How accurately condoms are being used vary across populations and knowledge of the factors determining its proper use remains unclear. Knowledge of such differentials and determinants would aid in evaluating the contributions of condom use to HIV epidemic reduction. Baseline data from the Situationally Focused Individual HIV/AIDS intervention to promote HIV protective behavior among 2,213 Nigerian Military Personnel were analyzed. Using composite score of the six steps for the knowledge of condom use and modeling as the outcome variable, we examined educational status as a predictor variable, modeling with unconditional univariable and multivariable logistic regression. In the unadjusted logistic regression model, compared to those with less than high school education, those with high school and some college education were two times more likely to demonstrate knowledge of condom use and modeling, prevalence odds ratio, 2.32, 95% Confidence Interval (CI)=1.60-3.37. However, the statistically significant association failed to persist after adjustment for the relevant covariates, prevalence odds ratio, 1.62, 95% CI=0.78-3.38. This study is indicative of low knowledge of condom use and modeling among the Nigerian military personnel; as well as a direct correlation between education attainment and knowledge of condom use and modeling.