MersV1, PubMed, Corpus, bibRecord, 000579

Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.

Identifieur interne : 000579 ( PubMed/Corpus ); précédent : 000578; suivant : 000580

Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.

Auteurs : Francis M. Gaitho ; Mesfin Tsige ; Genene T. Mola ; Giuseppe Pellicane

Source :

Polymers [ 2073-4360 ] ; 2018.

RBID : pubmed:30966359

Abstract

We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, which resemble short (10-mers) and long (100-mers) chains, at different concentrations of the binary mixture. We clearly show how the concentration variable affects the enrichment of either of the two polymer species at the interface, and also how the chain length influences this process.

DOI: 10.3390/polym10030324
PubMed: 30966359

Links to Exploration step

pubmed:30966359

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.</title>
<author><name sortKey="Gaitho, Francis M" sort="Gaitho, Francis M" uniqKey="Gaitho F" first="Francis M" last="Gaitho">Francis M. Gaitho</name>
<affiliation><nlm:affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. fgaitho@mmust.ac.ke.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Tsige, Mesfin" sort="Tsige, Mesfin" uniqKey="Tsige M" first="Mesfin" last="Tsige">Mesfin Tsige</name>
<affiliation><nlm:affiliation>Department of Polymer Science, University of Akron, Akron, OH 44325, USA. mtsige@uakron.edu.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Mola, Genene T" sort="Mola, Genene T" uniqKey="Mola G" first="Genene T" last="Mola">Genene T. Mola</name>
<affiliation><nlm:affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. mola@ukzn.ac.za.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Pellicane, Giuseppe" sort="Pellicane, Giuseppe" uniqKey="Pellicane G" first="Giuseppe" last="Pellicane">Giuseppe Pellicane</name>
<affiliation><nlm:affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. pellicane@ukzn.ac.za.</nlm:affiliation>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2018">2018</date>
<idno type="RBID">pubmed:30966359</idno>
<idno type="pmid">30966359</idno>
<idno type="doi">10.3390/polym10030324</idno>
<idno type="wicri:Area/PubMed/Corpus">000579</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000579</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.</title>
<author><name sortKey="Gaitho, Francis M" sort="Gaitho, Francis M" uniqKey="Gaitho F" first="Francis M" last="Gaitho">Francis M. Gaitho</name>
<affiliation><nlm:affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. fgaitho@mmust.ac.ke.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Tsige, Mesfin" sort="Tsige, Mesfin" uniqKey="Tsige M" first="Mesfin" last="Tsige">Mesfin Tsige</name>
<affiliation><nlm:affiliation>Department of Polymer Science, University of Akron, Akron, OH 44325, USA. mtsige@uakron.edu.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Mola, Genene T" sort="Mola, Genene T" uniqKey="Mola G" first="Genene T" last="Mola">Genene T. Mola</name>
<affiliation><nlm:affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. mola@ukzn.ac.za.</nlm:affiliation>
</affiliation>
</author>
<author><name sortKey="Pellicane, Giuseppe" sort="Pellicane, Giuseppe" uniqKey="Pellicane G" first="Giuseppe" last="Pellicane">Giuseppe Pellicane</name>
<affiliation><nlm:affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. pellicane@ukzn.ac.za.</nlm:affiliation>
</affiliation>
</author>
</analytic>
<series><title level="j">Polymers</title>
<idno type="eISSN">2073-4360</idno>
<imprint><date when="2018" type="published">2018</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, which resemble short (10-mers) and long (100-mers) chains, at different concentrations of the binary mixture. We clearly show how the concentration variable affects the enrichment of either of the two polymer species at the interface, and also how the chain length influences this process.</div>
</front>
</TEI>
<pubmed><MedlineCitation Status="PubMed-not-MEDLINE" Owner="NLM"><PMID Version="1">30966359</PMID>
<DateRevised><Year>2020</Year>
<Month>02</Month>
<Day>25</Day>
</DateRevised>
<Article PubModel="Electronic"><Journal><ISSN IssnType="Electronic">2073-4360</ISSN>
<JournalIssue CitedMedium="Internet"><Volume>10</Volume>
<Issue>3</Issue>
<PubDate><Year>2018</Year>
<Month>Mar</Month>
<Day>15</Day>
</PubDate>
</JournalIssue>
<Title>Polymers</Title>
<ISOAbbreviation>Polymers (Basel)</ISOAbbreviation>
</Journal>
<ArticleTitle>Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.</ArticleTitle>
<ELocationID EIdType="pii" ValidYN="Y">E324</ELocationID>
<ELocationID EIdType="doi" ValidYN="Y">10.3390/polym10030324</ELocationID>
<Abstract><AbstractText>We carry out extensive molecular dynamics simulations of thin films of bead-spring models of binary mixtures composed of cyclic and linear polymer chains. We study the equilibrium behavior of the polymer chains for two very different chain lengths, which resemble short (10-mers) and long (100-mers) chains, at different concentrations of the binary mixture. We clearly show how the concentration variable affects the enrichment of either of the two polymer species at the interface, and also how the chain length influences this process.</AbstractText>
</Abstract>
<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Gaitho</LastName>
<ForeName>Francis M</ForeName>
<Initials>FM</Initials>
<AffiliationInfo><Affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. fgaitho@mmust.ac.ke.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Tsige</LastName>
<ForeName>Mesfin</ForeName>
<Initials>M</Initials>
<Identifier Source="ORCID">0000-0002-7540-2050</Identifier>
<AffiliationInfo><Affiliation>Department of Polymer Science, University of Akron, Akron, OH 44325, USA. mtsige@uakron.edu.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Mola</LastName>
<ForeName>Genene T</ForeName>
<Initials>GT</Initials>
<Identifier Source="ORCID">0000-0002-1510-4641</Identifier>
<AffiliationInfo><Affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. mola@ukzn.ac.za.</Affiliation>
</AffiliationInfo>
</Author>
<Author ValidYN="Y"><LastName>Pellicane</LastName>
<ForeName>Giuseppe</ForeName>
<Initials>G</Initials>
<AffiliationInfo><Affiliation>School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. pellicane@ukzn.ac.za.</Affiliation>
</AffiliationInfo>
<AffiliationInfo><Affiliation>National Institute of Theoretical Physics (NITheP) KZN Node, Pietermaritzburg, Private Bag X01, Scottsville 3209, South Africa. pellicane@ukzn.ac.za.</Affiliation>
</AffiliationInfo>
</Author>
</AuthorList>
<Language>eng</Language>
<PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType>
</PublicationTypeList>
<ArticleDate DateType="Electronic"><Year>2018</Year>
<Month>03</Month>
<Day>15</Day>
</ArticleDate>
</Article>
<MedlineJournalInfo><Country>Switzerland</Country>
<MedlineTA>Polymers (Basel)</MedlineTA>
<NlmUniqueID>101545357</NlmUniqueID>
<ISSNLinking>2073-4360</ISSNLinking>
</MedlineJournalInfo>
<KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">concentration</Keyword>
<Keyword MajorTopicYN="N">interface</Keyword>
<Keyword MajorTopicYN="N">polymer melt</Keyword>
<Keyword MajorTopicYN="N">surface behavior</Keyword>
</KeywordList>
<CoiStatement>The authors declare no conflicts of interest.</CoiStatement>
</MedlineCitation>
<PubmedData><History><PubMedPubDate PubStatus="received"><Year>2017</Year>
<Month>12</Month>
<Day>31</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="revised"><Year>2018</Year>
<Month>02</Month>
<Day>21</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="accepted"><Year>2018</Year>
<Month>03</Month>
<Day>02</Day>
</PubMedPubDate>
<PubMedPubDate PubStatus="entrez"><Year>2019</Year>
<Month>4</Month>
<Day>11</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="pubmed"><Year>2019</Year>
<Month>4</Month>
<Day>11</Day>
<Hour>6</Hour>
<Minute>0</Minute>
</PubMedPubDate>
<PubMedPubDate PubStatus="medline"><Year>2019</Year>
<Month>4</Month>
<Day>11</Day>
<Hour>6</Hour>
<Minute>1</Minute>
</PubMedPubDate>
</History>
<PublicationStatus>epublish</PublicationStatus>
<ArticleIdList><ArticleId IdType="pubmed">30966359</ArticleId>
<ArticleId IdType="pii">polym10030324</ArticleId>
<ArticleId IdType="doi">10.3390/polym10030324</ArticleId>
<ArticleId IdType="pmc">PMC6414847</ArticleId>
</ArticleIdList>
<ReferenceList><Reference><Citation>Phys Rev E Stat Nonlin Soft Matter Phys. 2003 Aug;68(2 Pt 1):021104</Citation>
<ArticleIdList><ArticleId IdType="pubmed">14524950</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Mater Sci Mater Med. 2003 Feb;14(2):127-35</Citation>
<ArticleIdList><ArticleId IdType="pubmed">15348484</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Langmuir. 2005 Jan 4;21(1):240-50</Citation>
<ArticleIdList><ArticleId IdType="pubmed">15620309</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Chem Phys. 2005 Feb 8;122(6):064904</Citation>
<ArticleIdList><ArticleId IdType="pubmed">15740405</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Philos Trans R Soc Lond B Biol Sci. 2009 Jul 27;364(1526):1977-84</Citation>
<ArticleIdList><ArticleId IdType="pubmed">19528050</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Nano Lett. 2011 Feb 9;11(2):561-7</Citation>
<ArticleIdList><ArticleId IdType="pubmed">21174440</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Chem Chem Phys. 2011 Mar 21;13(11):4928-34</Citation>
<ArticleIdList><ArticleId IdType="pubmed">21243167</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>J Chem Phys. 2011 May 28;134(20):204904</Citation>
<ArticleIdList><ArticleId IdType="pubmed">21639474</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2012 Jan 20;108(3):038301</Citation>
<ArticleIdList><ArticleId IdType="pubmed">22400790</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Chem Rev. 2014 Jan 22;114(2):1082-115</Citation>
<ArticleIdList><ArticleId IdType="pubmed">24125074</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>ACS Appl Mater Interfaces. 2014 Jun 25;6(12):9711-8</Citation>
<ArticleIdList><ArticleId IdType="pubmed">24830329</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Soft Matter. 2014 Aug 21;10(31):5836-41</Citation>
<ArticleIdList><ArticleId IdType="pubmed">24974935</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2014 Nov 21;113(21):218301</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25479524</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2014 Nov 28;113(22):225702</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25494077</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Chem Chem Phys. 2015 Feb 14;17(6):4714-23</Citation>
<ArticleIdList><ArticleId IdType="pubmed">25589351</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Soft Matter. 2015 Aug 14;11(30):6018-28</Citation>
<ArticleIdList><ArticleId IdType="pubmed">26126895</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Sci Rep. 2016 Feb 01;6:20355</Citation>
<ArticleIdList><ArticleId IdType="pubmed">26829174</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev E. 2016 May;93(5):050501</Citation>
<ArticleIdList><ArticleId IdType="pubmed">27300817</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev Lett. 2017 Apr 21;118(16):167801</Citation>
<ArticleIdList><ArticleId IdType="pubmed">28474912</ArticleId>
</ArticleIdList>
</Reference>
<Reference><Citation>Phys Rev A Gen Phys. 1986 May;33(5):3628-3631</Citation>
<ArticleIdList><ArticleId IdType="pubmed">9897103</ArticleId>
</ArticleIdList>
</Reference>
</ReferenceList>
</PubmedData>
</pubmed>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/PubMed/Corpus

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000579 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd -nk 000579 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    MersV1
   |flux=    PubMed
   |étape=   Corpus
   |type=    RBID
   |clé=     pubmed:30966359
   |texte=   Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/PubMed/Corpus/RBID.i   -Sk "pubmed:30966359" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/PubMed/Corpus/biblio.hfd   \
       | NlmPubMed2Wicri -a MersV1

This area was generated with Dilib version V0.6.33.
Data generation: Mon Apr 20 23:26:43 2020. Site generation: Sat Mar 27 09:06:09 2021

	Serveur d'exploration MERS
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration MERS

Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.

Surface Segregation of Cyclic Chains in Binary Melts of Thin Polymer Films: The Influence of Constituent Concentration.

Source :

Abstract

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki