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2-Acetyl-pyridinium 3-amino-2-chloro-pyridinium tetra-chloridocobaltate(II).

Identifieur interne : 002050 ( PubMed/Corpus ); précédent : 002049; suivant : 002051

2-Acetyl-pyridinium 3-amino-2-chloro-pyridinium tetra-chloridocobaltate(II).

Auteurs : Ariel Adamski ; Violetta Patroniak ; Maciej Kubicki

Source :

Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2009.

RBID : pubmed:21581781

Abstract

In the title complex, (C(5)H(6)ClN(2))(C(7)H(8)NO)[CoCl(4)], the Co(II) ions are tetra-hedrally coordinated. The crystal structure is built from hydrogen-bonded centrosymmetric tetra-mers of tetra-chloridocobaltate(II) dianions and 3-amino-2-chloro-pyridinium cations, additionally strengthened by significant π-π stacking of pyridinium rings [interplanar distance 3.389 (3) Å]. The tetra-mers are linked by N-H⋯Cl hydrogen bonds into chains; the second kind of cations, viz. 2-acetyl-pyridinium, are connected by N-H⋯Cl hydrogen bonds to both sides of the chain. The Co-Cl bond lengths in the dianion correlate with the number of hydrogen bonds accepted by the Cl atom. An intramolecular C-H⋯Cl interaction is also present.

DOI: 10.1107/S1600536809000713
PubMed: 21581781

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<front><div type="abstract" xml:lang="en">In the title complex, (C(5)H(6)ClN(2))(C(7)H(8)NO)[CoCl(4)], the Co(II) ions are tetra-hedrally coordinated. The crystal structure is built from hydrogen-bonded centrosymmetric tetra-mers of tetra-chloridocobaltate(II) dianions and 3-amino-2-chloro-pyridinium cations, additionally strengthened by significant π-π stacking of pyridinium rings [interplanar distance 3.389 (3) Å]. The tetra-mers are linked by N-H⋯Cl hydrogen bonds into chains; the second kind of cations, viz. 2-acetyl-pyridinium, are connected by N-H⋯Cl hydrogen bonds to both sides of the chain. The Co-Cl bond lengths in the dianion correlate with the number of hydrogen bonds accepted by the Cl atom. An intramolecular C-H⋯Cl interaction is also present.</div>
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<Abstract><AbstractText>In the title complex, (C(5)H(6)ClN(2))(C(7)H(8)NO)[CoCl(4)], the Co(II) ions are tetra-hedrally coordinated. The crystal structure is built from hydrogen-bonded centrosymmetric tetra-mers of tetra-chloridocobaltate(II) dianions and 3-amino-2-chloro-pyridinium cations, additionally strengthened by significant π-π stacking of pyridinium rings [interplanar distance 3.389 (3) Å]. The tetra-mers are linked by N-H⋯Cl hydrogen bonds into chains; the second kind of cations, viz. 2-acetyl-pyridinium, are connected by N-H⋯Cl hydrogen bonds to both sides of the chain. The Co-Cl bond lengths in the dianion correlate with the number of hydrogen bonds accepted by the Cl atom. An intramolecular C-H⋯Cl interaction is also present.</AbstractText>
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2-Acetyl-pyridinium 3-amino-2-chloro-pyridinium tetra-chloridocobaltate(II).

2-Acetyl-pyridinium 3-amino-2-chloro-pyridinium tetra-chloridocobaltate(II).

Source :

Abstract

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