Structural analysis of 2-iodo-benzamide and 2-iodo-N-phenyl-benzamide.
Identifieur interne : 000810 ( PubMed/Corpus ); précédent : 000809; suivant : 000811Structural analysis of 2-iodo-benzamide and 2-iodo-N-phenyl-benzamide.
Auteurs : Keshab M. Bairagi ; Vipin B S. Kumar ; Subhrajyoti Bhandary ; Katharigatta N. Venugopala ; Susanta K. NayakSource :
- Acta crystallographica. Section E, Crystallographic communications [ 2056-9890 ] ; 2018.
Abstract
The title compounds, 2-iodo-benzamide, C7H6INO (I), and 2-iodo-N-phenyl-benzamide, C13H10INO (II), were both synthesized from 2-iodo-benzoic acid. In the crystal structure of (I), N-H⋯O and hydrogen bonds form two sets of closed rings, generating dimers and tetra-mers. These combine with C-I⋯π(ring) halogen bonds to form sheets of mol-ecules in the bc plane. For (II), N-H⋯O hydrogen bonds form chains along the a-axis direction, while inversion-related C-I⋯π(ring) contacts supported by C-H⋯π(ring) interactions generate sheets of mol-ecules along the ab diagonal.
DOI: 10.1107/S2056989018010162
PubMed: 30116577
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pubmed:30116577Le document en format XML
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<author><name sortKey="Venugopala, Katharigatta N" sort="Venugopala, Katharigatta N" uniqKey="Venugopala K" first="Katharigatta N" last="Venugopala">Katharigatta N. Venugopala</name>
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<front><div type="abstract" xml:lang="en">The title compounds, 2-iodo-benzamide, C<sub>7</sub>
H<sub>6</sub>
INO (I), and 2-iodo-<i>N</i>
-phenyl-benzamide, C<sub>13</sub>
H<sub>10</sub>
INO (II), were both synthesized from 2-iodo-benzoic acid. In the crystal structure of (I), N-H⋯O and hydrogen bonds form two sets of closed rings, generating dimers and tetra-mers. These combine with C-I⋯π(ring) halogen bonds to form sheets of mol-ecules in the <i>bc</i>
plane. For (II), N-H⋯O hydrogen bonds form chains along the <i>a</i>
-axis direction, while inversion-related C-I⋯π(ring) contacts supported by C-H⋯π(ring) interactions generate sheets of mol-ecules along the <i>ab</i>
diagonal.</div>
</front>
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<Day>20</Day>
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<Title>Acta crystallographica. Section E, Crystallographic communications</Title>
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<ArticleTitle>Structural analysis of 2-iodo-benzamide and 2-iodo-<i>N</i>
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<Abstract><AbstractText>The title compounds, 2-iodo-benzamide, C<sub>7</sub>
H<sub>6</sub>
INO (I), and 2-iodo-<i>N</i>
-phenyl-benzamide, C<sub>13</sub>
H<sub>10</sub>
INO (II), were both synthesized from 2-iodo-benzoic acid. In the crystal structure of (I), N-H⋯O and hydrogen bonds form two sets of closed rings, generating dimers and tetra-mers. These combine with C-I⋯π(ring) halogen bonds to form sheets of mol-ecules in the <i>bc</i>
plane. For (II), N-H⋯O hydrogen bonds form chains along the <i>a</i>
-axis direction, while inversion-related C-I⋯π(ring) contacts supported by C-H⋯π(ring) interactions generate sheets of mol-ecules along the <i>ab</i>
diagonal.</AbstractText>
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<KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">C—I⋯π(ring) interactions</Keyword>
<Keyword MajorTopicYN="N">benzamide</Keyword>
<Keyword MajorTopicYN="N">crystal structure</Keyword>
<Keyword MajorTopicYN="N">dimer</Keyword>
<Keyword MajorTopicYN="N">hydrogen bonds</Keyword>
<Keyword MajorTopicYN="N">tetramer</Keyword>
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