Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
Identifieur interne : 000987 ( Ncbi/Merge ); précédent : 000986; suivant : 000988Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
Auteurs : Wojciech Starosta [Pologne] ; Janusz Leciejewicz [Pologne]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.
Abstract
The asymmetric unit of the title compound, [Li4(C5H3N2O2)4(H2O)4], contains two symmetry-independent LiI ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two LiI ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the LiI ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.
Url:
DOI: 10.1107/S160053681203142X
PubMed: 22904735
PubMed Central: 3414128
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(μ<sub>3</sub>
-pyrimidine-4-carboxylato)bis(μ<sub>2</sub>
-pyrimidine-4-carboxylato)tetrakis(aqualithium)</title>
<author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name>
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<front><div type="abstract" xml:lang="en"><p>The asymmetric unit of the title compound, [Li<sub>4</sub>
(C<sub>5</sub>
H<sub>3</sub>
N<sub>2</sub>
O<sub>2</sub>
)<sub>4</sub>
(H<sub>2</sub>
O)<sub>4</sub>
], contains two symmetry-independent Li<sup>I</sup>
ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two Li<sup>I</sup>
ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the Li<sup>I</sup>
ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.</p>
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-pyrimidine-4-carboxylato)tetrakis(aqualithium)</title>
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<front><div type="abstract" xml:lang="en"><p>The asymmetric unit of the title compound, [Li<sub>4</sub>
(C<sub>5</sub>
H<sub>3</sub>
N<sub>2</sub>
O<sub>2</sub>
)<sub>4</sub>
(H<sub>2</sub>
O)<sub>4</sub>
], contains two symmetry-independent Li<sup>I</sup>
ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two Li<sup>I</sup>
ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the Li<sup>I</sup>
ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.</p>
</div>
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<pubmed><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(μ(3)-pyrimidine-4-carboxyl-ato)bis-(μ(2)-pyrimidine-4-carboxyl-ato)tetra-kis-(aqua-lithium).</title>
<author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name>
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<author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name>
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<author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name>
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<front><div type="abstract" xml:lang="en">The asymmetric unit of the title compound, [Li(4)(C(5)H(3)N(2)O(2))(4)(H(2)O)(4)], contains two symmetry-independent Li(I) ions, two symmetry-independent ligands and two symmetry-independent coordinated water mol-ecules. They form a dinuclear unit in which the two Li(I) ions are bridged by two carboxyl-ate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetra-meric mol-ecule. One of the Li(I) ions shows a distorted tetra-hedral coordination geometry, the other a distorted trigonal-bipyramidal environment. The tetra-mers are held together by hydrogen bonds in which coordinated water mol-ecules act as donors, and the carboxyl-ate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.</div>
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