Tetra-μ(2)-acetato-tetraaquadi-μ(3)-oxido-octaoxidotetrauranium(VI) methanol disolvate tetrahydrate.
Identifieur interne : 001E25 ( PubMed/Corpus ); précédent : 001E24; suivant : 001E26Tetra-μ(2)-acetato-tetraaquadi-μ(3)-oxido-octaoxidotetrauranium(VI) methanol disolvate tetrahydrate.
Auteurs : Hisham Sleem ; Paris Georghiou ; Louise N. DaweSource :
- Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2011.
Abstract
The centrosymmetric title tetra-mer, [U(4)(C(2)H(3)O(2))(4)O(10)(H(2)O)(4)]·2CH(4)O, has a near planar core [maximum deviation from the least squares plane of 0.294 (6) Å]. It consists of two hexa-gonal-bipyramidally coordinated U(VI) atoms connected via μ(2)-O (acetate) and μ(3)-O (oxide) bridges in the equatorial plane to two penta-gonal-bipyramidally coordinated U(VI) atoms. The equatorial plane of each U(VI) atom is completed by a bound water mol-ecule, while the axial positions are occupied by uranyl (UO(2))(2+) O atoms. Multiple O-H⋯O hydrogen bonds are present, including a lattice methanol mol-ecule bound to one of the penta-gonal bipyramidal uranyl O atoms, as well as two different C(1) (1)(6) chains orginating from a donor water mol-ecule, via a uranyl oxygen acceptor and an acetate acceptor on different, adjacent tetra-mers. Finally, the unit cell contains four U(VI) tetra-mers, all connected by hydrogen bonding, forming a supra-molecular R(4) (4)(24) ring.
DOI: 10.1107/S1600536811050549
PubMed: 22199642
Links to Exploration step
pubmed:22199642Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Tetra-μ(2)-acetato-tetraaquadi-μ(3)-oxido-octaoxidotetrauranium(VI) methanol disolvate tetrahydrate.</title>
<author><name sortKey="Sleem, Hisham" sort="Sleem, Hisham" uniqKey="Sleem H" first="Hisham" last="Sleem">Hisham Sleem</name>
</author>
<author><name sortKey="Georghiou, Paris" sort="Georghiou, Paris" uniqKey="Georghiou P" first="Paris" last="Georghiou">Paris Georghiou</name>
</author>
<author><name sortKey="Dawe, Louise N" sort="Dawe, Louise N" uniqKey="Dawe L" first="Louise N" last="Dawe">Louise N. Dawe</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2011">2011</date>
<idno type="RBID">pubmed:22199642</idno>
<idno type="pmid">22199642</idno>
<idno type="doi">10.1107/S1600536811050549</idno>
<idno type="wicri:Area/PubMed/Corpus">001E25</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001E25</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Tetra-μ(2)-acetato-tetraaquadi-μ(3)-oxido-octaoxidotetrauranium(VI) methanol disolvate tetrahydrate.</title>
<author><name sortKey="Sleem, Hisham" sort="Sleem, Hisham" uniqKey="Sleem H" first="Hisham" last="Sleem">Hisham Sleem</name>
</author>
<author><name sortKey="Georghiou, Paris" sort="Georghiou, Paris" uniqKey="Georghiou P" first="Paris" last="Georghiou">Paris Georghiou</name>
</author>
<author><name sortKey="Dawe, Louise N" sort="Dawe, Louise N" uniqKey="Dawe L" first="Louise N" last="Dawe">Louise N. Dawe</name>
</author>
</analytic>
<series><title level="j">Acta crystallographica. Section E, Structure reports online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2011" type="published">2011</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The centrosymmetric title tetra-mer, [U(4)(C(2)H(3)O(2))(4)O(10)(H(2)O)(4)]·2CH(4)O, has a near planar core [maximum deviation from the least squares plane of 0.294 (6) Å]. It consists of two hexa-gonal-bipyramidally coordinated U(VI) atoms connected via μ(2)-O (acetate) and μ(3)-O (oxide) bridges in the equatorial plane to two penta-gonal-bipyramidally coordinated U(VI) atoms. The equatorial plane of each U(VI) atom is completed by a bound water mol-ecule, while the axial positions are occupied by uranyl (UO(2))(2+) O atoms. Multiple O-H⋯O hydrogen bonds are present, including a lattice methanol mol-ecule bound to one of the penta-gonal bipyramidal uranyl O atoms, as well as two different C(1) (1)(6) chains orginating from a donor water mol-ecule, via a uranyl oxygen acceptor and an acetate acceptor on different, adjacent tetra-mers. Finally, the unit cell contains four U(VI) tetra-mers, all connected by hydrogen bonding, forming a supra-molecular R(4) (4)(24) ring.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">22199642</PMID>
<DateCompleted><Year>2012</Year>
<Month>10</Month>
<Day>02</Day>
</DateCompleted>
<DateRevised><Year>2018</Year>
<Month>11</Month>
<Day>13</Day>
</DateRevised>
<Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1600-5368</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>67</Volume>
<Issue>Pt 12</Issue>
<PubDate><Year>2011</Year>
<Month>Dec</Month>
<Day>01</Day>
</PubDate>
</JournalIssue>
<Title>Acta crystallographica. Section E, Structure reports online</Title>
<ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation>
</Journal>
<ArticleTitle>Tetra-μ(2)-acetato-tetraaquadi-μ(3)-oxido-octaoxidotetrauranium(VI) methanol disolvate tetrahydrate.</ArticleTitle>
<Pagination><MedlinePgn>m1880-1</MedlinePgn>
</Pagination>
<ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536811050549</ELocationID>
<Abstract><AbstractText>The centrosymmetric title tetra-mer, [U(4)(C(2)H(3)O(2))(4)O(10)(H(2)O)(4)]·2CH(4)O, has a near planar core [maximum deviation from the least squares plane of 0.294 (6) Å]. It consists of two hexa-gonal-bipyramidally coordinated U(VI) atoms connected via μ(2)-O (acetate) and μ(3)-O (oxide) bridges in the equatorial plane to two penta-gonal-bipyramidally coordinated U(VI) atoms. The equatorial plane of each U(VI) atom is completed by a bound water mol-ecule, while the axial positions are occupied by uranyl (UO(2))(2+) O atoms. Multiple O-H⋯O hydrogen bonds are present, including a lattice methanol mol-ecule bound to one of the penta-gonal bipyramidal uranyl O atoms, as well as two different C(1) (1)(6) chains orginating from a donor water mol-ecule, via a uranyl oxygen acceptor and an acetate acceptor on different, adjacent tetra-mers. Finally, the unit cell contains four U(VI) tetra-mers, all connected by hydrogen bonding, forming a supra-molecular R(4) (4)(24) ring.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Sleem</LastName>
<ForeName>Hisham</ForeName>
<Initials>H</Initials>
</Author>
<Author ValidYN="Y"><LastName>Georghiou</LastName>
<ForeName>Paris</ForeName>
<Initials>P</Initials>
</Author>
<Author ValidYN="Y"><LastName>Dawe</LastName>
<ForeName>Louise N</ForeName>
<Initials>LN</Initials>
</Author>
</AuthorList>
<Language>eng</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2011</Year>
<Month>11</Month>
<Day>30</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>United States</Country>
<MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA>
<NlmUniqueID>101089178</NlmUniqueID>
<ISSNLinking>1600-5368</ISSNLinking>
</MedlineJournalInfo>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2011</Year>
<Month>11</Month>
<Day>03</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="accepted"><Year>2011</Year>
<Month>11</Month>
<Day>24</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2011</Year>
<Month>12</Month>
<Day>27</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2011</Year>
<Month>12</Month>
<Day>27</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2011</Year>
<Month>12</Month>
<Day>27</Day>
<Hour>6</Hour>
<Minute>1</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>ppublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">22199642</ArticleId>
<ArticleId IdType="doi">10.1107/S1600536811050549</ArticleId>
<ArticleId IdType="pii">br2182</ArticleId>
<ArticleId IdType="pmc">PMC3238765</ArticleId>
</ArticleIdList>
<ReferenceList><Reference><Citation>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</Citation>
<ArticleIdList><ArticleId IdType="pubmed">18156677</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Dalton Trans. 2008 May 21;(19):2557-68</Citation>
<ArticleIdList><ArticleId IdType="pubmed">18443698</ArticleId>
</ArticleIdList>
</Reference>
</ReferenceList>
</PubmedData>
</pubmed>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/PubMed/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001E25 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd -nk 001E25 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Sante |area= MersV1 |flux= PubMed |étape= Corpus |type= RBID |clé= pubmed:22199642 |texte= Tetra-μ(2)-acetato-tetraaquadi-μ(3)-oxido-octaoxidotetrauranium(VI) methanol disolvate tetrahydrate. }}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/RBID.i -Sk "pubmed:22199642" \ | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd \ | NlmPubMed2Wicri -a MersV1
![]() | This area was generated with Dilib version V0.6.33. | ![]() |