Assembly of Zinc Ions by the New ON2S2 Ligand BMIBIP
Identifieur interne : 001F23 ( Istex/Curation ); précédent : 001F22; suivant : 001F24Assembly of Zinc Ions by the New ON2S2 Ligand BMIBIP
Auteurs : Claas Sudbrake ; Heinrich Vahrenkamp [Allemagne]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2001-03.
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- topic : Zinc.
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Abstract
The new ON2S2 ligand bis(iminomethyl)‐2‐6‐bis(mercaptoisobutyl)‐4‐methylphenol (H3BMIBIP) has been synthesized from 2,6‐diformyl‐4‐methylphenol and 2‐mercaptoisobutylamine. Its reaction with diethylzinc in the presence of alcohols yields complexes of composition [(BMIBIP)Zn2(OR)] (R = CH3, C2H5 and CH2C6H4CF3). A structure determination of the trifluoromethylbenzylate compound has shown it to be a tetranuclear complex consisting of two (BMIBIP)Zn2 units linked by triply bridging alkoxide ligands to form a double norcubane with a Zn4O4S2 framework.
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DOI: 10.1002/1099-0682(200103)2001:3<751::AID-EJIC751>3.0.CO;2-2
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Claas Sudbrake<affiliation><mods:affiliation>Institut für Anorganische und Analytische Chemie der Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany, Fax: (internat.) + 49‐761/203‐6001</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 49‐761/203‐6001</wicri:noCountry></affiliation><affiliation><mods:affiliation>Institut für Anorganische und Analytische Chemie der Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany, Fax: (internat.) + 49‐761/203‐6001</mods:affiliation><wicri:noCountry code="subField">Fax: (internat.) + 49‐761/203‐6001</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>E-mail: vahrenka@uni‐freiburg.de</mods:affiliation><country wicri:rule="url">Allemagne</country></affiliation>Le document en format XML
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