Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.
Identifieur interne : 000579 ( PubMed/Corpus ); précédent : 000578; suivant : 000580Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.
Auteurs : Francis M. Gaitho ; Mesfin Tsige ; Genene T. Mola ; Giuseppe PellicaneSource :
- Polymers [ 2073-4360 ] ; 2018.
Abstract
We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, which resemble short (10-mers) and long (100-mers) chains, at different concentrations of the binary mixture. We clearly show how the concentration variable affects the enrichment of either of the two polymer species at the interface, and also how the chain length influences this process.
DOI: 10.3390/polym10030324
PubMed: 30966359
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<author><name sortKey="Gaitho, Francis M" sort="Gaitho, Francis M" uniqKey="Gaitho F" first="Francis M" last="Gaitho">Francis M. Gaitho</name>
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<author><name sortKey="Tsige, Mesfin" sort="Tsige, Mesfin" uniqKey="Tsige M" first="Mesfin" last="Tsige">Mesfin Tsige</name>
<affiliation><nlm:affiliation>Department of Polymer Science, University of Akron, Akron, OH 44325, USA. mtsige@uakron.edu.</nlm:affiliation>
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<author><name sortKey="Mola, Genene T" sort="Mola, Genene T" uniqKey="Mola G" first="Genene T" last="Mola">Genene T. Mola</name>
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<author><name sortKey="Pellicane, Giuseppe" sort="Pellicane, Giuseppe" uniqKey="Pellicane G" first="Giuseppe" last="Pellicane">Giuseppe Pellicane</name>
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<front><div type="abstract" xml:lang="en">We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, which resemble short (10-mers) and long (100-mers) chains, at different concentrations of the binary mixture. We clearly show how the concentration variable affects the enrichment of either of the two polymer species at the interface, and also how the chain length influences this process.</div>
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<Abstract><AbstractText>We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, which resemble short (10-mers) and long (100-mers) chains, at different concentrations of the binary mixture. We clearly show how the concentration variable affects the enrichment of either of the two polymer species at the interface, and also how the chain length influences this process.</AbstractText>
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<AffiliationInfo><Affiliation>National Institute of Theoretical Physics (NITheP) KZN Node, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. pellicane@ukzn.ac.za.</Affiliation>
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<CoiStatement>The authors declare no conflicts of interest.</CoiStatement>
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<ReferenceList><Reference><Citation>Phys Rev E Stat Nonlin Soft Matter Phys. 2003 Aug;68(2 Pt 1):021104</Citation>
<ArticleIdList><ArticleId IdType="pubmed">14524950</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Mater Sci Mater Med. 2003 Feb;14(2):127-35</Citation>
<ArticleIdList><ArticleId IdType="pubmed">15348484</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Langmuir. 2005 Jan 4;21(1):240-50</Citation>
<ArticleIdList><ArticleId IdType="pubmed">15620309</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Chem Phys. 2005 Feb 8;122(6):064904</Citation>
<ArticleIdList><ArticleId IdType="pubmed">15740405</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Philos Trans R Soc Lond B Biol Sci. 2009 Jul 27;364(1526):1977-84</Citation>
<ArticleIdList><ArticleId IdType="pubmed">19528050</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Nano Lett. 2011 Feb 9;11(2):561-7</Citation>
<ArticleIdList><ArticleId IdType="pubmed">21174440</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Chem Chem Phys. 2011 Mar 21;13(11):4928-34</Citation>
<ArticleIdList><ArticleId IdType="pubmed">21243167</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Chem Phys. 2011 May 28;134(20):204904</Citation>
<ArticleIdList><ArticleId IdType="pubmed">21639474</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2012 Jan 20;108(3):038301</Citation>
<ArticleIdList><ArticleId IdType="pubmed">22400790</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Chem Rev. 2014 Jan 22;114(2):1082-115</Citation>
<ArticleIdList><ArticleId IdType="pubmed">24125074</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>ACS Appl Mater Interfaces. 2014 Jun 25;6(12):9711-8</Citation>
<ArticleIdList><ArticleId IdType="pubmed">24830329</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Soft Matter. 2014 Aug 21;10(31):5836-41</Citation>
<ArticleIdList><ArticleId IdType="pubmed">24974935</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2014 Nov 21;113(21):218301</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25479524</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2014 Nov 28;113(22):225702</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25494077</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Chem Chem Phys. 2015 Feb 14;17(6):4714-23</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25589351</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Soft Matter. 2015 Aug 14;11(30):6018-28</Citation>
<ArticleIdList><ArticleId IdType="pubmed">26126895</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Sci Rep. 2016 Feb 01;6:20355</Citation>
<ArticleIdList><ArticleId IdType="pubmed">26829174</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev E. 2016 May;93(5):050501</Citation>
<ArticleIdList><ArticleId IdType="pubmed">27300817</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2017 Apr 21;118(16):167801</Citation>
<ArticleIdList><ArticleId IdType="pubmed">28474912</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev A Gen Phys. 1986 May;33(5):3628-3631</Citation>
<ArticleIdList><ArticleId IdType="pubmed">9897103</ArticleId>
</ArticleIdList>
</Reference>
</ReferenceList>
</PubmedData>
</pubmed>
</record>
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