Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: a review.
Identifieur interne : 000168 ( PubMed/Curation ); précédent : 000167; suivant : 000169Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: a review.
Auteurs : M S More [Inde] ; P G Joshi [Inde] ; Y K Mishra [Allemagne] ; P K Khanna [Inde]Source :
- Materials today. Chemistry [ 2468-5194 ] ; 2019.
Abstract
Schiff bases are versatile organic compounds which are widely used and synthesized by condensation reaction of different amino compound with aldehydes or ketones known as imine. Schiff base ligands are considered as privileged ligands as they are simply synthesized by condensation. They show broad range of application in medicine, pharmacy, coordination chemistry, biological activities, industries, food packages, dyes, and polymer and also used as an O2 detector. Semicarbazone is an imine derivative which is derived from condensation of semicarbazide and suitable aldehyde and ketone. Imine ligand-containing transition metal complexes such as copper, zinc, and cadmium have shown to be excellent precursors for synthesis of metal or metal chalcogenide nanoparticles. In recent years, the researchers have attracted enormous attention toward Schiff bases, semicarbazones, thiosemicarbazones, and their metal complexes owing to numerous applications in pharmacology such as antiviral, antifungal, antimicrobial, antimalarial, antituberculosis, anticancer, anti-HIV, catalytic application in oxidation of organic compounds, and nanotechnology. In this review, we summarize the synthesis, structural, biological, and catalytic application of Schiff bases as well as their metal complexes.
DOI: 10.1016/j.mtchem.2019.100195
PubMed: 32289101
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411025</wicri:regionArea></affiliation></author><author><name sortKey="Joshi, P G" sort="Joshi, P G" uniqKey="Joshi P" first="P G" last="Joshi">P G Joshi</name><affiliation wicri:level="1"><nlm:affiliation>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025, India.</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025</wicri:regionArea></affiliation></author><author><name sortKey="Mishra, Y K" sort="Mishra, Y K" uniqKey="Mishra Y" first="Y K" last="Mishra">Y K Mishra</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Materials Science, Kiel University, Kaiserstrasse. 2, Kiel, 24143, Germany.</nlm:affiliation><country xml:lang="fr">Allemagne</country><wicri:regionArea>Institute for Materials Science, Kiel University, Kaiserstrasse. 2, Kiel, 24143</wicri:regionArea></affiliation></author><author><name sortKey="Khanna, P K" sort="Khanna, P K" uniqKey="Khanna P" first="P K" last="Khanna">P K Khanna</name><affiliation wicri:level="1"><nlm:affiliation>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025, India.</nlm:affiliation><country xml:lang="fr">Inde</country><wicri:regionArea>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025</wicri:regionArea></affiliation></author></analytic><series><title level="j">Materials today. Chemistry</title><idno type="eISSN">2468-5194</idno><imprint><date when="2019" type="published">2019</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Schiff bases are versatile organic compounds which are widely used and synthesized by condensation reaction of different amino compound with aldehydes or ketones known as imine. Schiff base ligands are considered as privileged ligands as they are simply synthesized by condensation. They show broad range of application in medicine, pharmacy, coordination chemistry, biological activities, industries, food packages, dyes, and polymer and also used as an O<sub>2</sub> detector. Semicarbazone is an imine derivative which is derived from condensation of semicarbazide and suitable aldehyde and ketone. Imine ligand-containing transition metal complexes such as copper, zinc, and cadmium have shown to be excellent precursors for synthesis of metal or metal chalcogenide nanoparticles. In recent years, the researchers have attracted enormous attention toward Schiff bases, semicarbazones, thiosemicarbazones, and their metal complexes owing to numerous applications in pharmacology such as antiviral, antifungal, antimicrobial, antimalarial, antituberculosis, anticancer, anti-HIV, catalytic application in oxidation of organic compounds, and nanotechnology. In this review, we summarize the synthesis, structural, biological, and catalytic application of Schiff bases as well as their metal complexes.</div></front></TEI><pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">32289101</PMID><DateRevised><Year>2020</Year><Month>04</Month><Day>16</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">2468-5194</ISSN><JournalIssue CitedMedium="Internet"><Volume>14</Volume><PubDate><Year>2019</Year><Month>Dec</Month></PubDate></JournalIssue><Title>Materials today. Chemistry</Title><ISOAbbreviation>Mater Today Chem</ISOAbbreviation></Journal><ArticleTitle>Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: a review.</ArticleTitle><Pagination><MedlinePgn>100195</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1016/j.mtchem.2019.100195</ELocationID><Abstract><AbstractText>Schiff bases are versatile organic compounds which are widely used and synthesized by condensation reaction of different amino compound with aldehydes or ketones known as imine. Schiff base ligands are considered as privileged ligands as they are simply synthesized by condensation. They show broad range of application in medicine, pharmacy, coordination chemistry, biological activities, industries, food packages, dyes, and polymer and also used as an O<sub>2</sub> detector. Semicarbazone is an imine derivative which is derived from condensation of semicarbazide and suitable aldehyde and ketone. Imine ligand-containing transition metal complexes such as copper, zinc, and cadmium have shown to be excellent precursors for synthesis of metal or metal chalcogenide nanoparticles. In recent years, the researchers have attracted enormous attention toward Schiff bases, semicarbazones, thiosemicarbazones, and their metal complexes owing to numerous applications in pharmacology such as antiviral, antifungal, antimicrobial, antimalarial, antituberculosis, anticancer, anti-HIV, catalytic application in oxidation of organic compounds, and nanotechnology. In this review, we summarize the synthesis, structural, biological, and catalytic application of Schiff bases as well as their metal complexes.</AbstractText><CopyrightInformation>© 2019 Elsevier Ltd. All rights reserved.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>More</LastName><ForeName>M S</ForeName><Initials>MS</Initials><AffiliationInfo><Affiliation>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025, India.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Joshi</LastName><ForeName>P G</ForeName><Initials>PG</Initials><AffiliationInfo><Affiliation>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025, India.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Mishra</LastName><ForeName>Y K</ForeName><Initials>YK</Initials><AffiliationInfo><Affiliation>Institute for Materials Science, Kiel University, Kaiserstrasse. 2, Kiel, 24143, Germany.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>NanoSYD, Mads Clausen Institute, University of Southern Denmark, Alsion 2, 6400, Sønderborg, Denmark.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Khanna</LastName><ForeName>P K</ForeName><Initials>PK</Initials><AffiliationInfo><Affiliation>Nanochemistry/QDs R & D Laboratory, Department of Applied Chemistry, Defence Institute of Advanced Technology (DIAT), Ministry of Defence, DRDO, Government of India, Girinagar, Pune, 411025, India.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2019</Year><Month>11</Month><Day>18</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Mater Today Chem</MedlineTA><NlmUniqueID>101726860</NlmUniqueID><ISSNLinking>2468-5194</ISSNLinking></MedlineJournalInfo><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">2,6-DAPBPTSC, 2,6-diacetylpyridine bis-4-phenyl-3-thiosemicarbazone</Keyword><Keyword MajorTopicYN="N">35-DTBP, 3,5-di-tert-butylphenol</Keyword><Keyword MajorTopicYN="N">3CLpro, 3C-like protease</Keyword><Keyword MajorTopicYN="N">ATNR, Amine terminated liquid natural rubber</Keyword><Keyword MajorTopicYN="N">ATT, 2-acetylthiophene thiosemicarbazone</Keyword><Keyword MajorTopicYN="N">BBPT, Biacetyl bis(4-phenyl-3-thiosemicarbazone)</Keyword><Keyword MajorTopicYN="N">BBTSC, Benzyloxybenzaldehyde thiosemicarbazone</Keyword><Keyword MajorTopicYN="N">BCG, Bacillus calmette-guérine</Keyword><Keyword MajorTopicYN="N">BDT, Benzyldithiosemicarbazone</Keyword><Keyword MajorTopicYN="N">BGPT, Bipyridyl glyoxal bis(4-phenyl-3-thiosemicarbazone)</Keyword><Keyword MajorTopicYN="N">BMTS, Biacetyl monothiosemicarbazone</Keyword><Keyword MajorTopicYN="N">Biological/biomedical activities</Keyword><Keyword MajorTopicYN="N">Bipy, 2,2-bipyridine</Keyword><Keyword MajorTopicYN="N">CT DNA, Calf thymus deoxyribonucleic acid</Keyword><Keyword MajorTopicYN="N">DAPY, 2,3-diamino-pyridine</Keyword><Keyword MajorTopicYN="N">DTBP, 2,6-di-tert-butylphenol</Keyword><Keyword MajorTopicYN="N">DTBQ, 2,6-di-tert-butyl-4,4′-benzoquinone</Keyword><Keyword MajorTopicYN="N">EAC, Enrichlish Ascitices Cells</Keyword><Keyword MajorTopicYN="N">HEK-293, Human Embryonic Kidney cells</Keyword><Keyword MajorTopicYN="N">HL-60, Human leukemia-60 cell line</Keyword><Keyword MajorTopicYN="N">HeLa, immortal cell lines</Keyword><Keyword MajorTopicYN="N">HepG2, Hepatic cellular carcinoma cells (Human liver cancer cell line)</Keyword><Keyword MajorTopicYN="N">IgG, Immunoglobin G</Keyword><Keyword MajorTopicYN="N">K B HCT-8, Human colon cancer cell line</Keyword><Keyword MajorTopicYN="N">M-IBDET, N-methylisatin-β-4′,4′-diethylthiosemicarbazone</Keyword><Keyword MajorTopicYN="N">MCF-7, Michigan Cancer Foundation-7</Keyword><Keyword MajorTopicYN="N">MCF7 cells, Michigan Cancer Foundation-7 (breast cancer cell line)</Keyword><Keyword MajorTopicYN="N">MHV, Mouse hepatitis virus</Keyword><Keyword MajorTopicYN="N">MLV, Moloney leukemia virus</Keyword><Keyword MajorTopicYN="N">MSOPD, N,N-bis(3-methylsalicylidene)-ortho-phenylenediamine</Keyword><Keyword MajorTopicYN="N">Metal complexes</Keyword><Keyword MajorTopicYN="N">NQSC, Naphthoquinone semicarbazone</Keyword><Keyword MajorTopicYN="N">NQTS, ortho-Naphthoquinone thiosemicarbazone</Keyword><Keyword MajorTopicYN="N">OLED, Organic light emitting diode</Keyword><Keyword MajorTopicYN="N">PAS, p-amino salicylic acid</Keyword><Keyword MajorTopicYN="N">PPTS, Picolinealdehyde-4-phenyl-3-thiosemicarbazone</Keyword><Keyword MajorTopicYN="N">Phen, 1,10-phenanthroline</Keyword><Keyword MajorTopicYN="N">SARS CoV, Severe Acute Respiratory Syndrome coronavirus</Keyword><Keyword MajorTopicYN="N">SARS, Severe acute respiratory syndrome</Keyword><Keyword MajorTopicYN="N">SB-HAG, Schiff bases of hydroxyamino guanidines</Keyword><Keyword MajorTopicYN="N">SK-MEL-30, Human Melanoma Cell Line</Keyword><Keyword MajorTopicYN="N">SK-OV-3 cells, Ovarian cancer cell line</Keyword><Keyword MajorTopicYN="N">SSB-HAG, salicylaldehyde Schiff bases of HAG</Keyword><Keyword MajorTopicYN="N">Schiff base</Keyword><Keyword MajorTopicYN="N">Semicarbazone</Keyword><Keyword MajorTopicYN="N">TCIDw, Tissue culture Infective Dose</Keyword><Keyword MajorTopicYN="N">TTBDQ, 3,5,3′,5′-tetra-tert-butyl-4,4′-diphenoquinone</Keyword><Keyword MajorTopicYN="N">VSV, vesicular stomatitis virus</Keyword><Keyword MajorTopicYN="N">scCO2, Super-critical carbon dioxide</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2019</Year><Month>04</Month><Day>15</Day></PubMedPubDate><PubMedPubDate 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