η3‐Vinylborane Complexes of Platinum and Nickel: Borataallyl‐ and Alkyl/Borataalkene‐Like Coordination Modes
Identifieur interne : 001B81 ( Istex/Corpus ); précédent : 001B80; suivant : 001B82η3‐Vinylborane Complexes of Platinum and Nickel: Borataallyl‐ and Alkyl/Borataalkene‐Like Coordination Modes
Auteurs : Kristopher Kolpin ; David EmslieSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2010-04-01.
English descriptors
Abstract
Anyone for pi? The vinylborane PhHCCH‐B(C6F5)2 reacts with zero‐valent Group 10 transition‐metal precursors to form η3‐vinylborane complexes. The platinum tri‐tert‐butylphosphine complex exhibits an η3‐borataallyl‐like coordination mode whereas the nickel bis(triphenylphosphine) complex tends towards alkyl/borataalkene coordination.
Url:
DOI: 10.1002/anie.200906931
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Anyone for pi? The vinylborane PhHCCH‐B(C6F5)2 reacts with zero‐valent Group 10 transition‐metal precursors to form η3‐vinylborane complexes. The platinum tri‐tert‐butylphosphine complex exhibits an η3‐borataallyl‐like coordination mode whereas the nickel bis(triphenylphosphine) complex tends towards alkyl/borataalkene coordination.</div>
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‐Vinylborane Complexes of Platinum and Nickel: Borataallyl‐ and Alkyl/Borataalkene‐Like Coordination Modes<link href="#nss"></link>
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<abstractGroup><abstract type="graphical" xml:lang="en"><p><b>Anyone for pi?</b>
The vinylborane PhHCCH‐B(C<sub>6</sub>
F<sub>5</sub>
)<sub>2</sub>
reacts with zero‐valent Group 10 transition‐metal precursors to form η<sup>3</sup>
‐vinylborane complexes. The platinum tri‐<i>tert</i>
‐butylphosphine complex exhibits an η<sup>3</sup>
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<abstract type="graphical" lang="en">Anyone for pi? The vinylborane PhHCCH‐B(C6F5)2 reacts with zero‐valent Group 10 transition‐metal precursors to form η3‐vinylborane complexes. The platinum tri‐tert‐butylphosphine complex exhibits an η3‐borataallyl‐like coordination mode whereas the nickel bis(triphenylphosphine) complex tends towards alkyl/borataalkene coordination.</abstract>
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<topic>transition metals</topic>
</subject>
<relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title>
</titleInfo>
<titleInfo type="abbreviated"><title>Angewandte Chemie International Edition</title>
</titleInfo>
<genre type="journal">journal</genre>
<note type="content"> Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer‐reviewed, but not copy‐edited or typeset. They are made available as submitted by the authors.Supporting Info Item: miscellaneous_information - </note>
<subject><genre>article-category</genre>
<topic>Communication</topic>
</subject>
<identifier type="ISSN">1433-7851</identifier>
<identifier type="eISSN">1521-3773</identifier>
<identifier type="DOI">10.1002/(ISSN)1521-3773</identifier>
<identifier type="PublisherID">ANIE</identifier>
<part><date>2010</date>
<detail type="volume"><caption>vol.</caption>
<number>49</number>
</detail>
<detail type="issue"><caption>no.</caption>
<number>15</number>
</detail>
<extent unit="pages"><start>2716</start>
<end>2719</end>
<total>4</total>
</extent>
</part>
</relatedItem>
<identifier type="istex">4599F0E6116509F77B6D1AA52B258FEA7380BE25</identifier>
<identifier type="DOI">10.1002/anie.200906931</identifier>
<identifier type="ArticleID">ANIE200906931</identifier>
<accessCondition type="use and reproduction" contentType="copyright">Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition>
<recordInfo><recordContentSource>WILEY</recordContentSource>
<recordOrigin>WILEY‐VCH Verlag</recordOrigin>
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<serie></serie>
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