Polymerization in microemulsions
Identifieur interne : 001075 ( Istex/Corpus ); précédent : 001074; suivant : 001076Polymerization in microemulsions
Auteurs : Pascale Buchert ; Françoise CandauSource :
- Journal of Colloid And Interface Science [ 0021-9797 ] ; 1990.
Abstract
The formulation of microemulsions containing methacryloyloxyethyltrimethylammonium chloride for purposes of polymerization has been investigated. By using cohesive energy ratio hydrophile-lipophite balance concepts, general rules of selection for a good chemical match between oils and nonionic surfactants have been established. The cationic water-soluble monomer plays an important role in the formulation, owing to its amphiphilic and electrolytic character, as confirmed by surface tension and turbidimetry experiments. As a cosurfactant, it enhances considerably the microemulsion domain and as an electrolyte, it salts-out the surfactant. These effects taken together control the structural properties of the microemulsions. The optimal conditions correspond to bicontinuous microemulsion which form in an HLB range (12–13) higher than would be expected in the balance of monomer.
Url:
DOI: 10.1016/0021-9797(90)90399-9
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By using cohesive energy ratio hydrophile-lipophite balance concepts, general rules of selection for a good chemical match between oils and nonionic surfactants have been established. The cationic water-soluble monomer plays an important role in the formulation, owing to its amphiphilic and electrolytic character, as confirmed by surface tension and turbidimetry experiments. As a cosurfactant, it enhances considerably the microemulsion domain and as an electrolyte, it salts-out the surfactant. These effects taken together control the structural properties of the microemulsions. The optimal conditions correspond to bicontinuous microemulsion which form in an HLB range (12–13) higher than would be expected in the balance of monomer.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>Pascale Buchert</name><affiliations><json:string>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</json:string></affiliations></json:item><json:item><name>Françoise Candau</name><affiliations><json:string>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</json:string></affiliations></json:item></author><language><json:string>eng</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>The formulation of microemulsions containing methacryloyloxyethyltrimethylammonium chloride for purposes of polymerization has been investigated. By using cohesive energy ratio hydrophile-lipophite balance concepts, general rules of selection for a good chemical match between oils and nonionic surfactants have been established. The cationic water-soluble monomer plays an important role in the formulation, owing to its amphiphilic and electrolytic character, as confirmed by surface tension and turbidimetry experiments. As a cosurfactant, it enhances considerably the microemulsion domain and as an electrolyte, it salts-out the surfactant. These effects taken together control the structural properties of the microemulsions. The optimal conditions correspond to bicontinuous microemulsion which form in an HLB range (12–13) higher than would be expected in the balance of monomer.</abstract><qualityIndicators><score>6.404</score><pdfVersion>1.3</pdfVersion><pdfPageSize>504 x 720 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>886</abstractCharCount><pdfWordCount>6733</pdfWordCount><pdfCharCount>36690</pdfCharCount><pdfPageCount>14</pdfPageCount><abstractWordCount>117</abstractWordCount></qualityIndicators><title>Polymerization in microemulsions</title><pii><json:string>0021-9797(90)90399-9</json:string></pii><refBibs><json:item><host><volume>114</volume><pages><first>398</first></pages><author></author><title>J. 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Phys.</title></host></json:item><json:item><host><author></author></host></json:item></refBibs><genre><json:string>research-article</json:string></genre><host><volume>136</volume><pii><json:string>S0021-9797(00)X0534-6</json:string></pii><pages><last>540</last><first>527</first></pages><issn><json:string>0021-9797</json:string></issn><issue>2</issue><genre><json:string>journal</json:string></genre><language><json:string>unknown</json:string></language><title>Journal of Colloid And Interface Science</title><publicationDate>1990</publicationDate></host><categories><wos><json:string>science</json:string><json:string>chemistry, physical</json:string></wos><scienceMetrix><json:string>natural sciences</json:string><json:string>physics & astronomy</json:string><json:string>chemical physics</json:string></scienceMetrix></categories><publicationDate>1990</publicationDate><copyrightDate>1990</copyrightDate><doi><json:string>10.1016/0021-9797(90)90399-9</json:string></doi><id>A3509BFC0DAC195C792DE3168403B3FF012C6358</id><score>0.13222766</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/A3509BFC0DAC195C792DE3168403B3FF012C6358/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/A3509BFC0DAC195C792DE3168403B3FF012C6358/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/A3509BFC0DAC195C792DE3168403B3FF012C6358/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a">Polymerization in microemulsions</title><title level="a" type="sub">I. Formulation and structural properties of microemulsions containing a cationic monomer</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>ELSEVIER</p></availability><date>1990</date></publicationStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a">Polymerization in microemulsions</title><title level="a" type="sub">I. Formulation and structural properties of microemulsions containing a cationic monomer</title><author xml:id="author-1"><persName><forename type="first">Pascale</forename><surname>Buchert</surname></persName><note type="biography">Present address: (Norsolor) ORKEM Group, B.P. 22, 60550 Verneuil-en Halatte (France).</note><affiliation>Present address: (Norsolor) ORKEM Group, B.P. 22, 60550 Verneuil-en Halatte (France).</affiliation><affiliation>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</affiliation></author><author xml:id="author-2"><persName><forename type="first">Françoise</forename><surname>Candau</surname></persName><affiliation>To whom correspondence should be addressed.</affiliation><affiliation>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</affiliation></author></analytic><monogr><title level="j">Journal of Colloid And Interface Science</title><title level="j" type="abbrev">YJCIS</title><idno type="pISSN">0021-9797</idno><idno type="PII">S0021-9797(00)X0534-6</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1990"></date><biblScope unit="volume">136</biblScope><biblScope unit="issue">2</biblScope><biblScope unit="page" from="527">527</biblScope><biblScope unit="page" to="540">540</biblScope></imprint></monogr><idno type="istex">A3509BFC0DAC195C792DE3168403B3FF012C6358</idno><idno type="DOI">10.1016/0021-9797(90)90399-9</idno><idno type="PII">0021-9797(90)90399-9</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1990</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>The formulation of microemulsions containing methacryloyloxyethyltrimethylammonium chloride for purposes of polymerization has been investigated. By using cohesive energy ratio hydrophile-lipophite balance concepts, general rules of selection for a good chemical match between oils and nonionic surfactants have been established. The cationic water-soluble monomer plays an important role in the formulation, owing to its amphiphilic and electrolytic character, as confirmed by surface tension and turbidimetry experiments. As a cosurfactant, it enhances considerably the microemulsion domain and as an electrolyte, it salts-out the surfactant. These effects taken together control the structural properties of the microemulsions. 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Formulation and structural properties of microemulsions containing a cationic monomer</ce:subtitle><ce:author-group><ce:author><ce:given-name>Pascale</ce:given-name><ce:surname>Buchert</ce:surname><ce:cross-ref refid="FN1"><ce:sup>1</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>Françoise</ce:given-name><ce:surname>Candau</ce:surname><ce:cross-ref refid="COR1"><ce:sup>2</ce:sup></ce:cross-ref></ce:author><ce:affiliation><ce:textfn>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</ce:textfn></ce:affiliation><ce:correspondence id="COR1"><ce:label>2</ce:label><ce:text>To whom correspondence should be addressed.</ce:text></ce:correspondence><ce:footnote id="FN1"><ce:label>1</ce:label><ce:note-para>Present address: (Norsolor) ORKEM Group, B.P. 22, 60550 Verneuil-en Halatte (France).</ce:note-para></ce:footnote></ce:author-group><ce:date-received day="27" month="6" year="1989"></ce:date-received><ce:date-accepted day="21" month="9" year="1989"></ce:date-accepted><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>The formulation of microemulsions containing methacryloyloxyethyltrimethylammonium chloride for purposes of polymerization has been investigated. By using cohesive energy ratio hydrophile-lipophite balance concepts, general rules of selection for a good chemical match between oils and nonionic surfactants have been established. The cationic water-soluble monomer plays an important role in the formulation, owing to its amphiphilic and electrolytic character, as confirmed by surface tension and turbidimetry experiments. As a cosurfactant, it enhances considerably the microemulsion domain and as an electrolyte, it salts-out the surfactant. These effects taken together control the structural properties of the microemulsions. The optimal conditions correspond to bicontinuous microemulsion which form in an HLB range (12–13) higher than would be expected in the balance of monomer.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Polymerization in microemulsions</title><subTitle>I. Formulation and structural properties of microemulsions containing a cationic monomer</subTitle></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Polymerization in microemulsions</title><subTitle>I. Formulation and structural properties of microemulsions containing a cationic monomer</subTitle></titleInfo><name type="personal"><namePart type="given">Pascale</namePart><namePart type="family">Buchert</namePart><affiliation>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</affiliation><description>Present address: (Norsolor) ORKEM Group, B.P. 22, 60550 Verneuil-en Halatte (France).</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Françoise</namePart><namePart type="family">Candau</namePart><affiliation>Institut Charles Sadron (CRM-EAHP) CNRS-ULP, 6 rue Boussingault, 67083 Strasbourg Cédex, France</affiliation><description>To whom correspondence should be addressed.</description><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1990</dateIssued><copyrightDate encoding="w3cdtf">1990</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">The formulation of microemulsions containing methacryloyloxyethyltrimethylammonium chloride for purposes of polymerization has been investigated. By using cohesive energy ratio hydrophile-lipophite balance concepts, general rules of selection for a good chemical match between oils and nonionic surfactants have been established. The cationic water-soluble monomer plays an important role in the formulation, owing to its amphiphilic and electrolytic character, as confirmed by surface tension and turbidimetry experiments. As a cosurfactant, it enhances considerably the microemulsion domain and as an electrolyte, it salts-out the surfactant. These effects taken together control the structural properties of the microemulsions. The optimal conditions correspond to bicontinuous microemulsion which form in an HLB range (12–13) higher than would be expected in the balance of monomer.</abstract><relatedItem type="host"><titleInfo><title>Journal of Colloid And Interface Science</title></titleInfo><titleInfo type="abbreviated"><title>YJCIS</title></titleInfo><genre type="journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">199005</dateIssued></originInfo><identifier type="ISSN">0021-9797</identifier><identifier type="PII">S0021-9797(00)X0534-6</identifier><part><date>199005</date><detail type="volume"><number>136</number><caption>vol.</caption></detail><detail type="issue"><number>2</number><caption>no.</caption></detail><extent unit="issue pages"><start>305</start><end>597</end></extent><extent unit="pages"><start>527</start><end>540</end></extent></part></relatedItem><identifier type="istex">A3509BFC0DAC195C792DE3168403B3FF012C6358</identifier><identifier type="DOI">10.1016/0021-9797(90)90399-9</identifier><identifier type="PII">0021-9797(90)90399-9</identifier><recordInfo><recordContentSource>ELSEVIER</recordContentSource></recordInfo></mods></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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