MersV1, Pmc, Checkpoint, bibRecord, 001402

Bostrycin

Identifieur interne : 001402 ( Pmc/Checkpoint ); précédent : 001401; suivant : 001403

Bostrycin

Auteurs : Shao-Yuan Chen [République populaire de Chine] ; Chao Huang [République populaire de Chine] ; Chu-Long Zhang [République populaire de Chine] ; Yu-Zhe Chen [République populaire de Chine] ; Fu-Cheng Lin [République populaire de Chine]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2008.

RBID : PMC:2959567

Abstract

The title compound, C₁₆H₁₆O₈, is a potent nonspecific phytotoxin. The crystal structure is the average of two tautomers, 5,6,7,9,10-pentahydroxy-2-methoxy-7-methyl-1,4,5,6,7,8-hexahydroanthracene-1,4-dione and 1,4,5,6,7-pentahydroxy-2-methoxy-7-methyl-5,6,7,8,9,10-hexahydroanthracene-9,10-dione. The cyclohexene rings in both tautomers display a half-chair conformation. An extensive O—H⋯O hydrogen-bonding network is present in the crystal structure.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959567

DOI: 10.1107/S1600536808032030
PubMed: 21581081
PubMed Central: 2959567

Affiliations:

République populaire de Chine

Links toward previous steps (curation, corpus...)

to stream Pmc, to step Corpus: 000A07
to stream Pmc, to step Curation: 000A07

Links to Exploration step

PMC:2959567

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bostrycin</title>
<author><name sortKey="Chen, Shao Yuan" sort="Chen, Shao Yuan" uniqKey="Chen S" first="Shao-Yuan" last="Chen">Shao-Yuan Chen</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Huang, Chao" sort="Huang, Chao" uniqKey="Huang C" first="Chao" last="Huang">Chao Huang</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Zhang, Chu Long" sort="Zhang, Chu Long" uniqKey="Zhang C" first="Chu-Long" last="Zhang">Chu-Long Zhang</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Chen, Yu Zhe" sort="Chen, Yu Zhe" uniqKey="Chen Y" first="Yu-Zhe" last="Chen">Yu-Zhe Chen</name>
<affiliation wicri:level="1"><nlm:aff id="b">College of Pharmaceutical Sicence, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lin, Fu Cheng" sort="Lin, Fu Cheng" uniqKey="Lin F" first="Fu-Cheng" last="Lin">Fu-Cheng Lin</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">21581081</idno>
<idno type="pmc">2959567</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959567</idno>
<idno type="RBID">PMC:2959567</idno>
<idno type="doi">10.1107/S1600536808032030</idno>
<date when="2008">2008</date>
<idno type="wicri:Area/Pmc/Corpus">000A07</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000A07</idno>
<idno type="wicri:Area/Pmc/Curation">000A07</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000A07</idno>
<idno type="wicri:Area/Pmc/Checkpoint">001402</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001402</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bostrycin</title>
<author><name sortKey="Chen, Shao Yuan" sort="Chen, Shao Yuan" uniqKey="Chen S" first="Shao-Yuan" last="Chen">Shao-Yuan Chen</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Huang, Chao" sort="Huang, Chao" uniqKey="Huang C" first="Chao" last="Huang">Chao Huang</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Zhang, Chu Long" sort="Zhang, Chu Long" uniqKey="Zhang C" first="Chu-Long" last="Zhang">Chu-Long Zhang</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Chen, Yu Zhe" sort="Chen, Yu Zhe" uniqKey="Chen Y" first="Yu-Zhe" last="Chen">Yu-Zhe Chen</name>
<affiliation wicri:level="1"><nlm:aff id="b">College of Pharmaceutical Sicence, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Lin, Fu Cheng" sort="Lin, Fu Cheng" uniqKey="Lin F" first="Fu-Cheng" last="Lin">Fu-Cheng Lin</name>
<affiliation wicri:level="1"><nlm:aff id="a">State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2008">2008</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>The title compound, C<sub>16</sub>
H<sub>16</sub>
O<sub>8</sub>
, is a potent nonspecific phytotoxin. The crystal structure is the average of two tautomers, 5,6,7,9,10-pentahydroxy-2-methoxy-7-methyl-1,4,5,6,7,8-hexahydroanthracene-1,4-dione and 1,4,5,6,7-pentahydroxy-2-methoxy-7-methyl-5,6,7,8,9,10-hexahydroanthracene-9,10-dione. The cyclohexene rings in both tautomers display a half-chair conformation. An extensive O—H⋯O hydrogen-bonding network is present in the crystal structure.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
  <front><journal-meta><journal-id journal-id-type="nlm-ta">Acta Crystallogr Sect E Struct Rep Online</journal-id>
<journal-id journal-id-type="publisher-id">Acta Cryst. E</journal-id>
<journal-title-group><journal-title>Acta Crystallographica Section E: Structure Reports Online</journal-title>
</journal-title-group>
<issn pub-type="epub">1600-5368</issn>
<publisher><publisher-name>International Union of Crystallography</publisher-name>
</publisher>
</journal-meta>
<article-meta><article-id pub-id-type="pmid">21581081</article-id>
<article-id pub-id-type="pmc">2959567</article-id>
<article-id pub-id-type="publisher-id">xu2453</article-id>
<article-id pub-id-type="doi">10.1107/S1600536808032030</article-id>
<article-id pub-id-type="coden">ACSEBH</article-id>
<article-id pub-id-type="pii">S1600536808032030</article-id>
<article-categories><subj-group subj-group-type="heading"><subject>Organic Papers</subject>
</subj-group>
</article-categories>
<title-group><article-title>Bostrycin</article-title>
<alt-title><italic>C<sub>16</sub>
H<sub>16</sub>
O<sub>8</sub>
</italic>
</alt-title>
</title-group>
<contrib-group><contrib contrib-type="author"><name><surname>Chen</surname>
<given-names>Shao-Yuan</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
<xref ref-type="corresp" rid="cor">*</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Huang</surname>
<given-names>Chao</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Zhang</surname>
<given-names>Chu-Long</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Chen</surname>
<given-names>Yu-Zhe</given-names>
</name>
<xref ref-type="aff" rid="b">b</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Lin</surname>
<given-names>Fu-Cheng</given-names>
</name>
<xref ref-type="aff" rid="a">a</xref>
</contrib>
<aff id="a"><label>a</label>
State Key Laboratory for Rice Biology, Institute of Biotechnology, Zhejiang University,<country>People’s Republic of China</country>
</aff>
<aff id="b"><label>b</label>
College of Pharmaceutical Sicence, Zhejiang University,<country>People’s Republic of China</country>
</aff>
</contrib-group>
<author-notes><corresp id="cor">Correspondence e-mail: <email>fuchenglin@zju.edu.cn</email>
</corresp>
</author-notes>
<pub-date pub-type="collection"><day>01</day>
<month>11</month>
<year>2008</year>
</pub-date>
<pub-date pub-type="epub"><day>31</day>
<month>10</month>
<year>2008</year>
</pub-date>
<pub-date pub-type="pmc-release"><day>31</day>
<month>10</month>
<year>2008</year>
</pub-date>
<pmc-comment> PMC Release delay is 0 months and 0 days and was based on the 
 							. </pmc-comment>
      <volume>64</volume>
<issue>Pt 11</issue>
<issue-id pub-id-type="publisher-id">e081100</issue-id>
<fpage>o2226</fpage>
<lpage>o2226</lpage>
<history><date date-type="received"><day>06</day>
<month>9</month>
<year>2008</year>
</date>
<date date-type="accepted"><day>06</day>
<month>10</month>
<year>2008</year>
</date>
</history>
<permissions><copyright-statement>© Chen et al. 2008</copyright-statement>
<copyright-year>2008</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by/2.0/uk/"><license-p>This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.</license-p>
</license>
</permissions>
<self-uri xlink:type="simple" xlink:href="http://dx.doi.org/10.1107/S1600536808032030">A full version of this article is available from Crystallography Journals Online.</self-uri>
<abstract><p>The title compound, C<sub>16</sub>
H<sub>16</sub>
O<sub>8</sub>
, is a potent nonspecific phytotoxin. The crystal structure is the average of two tautomers, 5,6,7,9,10-pentahydroxy-2-methoxy-7-methyl-1,4,5,6,7,8-hexahydroanthracene-1,4-dione and 1,4,5,6,7-pentahydroxy-2-methoxy-7-methyl-5,6,7,8,9,10-hexahydroanthracene-9,10-dione. The cyclohexene rings in both tautomers display a half-chair conformation. An extensive O—H⋯O hydrogen-bonding network is present in the crystal structure.</p>
</abstract>
</article-meta>
</front>
<floats-group><table-wrap id="table1" position="float"><label>Table 1</label>
<caption><title>Hydrogen-bond geometry (Å, °)</title>
</caption>
<table frame="hsides" rules="groups"><thead valign="bottom"><tr><th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom">H⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
⋯<italic>A</italic>
</th>
<th style="border-bottom:1px solid black;" rowspan="1" colspan="1" align="left" valign="bottom"><italic>D</italic>
—H⋯<italic>A</italic>
</th>
</tr>
</thead>
<tbody valign="top"><tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O1—H1<italic>A</italic>
⋯O3<sup>i</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.85</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.55</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.229 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">137</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O3—H3<italic>A</italic>
⋯O8<sup>ii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.84</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.40</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.808 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">111</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O4—H4<italic>A</italic>
⋯O8<sup>ii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.90</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.54</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.223 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">132</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O5—H5<italic>A</italic>
⋯O4</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.92</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.85</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.687 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">152</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O6—H6<italic>A</italic>
⋯O7<sup>iii</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.97</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">1.92</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.821 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">154</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H7<italic>A</italic>
⋯O1<sup>iv</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.90</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.11</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.966 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">159</td>
</tr>
<tr><td style="" rowspan="1" colspan="1" align="left" valign="top">O7—H7<italic>A</italic>
⋯O2<sup>iv</sup>
</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">0.90</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">2.40</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">3.066 (3)</td>
<td style="" rowspan="1" colspan="1" align="left" valign="top">131</td>
</tr>
</tbody>
</table>
<table-wrap-foot><p>Symmetry codes: (i) <inline-formula><inline-graphic xlink:href="e-64-o2226-efi2.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (ii) <inline-formula><inline-graphic xlink:href="e-64-o2226-efi3.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iii) <inline-formula><inline-graphic xlink:href="e-64-o2226-efi4.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
; (iv) <inline-formula><inline-graphic xlink:href="e-64-o2226-efi5.jpg" mimetype="image" mime-subtype="gif"></inline-graphic>
</inline-formula>
.</p>
</table-wrap-foot>
</table-wrap>
</floats-group>
</pmc>
<affiliations><list><country><li>République populaire de Chine</li>
</country>
</list>
<tree><country name="République populaire de Chine"><noRegion><name sortKey="Chen, Shao Yuan" sort="Chen, Shao Yuan" uniqKey="Chen S" first="Shao-Yuan" last="Chen">Shao-Yuan Chen</name>
</noRegion>
<name sortKey="Chen, Yu Zhe" sort="Chen, Yu Zhe" uniqKey="Chen Y" first="Yu-Zhe" last="Chen">Yu-Zhe Chen</name>
<name sortKey="Huang, Chao" sort="Huang, Chao" uniqKey="Huang C" first="Chao" last="Huang">Chao Huang</name>
<name sortKey="Lin, Fu Cheng" sort="Lin, Fu Cheng" uniqKey="Lin F" first="Fu-Cheng" last="Lin">Fu-Cheng Lin</name>
<name sortKey="Zhang, Chu Long" sort="Zhang, Chu Long" uniqKey="Zhang C" first="Chu-Long" last="Zhang">Chu-Long Zhang</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Pmc/Checkpoint

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001402 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Pmc/Checkpoint/biblio.hfd -nk 001402 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    MersV1
   |flux=    Pmc
   |étape=   Checkpoint
   |type=    RBID
   |clé=     PMC:2959567
   |texte=   Bostrycin
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Pmc/Checkpoint/RBID.i   -Sk "pubmed:21581081" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Pmc/Checkpoint/biblio.hfd   \
       | NlmPubMed2Wicri -a MersV1

This area was generated with Dilib version V0.6.33.
Data generation: Mon Apr 20 23:26:43 2020. Site generation: Sat Mar 27 09:06:09 2021

	Serveur d'exploration MERS
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration MERS

Bostrycin

Bostrycin

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki