Bostrycin.
Identifieur interne : 002134 ( PubMed/Corpus ); précédent : 002133; suivant : 002135Bostrycin.
Auteurs : Shao-Yuan Chen ; Chao Huang ; Chu-Long Zhang ; Yu-Zhe Chen ; Fu-Cheng LinSource :
- Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2008.
Abstract
The title compound, C(16)H(16)O(8), is a potent nonspecific phyto-toxin. The crystal structure is the average of two tauto-mers, 5,6,7,9,10-penta-hydr-oxy-2-meth-oxy-7-methyl-1,4,5,6,7,8-hexa-hydro-anthracene-1,4-dione and 1,4,5,6,7-pentahydr-oxy-2-meth--oxy-7-methyl-5,6,7,8,9,10-hexa-hydro-anthracene-9,10-di-one. The cyclo-hexene rings in both tautomers display a half-chair conformation. An extensive O-H⋯O hydrogen-bonding network is present in the crystal structure.
DOI: 10.1107/S1600536808032030
PubMed: 21581081
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pubmed:21581081Le document en format XML
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<author><name sortKey="Huang, Chao" sort="Huang, Chao" uniqKey="Huang C" first="Chao" last="Huang">Chao Huang</name>
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<author><name sortKey="Zhang, Chu Long" sort="Zhang, Chu Long" uniqKey="Zhang C" first="Chu-Long" last="Zhang">Chu-Long Zhang</name>
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<author><name sortKey="Chen, Yu Zhe" sort="Chen, Yu Zhe" uniqKey="Chen Y" first="Yu-Zhe" last="Chen">Yu-Zhe Chen</name>
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<author><name sortKey="Chen, Yu Zhe" sort="Chen, Yu Zhe" uniqKey="Chen Y" first="Yu-Zhe" last="Chen">Yu-Zhe Chen</name>
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<front><div type="abstract" xml:lang="en">The title compound, C(16)H(16)O(8), is a potent nonspecific phyto-toxin. The crystal structure is the average of two tauto-mers, 5,6,7,9,10-penta-hydr-oxy-2-meth-oxy-7-methyl-1,4,5,6,7,8-hexa-hydro-anthracene-1,4-dione and 1,4,5,6,7-pentahydr-oxy-2-meth--oxy-7-methyl-5,6,7,8,9,10-hexa-hydro-anthracene-9,10-di-one. The cyclo-hexene rings in both tautomers display a half-chair conformation. An extensive O-H⋯O hydrogen-bonding network is present in the crystal structure.</div>
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<Abstract><AbstractText>The title compound, C(16)H(16)O(8), is a potent nonspecific phyto-toxin. The crystal structure is the average of two tauto-mers, 5,6,7,9,10-penta-hydr-oxy-2-meth-oxy-7-methyl-1,4,5,6,7,8-hexa-hydro-anthracene-1,4-dione and 1,4,5,6,7-pentahydr-oxy-2-meth--oxy-7-methyl-5,6,7,8,9,10-hexa-hydro-anthracene-9,10-di-one. The cyclo-hexene rings in both tautomers display a half-chair conformation. An extensive O-H⋯O hydrogen-bonding network is present in the crystal structure.</AbstractText>
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