MersV1, Pmc, Curation, bibRecord, 000076

Synthèse et structure cristalline d’un matériau noir AgMnII3(MnIII0,26Al0,74)(MoO4)5

Identifieur interne : 000076 ( Pmc/Curation ); précédent : 000075; suivant : 000077

Synthèse et structure cristalline d’un matériau noir AgMnII3(MnIII0,26Al0,74)(MoO4)5

Auteurs : Chahira Bouzidi [Tunisie] ; Wafa Frigui [Tunisie] ; Mohamed Faouzi Zid [Tunisie]

Source :

Acta Crystallographica Section E: Crystallographic Communications [ 2056-9890 ] ; 2015.

RBID : PMC:4350738

Abstract

A new silver aluminium trimanganese pentamolybdate, AgMn^II₃(Mn^III_0,26Al_0,74)(MoO₄)₅, is composed of M₂O₁₀ dimers, M₃O₁₄ (M = Mn, Al) trimers and MoO₄ tetrahedra sharing corners and forming three types of layers. A comparative structural description is provided with the structures of related phases containing dimers, trimers and tetramers.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350738

DOI: 10.1107/S2056989015003345
PubMed: 25844193
PubMed Central: 4350738

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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Synthèse et structure cristalline d’un matériau noir AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
</title>
<author><name sortKey="Bouzidi, Chahira" sort="Bouzidi, Chahira" uniqKey="Bouzidi C" first="Chahira" last="Bouzidi">Chahira Bouzidi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
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<country xml:lang="fr">Tunisie</country>
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<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Synthèse et structure cristalline d’un matériau noir AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
</title>
<author><name sortKey="Bouzidi, Chahira" sort="Bouzidi, Chahira" uniqKey="Bouzidi C" first="Chahira" last="Bouzidi">Chahira Bouzidi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</author>
<author><name sortKey="Frigui, Wafa" sort="Frigui, Wafa" uniqKey="Frigui W" first="Wafa" last="Frigui">Wafa Frigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Zid, Mohamed Faouzi" sort="Zid, Mohamed Faouzi" uniqKey="Zid M" first="Mohamed Faouzi" last="Zid">Mohamed Faouzi Zid</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Crystallographic Communications</title>
<idno type="eISSN">2056-9890</idno>
<imprint><date when="2015">2015</date>
</imprint>
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<front><div type="abstract" xml:lang="en"><p>A new silver aluminium trimanganese pentamolybdate, AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
, is composed of <italic>M</italic>
<sub>2</sub>
O<sub>10</sub>
 dimers, <italic>M</italic>
<sub>3</sub>
O<sub>14</sub>
 (<italic>M</italic>
 = Mn, Al) trimers and MoO<sub>4</sub>
 tetrahedra sharing corners and forming three types of layers. A comparative structural description is provided with the structures of related phases containing dimers, trimers and tetramers.</p>
</div>
</front>
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</TEI>
<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
  <front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr E Crystallogr Commun</journal-id>
<journal-id journal-id-type="iso-abbrev">Acta Crystallogr E Crystallogr Commun</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Crystallographic Communications</journal-title>
</journal-title-group>
<issn pub-type="epub">2056-9890</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">25844193</article-id>
<article-id pub-id-type="pmc">4350738</article-id>
<article-id pub-id-type="publisher-id">ru2061</article-id>
<article-id pub-id-type="doi">10.1107/S2056989015003345</article-id>
<article-id pub-id-type="coden">ACSECI</article-id>
<article-id pub-id-type="pii">S2056989015003345</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Research Communications</subject>
</subj-group>
</article-categories>
<title-group><article-title>Synthèse et structure cristalline d’un matériau noir AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
</article-title>
<alt-title><italic>AgAl<sub>0.74</sub>
Mn<sub>3.26</sub>
Mo<sub>5</sub>
O<sub>20</sub>
</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Bouzidi</surname>
<given-names>Chahira</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Frigui</surname>
<given-names>Wafa</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Zid</surname>
<given-names>Mohamed Faouzi</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<aff id="a"><label>a</label>
Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis,<country>Tunisie</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>frigui.wafa@gmail.com</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>3</month>
<year>2015</year>
</pub-date>
<pub-date pub-type="epub"><day>21</day>
<month>2</month>
<year>2015</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>21</day>
<month>2</month>
<year>2015</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the 
 							. </pmc-comment>
      <volume>71</volume>
<issue>Pt 3</issue>
<issue-id pub-id-type="publisher-id">e150300</issue-id>
<fpage>299</fpage>
<lpage>304</lpage>
<history><date date-type="received"><day>27</day>
<month>1</month>
<year>2015</year>
</date>
<date date-type="accepted"><day>16</day>
<month>2</month>
<year>2015</year>
</date>
</history>
<permissions><copyright-statement>© Bouzidi et al. 2015</copyright-statement>
<copyright-year>2015</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits
unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S2056989015003345">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract abstract-type="toc"><p>A new silver aluminium trimanganese pentamolybdate, AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
, is composed of <italic>M</italic>
<sub>2</sub>
O<sub>10</sub>
 dimers, <italic>M</italic>
<sub>3</sub>
O<sub>14</sub>
 (<italic>M</italic>
 = Mn, Al) trimers and MoO<sub>4</sub>
 tetrahedra sharing corners and forming three types of layers. A comparative structural description is provided with the structures of related phases containing dimers, trimers and tetramers.</p>
</abstract>
<abstract><p>A new silver aluminium trimanganese pentamolybdate {silver(I) trimanganese(II) aluminium pentakis[tetraoxidomolybdate(VI)]}, AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
, has been synthesized using solid-state methods. The structure is composed of <italic>M</italic>
<sub>2</sub>
O<sub>10</sub>
 dimers, <italic>M</italic>
<sub>3</sub>
O<sub>14</sub>
 (<italic>M</italic>
 = Mn, Al) trimers and MoO<sub>4</sub>
 tetrahedra sharing corners and forming three types of layers <italic>A</italic>
, <italic>B</italic>
 and <italic>B</italic>
′. The sequence of the constituting layers is <italic>A</italic>
–<italic>BB</italic>
′–<italic>A</italic>
–<italic>BB</italic>
′, with <italic>B</italic>
′ obtained from <italic>B</italic>
 by inversion symmetry, forming a three-dimensional structure with large channels in which the positionally disordered and partially occupied Ag<sup>+</sup>
 ions reside. The Mn<sup>III</sup>
 and Al<sup>III</sup>
 atoms share the same site, <italic>M</italic>
. AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
 is isotypic with the NaMg<sub>3</sub>
<italic>X</italic>
(MoO<sub>4</sub>
)<sub>5</sub>
 (<italic>X</italic>
 = Al, In) family and with NaFe<sub>4</sub>
(MoO<sub>4</sub>
)<sub>5</sub>
. A comparative structural description is provided between the structure of the title compound and those of related phases containing dimers, trimers and tetramers.</p>
</abstract>
<kwd-group><kwd>crystal structure</kwd>
<kwd>aluminium</kwd>
<kwd>manganese</kwd>
<kwd>molybdate</kwd>
<kwd>solid-state methods</kwd>
<kwd>physicochemical properties</kwd>
</kwd-group>
</article-meta>
</front>
<floats-group><fig id="fig1" position="float"><label>Figure 1</label>
<caption><p>Représentation de l’unité asymétrique dans AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
. Les éllipsoïdes ont été définis avec 50% de probabilité. [Code de symétrie: (i) −<italic>x</italic>
 + 1, −<italic>y</italic>
 + 1, −<italic>z</italic>
 + 1; (ii) <italic>x</italic>
 + 1, <italic>y</italic>
, <italic>z</italic>
; (iii) <italic>x</italic>
, <italic>y</italic>
 + 1, <italic>z</italic>
; (iv) <italic>x</italic>
 − 1, <italic>y</italic>
, <italic>z</italic>
; (v) −<italic>x</italic>
 + 1, −<italic>y</italic>
 + 1, −<italic>z</italic>
 + 2; (vi) −<italic>x</italic>
 + 1, −<italic>y</italic>
 + 2, −<italic>z</italic>
 + 1; (vii) <italic>x</italic>
 + 1, <italic>y</italic>
 − 1, <italic>z</italic>
; (viii) <italic>x</italic>
, <italic>y</italic>
 − 1, <italic>z</italic>
; (ix) <italic>x</italic>
, <italic>y</italic>
, <italic>z</italic>
 + 1; (x) <italic>x</italic>
, <italic>y</italic>
 + 1, <italic>z</italic>
 + 1.]</p>
</caption>
<graphic xlink:href="e-71-00299-fig1"></graphic>
</fig>
<fig id="fig2" position="float"><label>Figure 2</label>
<caption><p>Projection de la structure de AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
, selon <italic>c</italic>
.</p>
</caption>
<graphic xlink:href="e-71-00299-fig2"></graphic>
</fig>
<fig id="fig3" position="float"><label>Figure 3</label>
<caption><p>Représentation d’une couche de type <italic>A</italic>
, selon [001], dans AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
.</p>
</caption>
<graphic xlink:href="e-71-00299-fig3"></graphic>
</fig>
<fig id="fig4" position="float"><label>Figure 4</label>
<caption><p>Représentation de couches de type <italic>B</italic>
, selon [001], dans AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
.</p>
</caption>
<graphic xlink:href="e-71-00299-fig4"></graphic>
</fig>
<fig id="fig5" position="float"><label>Figure 5</label>
<caption><p>Représentation des doubles couches <italic>BB</italic>
′, montrant leur jonction selon <italic>a</italic>
.</p>
</caption>
<graphic xlink:href="e-71-00299-fig5"></graphic>
</fig>
<fig id="fig6" position="float"><label>Figure 6</label>
<caption><p>Environnement du tétraèdre Mo<sub>2</sub>
O<sub>4</sub>
 mettant en évidence le groupement molybdyl (Mo—O<sub>L</sub>
).</p>
</caption>
<graphic xlink:href="e-71-00299-fig6"></graphic>
</fig>
<fig id="fig7" position="float"><label>Figure 7</label>
<caption><p>Représentation d’une couche, selon <italic>a</italic>
, dans Na<sub>2</sub>
FeMn<sub>2</sub>
(PO<sub>4</sub>
)<sub>3</sub>
 montrant la disposition des dimères <italic>M</italic>
<sub>2</sub>
O<sub>12</sub>
 (<italic>M</italic>
 = Mn, Fe).</p>
</caption>
<graphic xlink:href="e-71-00299-fig7"></graphic>
</fig>
<fig id="fig8" position="float"><label>Figure 8</label>
<caption><p>Projection de la structure de K<sub>2</sub>
Co<sub>2</sub>
Mo<sub>3</sub>
O<sub>12</sub>
, selon <italic>b</italic>
, mettant en évidence les tétramères Co<sub>4</sub>
O<sub>18</sub>
.</p>
</caption>
<graphic xlink:href="e-71-00299-fig8"></graphic>
</fig>
<fig id="fig9" position="float"><label>Figure 9</label>
<caption><p>Projection de la structure de RbMn<sub>6</sub>
(As<sub>2</sub>
O<sub>7</sub>
)<sub>2</sub>
(As<sub>3</sub>
O<sub>10</sub>
), montrant les chaînes d’octaèdres MnO<sub>6</sub>
 disposées en zigzag.</p>
</caption>
<graphic xlink:href="e-71-00299-fig9"></graphic>
</fig>
<fig id="fig10" position="float"><label>Figure 10</label>
<caption><p>Spectre d’analyse qualitative et morphologie d’un cristal de AgMn<sup>II</sup>
<sub>3</sub>
(Mn<sup>III</sup>
<sub>0,26</sub>
Al<sub>0,74</sub>
)(MoO<sub>4</sub>
)<sub>5</sub>
.</p>
</caption>
<graphic xlink:href="e-71-00299-fig10"></graphic>
</fig>
<table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Longueurs des liaisons slectionnes ()</title>
</caption>
<table frame="hsides" rules="groups"><tbody valign="top"><tr><td rowspan="1" colspan="1" align="left" valign="top">Mo1O14<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.729(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn2O14</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.084(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo1O18</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.737(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn2O13</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.096(3)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo1O12</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.747(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn2O1</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.121(3)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo1O20</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.796(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn2O20</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.148(3)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo2O6<sup>ii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.717(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn2O9</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.164(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo2O19</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.749(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn3O4</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.037(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo2O15<sup>iii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.758(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn3O17</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.043(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo2O9</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.819(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn3O19<sup>ix</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.079(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo3O17<sup>iv</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.737(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn3O10</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.105(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo3O10<sup>v</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.748(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn3O16<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.126(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo3O3<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.751(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn3O16<sup>x</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.160(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo3O16<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.795(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn4O3</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.985(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo4O4</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.732(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn4O5<sup>ii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.016(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo4O5<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.744(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn4O1</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.035(3)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo4O2<sup>vi</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.765(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn4O15</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.036(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo4O8<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.792(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn4O8</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.068(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo5O11<sup>vii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.721(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mn4O9</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.131(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo5O7</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.721(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag1O8</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.242(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo5O13<sup>viii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.781(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag1O2</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.260(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mo5O1</td>
<td rowspan="1" colspan="1" align="char" valign="top">1.808(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag1O6</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.275(4)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn1O12<sup>iii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.094(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag2O6</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.255(9)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn1O11</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.114(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag2O8</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.388(13)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn1O20</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.150(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag2O2</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.514(12)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn1O7<sup>i</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.158(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag3O6</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.245(5)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn1O2</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.161(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag3O8</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.519(5)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn1O13</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.188(3)</td>
<td rowspan="1" colspan="1" align="left" valign="top">Ag3O19</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.539(5)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Mn2O18<sup>ii</sup>
</td>
<td rowspan="1" colspan="1" align="char" valign="top">2.059(4)</td>
<td rowspan="1" colspan="1" align="left" valign="top"> </td>
<td rowspan="1" colspan="1" align="char" valign="top"> </td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-71-00299-efi1.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ii) <inline-formula><inline-graphic xlink:href="e-71-00299-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iii) <inline-formula><inline-graphic xlink:href="e-71-00299-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iv) <inline-formula><inline-graphic xlink:href="e-71-00299-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (v) <inline-formula><inline-graphic xlink:href="e-71-00299-efi5.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (vi) <inline-formula><inline-graphic xlink:href="e-71-00299-efi6.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (vii) <inline-formula><inline-graphic xlink:href="e-71-00299-efi7.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (viii) <inline-formula><inline-graphic xlink:href="e-71-00299-efi8.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ix) <inline-formula><inline-graphic xlink:href="e-71-00299-efi9.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (x) <inline-formula><inline-graphic xlink:href="e-71-00299-efi10.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ix) <inline-formula><inline-graphic xlink:href="e-71-00299-efi9.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (x) <inline-formula><inline-graphic xlink:href="e-71-00299-efi12.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
<table-wrap id="table2" position="float"><label>Table 2</label>
<caption><title>Dtails exprimentaux</title>
</caption>
<table frame="hsides" rules="groups"><tbody valign="top"><tr><td rowspan="1" colspan="2" align="left" valign="top">Donnes crystallines</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Formule chimique</td>
<td rowspan="1" colspan="1" align="left" valign="top">AgAl<sub>0.74</sub>
Mn<sub>3.26</sub>
Mo<sub>5</sub>
O<sub>20</sub>
</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>M</italic>
<sub>r</sub>
</td>
<td rowspan="1" colspan="1" align="left" valign="top">1106.64</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Systme cristallin, groupe d’espace</td>
<td rowspan="1" colspan="1" align="left" valign="top">Triclinique, <italic>P</italic>
<inline-formula><inline-graphic xlink:href="e-71-00299-efi13.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Temprature (K)</td>
<td rowspan="1" colspan="1" align="left" valign="top">298</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>a</italic>
, <italic>b</italic>
, <italic>c</italic>
 ()</td>
<td rowspan="1" colspan="1" align="left" valign="top">6.9596(6), 7.0326(7), 17.909(6)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">, , ()</td>
<td rowspan="1" colspan="1" align="left" valign="top">87.654(6), 87.442(6), 79.299(7)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>V</italic>
 (<sup>3</sup>
)</td>
<td rowspan="1" colspan="1" align="left" valign="top">860.0(3)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>Z</italic>
</td>
<td rowspan="1" colspan="1" align="left" valign="top">2</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Type de rayonnement</td>
<td rowspan="1" colspan="1" align="left" valign="top">Mo <italic>K</italic>
</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"> (mm<sup>1</sup>
)</td>
<td rowspan="1" colspan="1" align="left" valign="top">7.08</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Taille des cristaux (mm)</td>
<td rowspan="1" colspan="1" align="left" valign="top">0.28 0.21 0.21</td>
</tr>
<tr><td rowspan="1" colspan="2" align="left" valign="top"> </td>
</tr>
<tr><td rowspan="1" colspan="2" align="left" valign="top">Collection de donnes</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Diffractomtre</td>
<td rowspan="1" colspan="1" align="left" valign="top">EnrafNonius CAD-4</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Correction d’absorption</td>
<td rowspan="1" colspan="1" align="left" valign="top"> scan (North <italic>et al.</italic>
, 1968<xref ref-type="bibr" rid="bb20"> ▸</xref>
)</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>T</italic>
<sub>min</sub>
, <italic>T</italic>
<sub>max</sub>
</td>
<td rowspan="1" colspan="1" align="left" valign="top">0.153, 0.263</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Nombre de rflexions mesures, indpendantes et observes [<italic>I</italic>
 > 2(<italic>I</italic>
)]</td>
<td rowspan="1" colspan="1" align="left" valign="top">5479, 3736, 3470</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>R</italic>
<sub>int</sub>
</td>
<td rowspan="1" colspan="1" align="left" valign="top">0.015</td>
</tr>
<tr><td rowspan="1" colspan="2" align="left" valign="top"> </td>
</tr>
<tr><td rowspan="1" colspan="2" align="left" valign="top">Affinement</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><italic>R</italic>
[<italic>F</italic>
<sup>2</sup>
 > 2(<italic>F</italic>
<sup>2</sup>
)], <italic>wR</italic>
(<italic>F</italic>
<sup>2</sup>
), <italic>S</italic>
</td>
<td rowspan="1" colspan="1" align="left" valign="top">0.025, 0.064, 1.23</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Nombre de rflexions</td>
<td rowspan="1" colspan="1" align="left" valign="top">3736</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Nombre de paramtres</td>
<td rowspan="1" colspan="1" align="left" valign="top">291</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top">Nombre de restraints</td>
<td rowspan="1" colspan="1" align="left" valign="top">1</td>
</tr>
<tr><td rowspan="1" colspan="1" align="left" valign="top"><sub>max</sub>
, <sub>min</sub>
 (e <sup>3</sup>
)</td>
<td rowspan="1" colspan="1" align="left" valign="top">1.00, 1.06</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Programmes informatiques: <italic>CAD-4 EXPRESS</italic>
 (Duisenberg, 1992<xref ref-type="bibr" rid="bb7"> ▸</xref>
; Macek Yordanov, 1992<xref ref-type="bibr" rid="bb17"> ▸</xref>
), <italic>XCAD4</italic>
 (Harms Wocadlo, 1995<xref ref-type="bibr" rid="bb11"> ▸</xref>
), <italic>SHELXS97</italic>
 et <italic>SHELXL97</italic>
 (Sheldrick, 2008<xref ref-type="bibr" rid="bb24"> ▸</xref>
), <italic>DIAMOND</italic>
 (Brandenburg Putz, 2001<xref ref-type="bibr" rid="bb4"> ▸</xref>
) et <italic>WinGX</italic>
 (Farrugia, 2012<xref ref-type="bibr" rid="bb10"> ▸</xref>
).</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
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Synthèse et structure cristalline d’un matériau noir AgMnII3(MnIII0,26Al0,74)(MoO4)5

Synthèse et structure cristalline d’un matériau noir AgMnII3(MnIII0,26Al0,74)(MoO4)5

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