MersV1, PubMed, Corpus, bibRecord, 001656

Synthèse et structure cristalline d'un matériau noir AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5.

Identifieur interne : 001656 ( PubMed/Corpus ); précédent : 001655; suivant : 001657

Synthèse et structure cristalline d'un matériau noir AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5.

Auteurs : Chahira Bouzidi ; Wafa Frigui ; Mohamed Faouzi Zid

Source :

Acta crystallographica. Section E, Crystallographic communications [ 2056-9890 ] ; 2015.

RBID : pubmed:25844193

Abstract

A new silver aluminium trimangan-ese penta-molybdate {silver(I) trimanganese(II) aluminium penta-kis-[tetra-oxidomolybdate(VI)]}, AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5, has been synthesized using solid-state methods. The structure is composed of M 2O10 dimers, M 3O14 (M = Mn, Al) trimers and MoO4 tetra-hedra sharing corners and forming three types of layers A, B and B'. The sequence of the constituting layers is A-BB'-A-BB', with B' obtained from B by inversion symmetry, forming a three-dimensional structure with large channels in which the positionally disordered and partially occupied Ag(+) ions reside. The Mn(III) and Al(III) atoms share the same site, M. AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5 is isotypic with the NaMg3 X(MoO4)5 (X = Al, In) family and with NaFe4(MoO4)5. A comparative structural description is provided between the structure of the title compound and those of related phases containing dimers, trimers and tetra-mers.

DOI: 10.1107/S2056989015003345
PubMed: 25844193

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<author><name sortKey="Bouzidi, Chahira" sort="Bouzidi, Chahira" uniqKey="Bouzidi C" first="Chahira" last="Bouzidi">Chahira Bouzidi</name>
<affiliation><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis, Tunisie.</nlm:affiliation>
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<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<affiliation><nlm:affiliation>Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis, Tunisie.</nlm:affiliation>
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<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
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<front><div type="abstract" xml:lang="en">A new silver aluminium trimangan-ese penta-molybdate {silver(I) trimanganese(II) aluminium penta-kis-[tetra-oxidomolybdate(VI)]}, AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5, has been synthesized using solid-state methods. The structure is composed of M 2O10 dimers, M 3O14 (M = Mn, Al) trimers and MoO4 tetra-hedra sharing corners and forming three types of layers A, B and B'. The sequence of the constituting layers is A-BB'-A-BB', with B' obtained from B by inversion symmetry, forming a three-dimensional structure with large channels in which the positionally disordered and partially occupied Ag(+) ions reside. The Mn(III) and Al(III) atoms share the same site, M. AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5 is isotypic with the NaMg3 X(MoO4)5 (X = Al, In) family and with NaFe4(MoO4)5. A comparative structural description is provided between the structure of the title compound and those of related phases containing dimers, trimers and tetra-mers. </div>
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<Title>Acta crystallographica. Section E, Crystallographic communications</Title>
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<ArticleTitle>Synthèse et structure cristalline d'un matériau noir AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5.</ArticleTitle>
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<Abstract><AbstractText>A new silver aluminium trimangan-ese penta-molybdate {silver(I) trimanganese(II) aluminium penta-kis-[tetra-oxidomolybdate(VI)]}, AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5, has been synthesized using solid-state methods. The structure is composed of M 2O10 dimers, M 3O14 (M = Mn, Al) trimers and MoO4 tetra-hedra sharing corners and forming three types of layers A, B and B'. The sequence of the constituting layers is A-BB'-A-BB', with B' obtained from B by inversion symmetry, forming a three-dimensional structure with large channels in which the positionally disordered and partially occupied Ag(+) ions reside. The Mn(III) and Al(III) atoms share the same site, M. AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5 is isotypic with the NaMg3 X(MoO4)5 (X = Al, In) family and with NaFe4(MoO4)5. A comparative structural description is provided between the structure of the title compound and those of related phases containing dimers, trimers and tetra-mers. </AbstractText>
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<ReferenceList><Reference><Citation>Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 14;69(Pt 9):i54-i55</Citation>
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<Reference><Citation>Acta Crystallogr B. 2003 Oct;59(Pt 5):611-6</Citation>
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<Reference><Citation>Acta Crystallogr C. 2006 Jan;62(Pt 1):i1-2</Citation>
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<Reference><Citation>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</Citation>
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<Reference><Citation>Acta Crystallogr B. 2009 Feb;65(Pt 1):29-35</Citation>
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Synthèse et structure cristalline d'un matériau noir AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5.

Synthèse et structure cristalline d'un matériau noir AgMn(II) 3(Mn(III) 0,26Al0,74)(MoO4)5.

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