Salt effect on solutions of nonionic surfactants and its influence on the stability of polymerized microemulsions
Identifieur interne : 001248 ( Istex/Corpus ); précédent : 001247; suivant : 001249Salt effect on solutions of nonionic surfactants and its influence on the stability of polymerized microemulsions
Auteurs : Christine Holtzscherer ; Francoise CandauSource :
- Journal of Colloid And Interface Science [ 0021-9797 ] ; 1988.
Abstract
The effect of various salts on the cloud points of nonionic surfactant solutions has been studied by turbidimetry. The elevation or depression of cloud points can be discussed in terms of salting in or salting out, respectively. Assignment of cloud point shift values to the individual ions forming the electrolyte shows that the salting effects are mainly due to the prominent influence of the anions as compared to that of the cations. The salt effects are shown to affect the stability of inverse polyacrylamide microlatexes prepared by polymerization in nonionic microemulsions. Addition of electrolytes with high salting out efficiency, such as sodium acetate, induces the phase transition Winsor I → Winsor III. This allows the polymerization of monomers in bicontinuous microemulsions characterized by low interfacial tensions (⋍10−3 dyn cm−1), which subsequently leads to clear and stable inverse microlatexes.
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DOI: 10.1016/0021-9797(88)90058-6
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The elevation or depression of cloud points can be discussed in terms of salting in or salting out, respectively. Assignment of cloud point shift values to the individual ions forming the electrolyte shows that the salting effects are mainly due to the prominent influence of the anions as compared to that of the cations. The salt effects are shown to affect the stability of inverse polyacrylamide microlatexes prepared by polymerization in nonionic microemulsions. Addition of electrolytes with high salting out efficiency, such as sodium acetate, induces the phase transition Winsor I → Winsor III. 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The elevation or depression of cloud points can be discussed in terms of salting in or salting out, respectively. Assignment of cloud point shift values to the individual ions forming the electrolyte shows that the salting effects are mainly due to the prominent influence of the anions as compared to that of the cations. The salt effects are shown to affect the stability of inverse polyacrylamide microlatexes prepared by polymerization in nonionic microemulsions. Addition of electrolytes with high salting out efficiency, such as sodium acetate, induces the phase transition Winsor I → Winsor III. This allows the polymerization of monomers in bicontinuous microemulsions characterized by low interfacial tensions (⋍10−3 dyn cm−1), which subsequently leads to clear and stable inverse microlatexes.</abstract><qualityIndicators><score>6.656</score><pdfVersion>1.3</pdfVersion><pdfPageSize>504 x 720 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>918</abstractCharCount><pdfWordCount>6465</pdfWordCount><pdfCharCount>37783</pdfCharCount><pdfPageCount>14</pdfPageCount><abstractWordCount>138</abstractWordCount></qualityIndicators><title>Salt effect on solutions of nonionic surfactants and its influence on the stability of polymerized microemulsions</title><pii><json:string>0021-9797(88)90058-6</json:string></pii><refBibs><json:item><host><pages><first>32</first></pages><author></author><title>Polymerization and Polycondensation Processes: Adv. Chem. 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The elevation or depression of cloud points can be discussed in terms of salting in or salting out, respectively. Assignment of cloud point shift values to the individual ions forming the electrolyte shows that the salting effects are mainly due to the prominent influence of the anions as compared to that of the cations. The salt effects are shown to affect the stability of inverse polyacrylamide microlatexes prepared by polymerization in nonionic microemulsions. Addition of electrolytes with high salting out efficiency, such as sodium acetate, induces the phase transition Winsor I → Winsor III. 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The elevation or depression of cloud points can be discussed in terms of salting in or salting out, respectively. Assignment of cloud point shift values to the individual ions forming the electrolyte shows that the salting effects are mainly due to the prominent influence of the anions as compared to that of the cations. The salt effects are shown to affect the stability of inverse polyacrylamide microlatexes prepared by polymerization in nonionic microemulsions. Addition of electrolytes with high salting out efficiency, such as sodium acetate, induces the phase transition Winsor I → Winsor III. This allows the polymerization of monomers in bicontinuous microemulsions characterized by low interfacial tensions (⋍10<ce:sup>−3</ce:sup> dyn cm<ce:sup>−1</ce:sup>), which subsequently leads to clear and stable inverse microlatexes.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Salt effect on solutions of nonionic surfactants and its influence on the stability of polymerized microemulsions</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Salt effect on solutions of nonionic surfactants and its influence on the stability of polymerized microemulsions</title></titleInfo><name type="personal"><namePart type="given">Christine</namePart><namePart type="family">Holtzscherer</namePart><affiliation>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6, rue Boussingault, 67083 Strasbourg Cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Francoise</namePart><namePart type="family">Candau</namePart><affiliation>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6, rue Boussingault, 67083 Strasbourg Cedex, France</affiliation><description>To whom correspondence should be addressed.</description><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1988</dateIssued><copyrightDate encoding="w3cdtf">1988</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">The effect of various salts on the cloud points of nonionic surfactant solutions has been studied by turbidimetry. The elevation or depression of cloud points can be discussed in terms of salting in or salting out, respectively. Assignment of cloud point shift values to the individual ions forming the electrolyte shows that the salting effects are mainly due to the prominent influence of the anions as compared to that of the cations. The salt effects are shown to affect the stability of inverse polyacrylamide microlatexes prepared by polymerization in nonionic microemulsions. Addition of electrolytes with high salting out efficiency, such as sodium acetate, induces the phase transition Winsor I → Winsor III. This allows the polymerization of monomers in bicontinuous microemulsions characterized by low interfacial tensions (⋍10−3 dyn cm−1), which subsequently leads to clear and stable inverse microlatexes.</abstract><relatedItem type="host"><titleInfo><title>Journal of Colloid And Interface Science</title></titleInfo><titleInfo type="abbreviated"><title>YJCIS</title></titleInfo><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">198809</dateIssued></originInfo><identifier type="ISSN">0021-9797</identifier><identifier type="PII">S0021-9797(00)X0481-X</identifier><part><date>198809</date><detail type="volume"><number>125</number><caption>vol.</caption></detail><detail type="issue"><number>1</number><caption>no.</caption></detail><extent unit="issue pages"><start>1</start><end>364</end></extent><extent unit="pages"><start>97</start><end>110</end></extent></part></relatedItem><identifier type="istex">1F3E6FE8CE80EACFCA4AD2B5DA34200D22DCE47D</identifier><identifier type="DOI">10.1016/0021-9797(88)90058-6</identifier><identifier type="PII">0021-9797(88)90058-6</identifier><recordInfo><recordContentSource>ELSEVIER</recordContentSource></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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