward" sort="G Robins, Edward" uniqKey="G Robins E" first="Edward" last="G. Robins">Edward G. Robins</name></author><author wicri:is="90%"><name sortKey="S Yufit, Dmitri" sort="S Yufit, Dmitri" uniqKey="S Yufit D" first="Dmitri" last="S. Yufit">Dmitri S. Yufit</name></author><author wicri:is="90%"><name sortKey="A K Howard, Judith" sort="A K Howard, Judith" uniqKey="A K Howard J" first="Judith" last="A. K. Howard">Judith A. K. Howard</name></author><author wicri:is="90%"><name sortKey="B Marder, Todd" sort="B Marder, Todd" uniqKey="B Marder T" first="Todd" last="B. Marder">Todd B. Marder</name></author><author wicri:is="90%"><name sortKey="J Scott, Andrew" sort="J Scott, Andrew" uniqKey="J Scott A" first="Andrew" last="J. Scott">Andrew J. Scott</name></author><author wicri:is="90%"><name sortKey="Clegg, William" sort="Clegg, William" uniqKey="Clegg W" first="William" last="Clegg">William Clegg</name></author></analytic><monogr></monogr><series><title level="j">Chemical Communications</title><title level="j" type="abbrev">Chem. Commun.</title><idno type="ISSN">1359-7345</idno><idno type="eISSN">1364-548X</idno><imprint><publisher>The Royal Society of Chemistry.</publisher><date type="published" when="1998">1998</date><biblScope unit="volume">0</biblScope><biblScope unit="issue">18</biblScope><biblScope unit="page" from="1983">1983</biblScope><biblScope unit="page" to="1984">1984</biblScope></imprint><idno type="ISSN">1359-7345</idno></series><idno type="istex">E5403672F3CE834801493CB1DE86C6BE3CD3887C</idno><idno type="DOI">10.1039/a804710c</idno><idno type="ms-id">a804710c</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1359-7345</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">Reactions of [L2Rh(acac)] (L = alkene or phosphine) with B2cat3 yield the zwitterionic complexes [L2Rh(η6-catBcat)] and [(acac)Bcat] cleanly; [(dppm)Rh(η6-catBcat)], the X-ray structure of which is reported, is an excellent catalyst for the diboration of vinylarenes and unstrained internal alkenes cis- and trans-stilbene and trans-β-methylstyrene.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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