Phenoxazine Based Units- Synthesis, Photophysics and Electrochemistry
Identifieur interne : 000389 ( Pmc/Curation ); précédent : 000388; suivant : 000390Phenoxazine Based Units- Synthesis, Photophysics and Electrochemistry
Auteurs : Anna Nowakowska-Oleksy [Pologne] ; Jadwiga Sołoducho [Pologne] ; Joanna Cabaj [Pologne]Source :
- Journal of Fluorescence [ 1053-0509 ] ; 2010.
Abstract
A few new phenoxazine-based conjugated monomers were synthesized, characterized, and successfully used as semiconducting materials. The phenoxazine-based oligomers have low ionization potentials or high-lying HOMO levels (~4.7 eV), which were estimated from cyclic voltammetry. Conjugated oligomers offer good film—forming, mechanical and optical properties connected with their wide application. These results demonstrate that phenoxazine-based conjugated mers are a promising type of semiconducting and luminescent structures able to be used as thin films in organic electronics.
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DOI: 10.1007/s10895-010-0701-6
PubMed: 20625802
PubMed Central: 3032184
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The phenoxazine-based oligomers have low ionization potentials or high-lying HOMO levels (~4.7 eV), which were estimated from cyclic voltammetry. Conjugated oligomers offer good film—forming, mechanical and optical properties connected with their wide application. These results demonstrate that phenoxazine-based conjugated mers are a promising type of semiconducting and luminescent structures able to be used as thin films in organic electronics.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Newman, Cr" uniqKey="Newman C">CR Newman</name></author><author><name sortKey="Frisbie, Cd" uniqKey="Frisbie C">CD Frisbie</name></author><author><name sortKey="Silva Filho, Da" uniqKey="Silva Filho D">DA Silva Filho</name></author><author><name sortKey="Bredas, Jl" uniqKey="Bredas J">JL Bredas</name></author><author><name sortKey="Ewbank, Pc" uniqKey="Ewbank P">PC Ewbank</name></author><author><name sortKey="Mann, Kr" uniqKey="Mann K">KR Mann</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Kline, Rj" uniqKey="Kline R">RJ Kline</name></author><author><name sortKey="Mcgehee, Md" uniqKey="Mcgehee M">MD McGehee</name></author><author><name sortKey="Kadnikova, En" 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<front><journal-meta><journal-id journal-id-type="nlm-ta">J Fluoresc</journal-id><journal-title-group><journal-title>Journal of Fluorescence</journal-title></journal-title-group><issn pub-type="ppub">1053-0509</issn><issn pub-type="epub">1573-4994</issn><publisher><publisher-name>Springer US</publisher-name><publisher-loc>Boston</publisher-loc></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">20625802</article-id><article-id pub-id-type="pmc">3032184</article-id><article-id pub-id-type="publisher-id">701</article-id><article-id pub-id-type="doi">10.1007/s10895-010-0701-6</article-id><article-categories><subj-group subj-group-type="heading"><subject>Original Paper</subject></subj-group></article-categories><title-group><article-title>Phenoxazine Based Units- Synthesis, Photophysics and Electrochemistry</article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Nowakowska-Oleksy</surname><given-names>Anna</given-names></name><xref ref-type="aff" rid="Aff1"></xref></contrib><contrib contrib-type="author" corresp="yes"><name><surname>Sołoducho</surname><given-names>Jadwiga</given-names></name><address><email>jadwiga.soloducho@pwr.wroc.pl</email></address><xref ref-type="aff" rid="Aff1"></xref></contrib><contrib contrib-type="author"><name><surname>Cabaj</surname><given-names>Joanna</given-names></name><xref ref-type="aff" rid="Aff1"></xref></contrib><aff id="Aff1">Faculty of Chemistry, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland</aff></contrib-group><pub-date pub-type="epub"><day>13</day><month>7</month><year>2010</year></pub-date><pub-date pub-type="pmc-release"><day>13</day><month>7</month><year>2010</year></pub-date><pub-date pub-type="ppub"><month>1</month><year>2011</year></pub-date><volume>21</volume><issue>1</issue><fpage>169</fpage><lpage>178</lpage><history><date date-type="received"><day>14</day><month>4</month><year>2010</year></date><date date-type="accepted"><day>22</day><month>6</month><year>2010</year></date></history><permissions><copyright-statement>© The Author(s) 2010</copyright-statement></permissions><abstract><p>A few new phenoxazine-based conjugated monomers were synthesized, characterized, and successfully used as semiconducting materials. The phenoxazine-based oligomers have low ionization potentials or high-lying HOMO levels (~4.7 eV), which were estimated from cyclic voltammetry. Conjugated oligomers offer good film—forming, mechanical and optical properties connected with their wide application. These results demonstrate that phenoxazine-based conjugated mers are a promising type of semiconducting and luminescent structures able to be used as thin films in organic electronics.</p></abstract><kwd-group><title>Keywords</title><kwd>Phenoxazines</kwd><kwd>Stille condensation</kwd><kwd>Cyclic voltammetry</kwd><kwd>Conductivity</kwd><kwd>Luminescence</kwd><kwd>Atomic Force Microscopy (AFM)</kwd></kwd-group><custom-meta-group><custom-meta><meta-name>issue-copyright-statement</meta-name><meta-value>© Springer Science+Business Media, LLC 2011</meta-value></custom-meta></custom-meta-group></article-meta></front></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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