Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
Identifieur interne : 000987 ( Ncbi/Merge ); précédent : 000986; suivant : 000988Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
Auteurs : Wojciech Starosta [Pologne] ; Janusz Leciejewicz [Pologne]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.
Abstract
The asymmetric unit of the title compound, [Li4(C5H3N2O2)4(H2O)4], contains two symmetry-independent LiI ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two LiI ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the LiI ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.
Url:
DOI: 10.1107/S160053681203142X
PubMed: 22904735
PubMed Central: 3414128
Links toward previous steps (curation, corpus...)
- to stream Pmc, to step Corpus: 000989
- to stream Pmc, to step Curation: 000989
- to stream Pmc, to step Checkpoint: 001305
- to stream PubMed, to step Corpus: 001D56
- to stream PubMed, to step Curation: 001D56
- to stream PubMed, to step Checkpoint: 001C99
Links to Exploration step
PMC:3414128Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(μ<sub>3</sub>-pyrimidine-4-carboxylato)bis(μ<sub>2</sub>-pyrimidine-4-carboxylato)tetrakis(aqualithium)</title><author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">22904735</idno><idno type="pmc">3414128</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414128</idno><idno type="RBID">PMC:3414128</idno><idno type="doi">10.1107/S160053681203142X</idno><date when="2012">2012</date><idno type="wicri:Area/Pmc/Corpus">000989</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000989</idno><idno type="wicri:Area/Pmc/Curation">000989</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000989</idno><idno type="wicri:Area/Pmc/Checkpoint">001305</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001305</idno><idno type="wicri:source">PubMed</idno><idno type="RBID">pubmed:22904735</idno><idno type="wicri:Area/PubMed/Corpus">001D56</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001D56</idno><idno type="wicri:Area/PubMed/Curation">001D56</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001D56</idno><idno type="wicri:Area/PubMed/Checkpoint">001C99</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001C99</idno><idno type="wicri:Area/Ncbi/Merge">000987</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(μ<sub>3</sub>-pyrimidine-4-carboxylato)bis(μ<sub>2</sub>-pyrimidine-4-carboxylato)tetrakis(aqualithium)</title><author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The asymmetric unit of the title compound, [Li<sub>4</sub>(C<sub>5</sub>H<sub>3</sub>N<sub>2</sub>O<sub>2</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>4</sub>], contains two symmetry-independent Li<sup>I</sup> ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two Li<sup>I</sup> ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the Li<sup>I</sup> ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><double pmid="22904735"><pmc><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(μ<sub>3</sub>-pyrimidine-4-carboxylato)bis(μ<sub>2</sub>-pyrimidine-4-carboxylato)tetrakis(aqualithium)</title><author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">22904735</idno><idno type="pmc">3414128</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414128</idno><idno type="RBID">PMC:3414128</idno><idno type="doi">10.1107/S160053681203142X</idno><date when="2012">2012</date><idno type="wicri:Area/Pmc/Corpus">000989</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000989</idno><idno type="wicri:Area/Pmc/Curation">000989</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000989</idno><idno type="wicri:Area/Pmc/Checkpoint">001305</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001305</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(μ<sub>3</sub>-pyrimidine-4-carboxylato)bis(μ<sub>2</sub>-pyrimidine-4-carboxylato)tetrakis(aqualithium)</title><author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name><affiliation wicri:level="1"><nlm:aff id="a">Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa,<country>Poland</country></nlm:aff><country xml:lang="fr">Pologne</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The asymmetric unit of the title compound, [Li<sub>4</sub>(C<sub>5</sub>H<sub>3</sub>N<sub>2</sub>O<sub>2</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>4</sub>], contains two symmetry-independent Li<sup>I</sup> ions, two symmetry-independent ligands and two symmetry-independent coordinated water molecules. They form a dinuclear unit in which the two Li<sup>I</sup> ions are bridged by two carboxylate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetrameric molecule. One of the Li<sup>I</sup> ions shows a distorted tetrahedral coordination geometry, the other a distorted trigonal–bipyramidal environment. The tetramers are held together by hydrogen bonds in which coordinated water molecules act as donors, and the carboxylate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI></pmc><pubmed><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(μ(3)-pyrimidine-4-carboxyl-ato)bis-(μ(2)-pyrimidine-4-carboxyl-ato)tetra-kis-(aqua-lithium).</title><author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name><affiliation wicri:level="1"><nlm:affiliation>Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa, Poland.</nlm:affiliation><country xml:lang="fr">Pologne</country><wicri:regionArea>Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa</wicri:regionArea><wicri:noRegion>03-195 Warszawa</wicri:noRegion></affiliation></author><author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2012">2012</date><idno type="RBID">pubmed:22904735</idno><idno type="pmid">22904735</idno><idno type="doi">10.1107/S160053681203142X</idno><idno type="wicri:Area/PubMed/Corpus">001D56</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001D56</idno><idno type="wicri:Area/PubMed/Curation">001D56</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001D56</idno><idno type="wicri:Area/PubMed/Checkpoint">001C99</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001C99</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Bis(μ(3)-pyrimidine-4-carboxyl-ato)bis-(μ(2)-pyrimidine-4-carboxyl-ato)tetra-kis-(aqua-lithium).</title><author><name sortKey="Starosta, Wojciech" sort="Starosta, Wojciech" uniqKey="Starosta W" first="Wojciech" last="Starosta">Wojciech Starosta</name><affiliation wicri:level="1"><nlm:affiliation>Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa, Poland.</nlm:affiliation><country xml:lang="fr">Pologne</country><wicri:regionArea>Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa</wicri:regionArea><wicri:noRegion>03-195 Warszawa</wicri:noRegion></affiliation></author><author><name sortKey="Leciejewicz, Janusz" sort="Leciejewicz, Janusz" uniqKey="Leciejewicz J" first="Janusz" last="Leciejewicz">Janusz Leciejewicz</name></author></analytic><series><title level="j">Acta crystallographica. Section E, Structure reports online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2012" type="published">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The asymmetric unit of the title compound, [Li(4)(C(5)H(3)N(2)O(2))(4)(H(2)O)(4)], contains two symmetry-independent Li(I) ions, two symmetry-independent ligands and two symmetry-independent coordinated water mol-ecules. They form a dinuclear unit in which the two Li(I) ions are bridged by two carboxyl-ate O atoms from the two ligands. Two dinuclear units related by an inversion centre form the tetra-meric mol-ecule. One of the Li(I) ions shows a distorted tetra-hedral coordination geometry, the other a distorted trigonal-bipyramidal environment. The tetra-mers are held together by hydrogen bonds in which coordinated water mol-ecules act as donors, and the carboxyl-ate O atoms act as acceptors. A hydrogen bond between coordinated water molecule as donor and a ring N atom as acceptor is also observed.</div></front></TEI></pubmed></double></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Ncbi/Merge
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000987 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd -nk 000987 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Sante
|area= MersV1
|flux= Ncbi
|étape= Merge
|type= RBID
|clé= PMC:3414128
|texte= Bis(μ3-pyrimidine-4-carboxylato)bis(μ2-pyrimidine-4-carboxylato)tetrakis(aqualithium)
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/RBID.i -Sk "pubmed:22904735" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd \
| NlmPubMed2Wicri -a MersV1
| This area was generated with Dilib version V0.6.33. |  |