MersV1, Ncbi, Curation, bibRecord, 000872

Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate

Identifieur interne : 000872 ( Ncbi/Curation ); précédent : 000871; suivant : 000873

Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate

Auteurs : Miao Feng [République populaire de Chine] ; Chao Gu [République populaire de Chine] ; Huai-Feng Mi [République populaire de Chine] ; Tong-Liang Hu [République populaire de Chine]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3089088

Abstract

The tetranuclear title complex, [Cu₄(C₇H₄O₃)₂(OH)₂(C₁₀H₈N₂)₄](NO₃)₂·4H₂O, has a crystallographically imposed centre of symmetry. The Cu^II atoms display a distorted square-pyramidal coordination geometry and are linked by two μ₂-phenolate O atoms from the salicylate ligands and two μ₃-hydroxo groups, forming a Cu₄O₄ core that adopts a ‘stepped-cubane’ geometry. In the crystal, the cations are linked by O—H⋯O hydrogen bonds to the nitrate anions, which are in turn connected via O—H⋯O interactions to centrosymmentric water tetramers.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089088

DOI: 10.1107/S1600536811011433
PubMed: 21754263
PubMed Central: 3089088

Links toward previous steps (curation, corpus...)

to stream Pmc, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000A19
to stream Pmc, to step Curation: Pour aller vers cette notice dans l'étape Curation :000A19
to stream Pmc, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :001320
to stream PubMed, to step Corpus: Pour aller vers cette notice dans l'étape Curation :001E59
to stream PubMed, to step Curation: Pour aller vers cette notice dans l'étape Curation :001E59
to stream PubMed, to step Checkpoint: Pour aller vers cette notice dans l'étape Curation :001D35
to stream Ncbi, to step Merge: Pour aller vers cette notice dans l'étape Curation :000872

Links to Exploration step

PMC:3089088

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Tetrakis(2,2′-bipyridine)di-μ<sub>3</sub>
-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate</title>
<author><name sortKey="Feng, Miao" sort="Feng, Miao" uniqKey="Feng M" first="Miao" last="Feng">Miao Feng</name>
<affiliation wicri:level="1"><nlm:aff id="a">Biochemical Section of Key Laboratory of Functional Polymer Materials, Ministry of Education of China, Chemical School of Nankai University, 300071 Tianjin,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Gu, Chao" sort="Gu, Chao" uniqKey="Gu C" first="Chao" last="Gu">Chao Gu</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry, Nankai University, 300071 Tianjin ,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Mi, Huai Feng" sort="Mi, Huai Feng" uniqKey="Mi H" first="Huai-Feng" last="Mi">Huai-Feng Mi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Biochemical Section of Key Laboratory of Functional Polymer Materials, Ministry of Education of China, Chemical School of Nankai University, 300071 Tianjin,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Hu, Tong Liang" sort="Hu, Tong Liang" uniqKey="Hu T" first="Tong-Liang" last="Hu">Tong-Liang Hu</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry, Nankai University, 300071 Tianjin ,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">21754263</idno>
<idno type="pmc">3089088</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089088</idno>
<idno type="RBID">PMC:3089088</idno>
<idno type="doi">10.1107/S1600536811011433</idno>
<date when="2011">2011</date>
<idno type="wicri:Area/Pmc/Corpus">000A19</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000A19</idno>
<idno type="wicri:Area/Pmc/Curation">000A19</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000A19</idno>
<idno type="wicri:Area/Pmc/Checkpoint">001320</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">001320</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="RBID">pubmed:21754263</idno>
<idno type="wicri:Area/PubMed/Corpus">001E59</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001E59</idno>
<idno type="wicri:Area/PubMed/Curation">001E59</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001E59</idno>
<idno type="wicri:Area/PubMed/Checkpoint">001D35</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001D35</idno>
<idno type="wicri:Area/Ncbi/Merge">000872</idno>
<idno type="wicri:Area/Ncbi/Curation">000872</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Tetrakis(2,2′-bipyridine)di-μ<sub>3</sub>
-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate</title>
<author><name sortKey="Feng, Miao" sort="Feng, Miao" uniqKey="Feng M" first="Miao" last="Feng">Miao Feng</name>
<affiliation wicri:level="1"><nlm:aff id="a">Biochemical Section of Key Laboratory of Functional Polymer Materials, Ministry of Education of China, Chemical School of Nankai University, 300071 Tianjin,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Gu, Chao" sort="Gu, Chao" uniqKey="Gu C" first="Chao" last="Gu">Chao Gu</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry, Nankai University, 300071 Tianjin ,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Mi, Huai Feng" sort="Mi, Huai Feng" uniqKey="Mi H" first="Huai-Feng" last="Mi">Huai-Feng Mi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Biochemical Section of Key Laboratory of Functional Polymer Materials, Ministry of Education of China, Chemical School of Nankai University, 300071 Tianjin,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Hu, Tong Liang" sort="Hu, Tong Liang" uniqKey="Hu T" first="Tong-Liang" last="Hu">Tong-Liang Hu</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Chemistry, Nankai University, 300071 Tianjin ,<country>People’s Republic of China</country>
</nlm:aff>
<country xml:lang="fr">République populaire de Chine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2011">2011</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>The tetranuclear title complex, [Cu<sub>4</sub>
(C<sub>7</sub>
H<sub>4</sub>
O<sub>3</sub>
)<sub>2</sub>
(OH)<sub>2</sub>
(C<sub>10</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>4</sub>
](NO<sub>3</sub>
)<sub>2</sub>
·4H<sub>2</sub>
O, has a crystallographically imposed centre of symmetry. The Cu<sup>II</sup>
 atoms display a distorted square-pyramidal coordination geometry and are linked by two μ<sub>2</sub>
-phenolate O atoms from the salicylate ligands and two μ<sub>3</sub>
-hydroxo groups, forming a Cu<sub>4</sub>
O<sub>4</sub>
 core that adopts a ‘stepped-cubane’ geometry. In the crystal, the cations are linked by O—H⋯O hydrogen bonds to the nitrate anions, which are in turn connected <italic>via</italic>
 O—H⋯O interactions to centrosymmentric water tetramers.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Sante/explor/MersV1/Data/Ncbi/Curation

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000872 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Ncbi/Curation/biblio.hfd -nk 000872 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Sante
   |area=    MersV1
   |flux=    Ncbi
   |étape=   Curation
   |type=    RBID
   |clé=     PMC:3089088
   |texte=   Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Ncbi/Curation/RBID.i   -Sk "pubmed:21754263" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Ncbi/Curation/biblio.hfd   \
       | NlmPubMed2Wicri -a MersV1

This area was generated with Dilib version V0.6.33.
Data generation: Mon Apr 20 23:26:43 2020. Site generation: Sat Mar 27 09:06:09 2021

	Serveur d'exploration MERS
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration MERS

Tetra­kis(2,2′-bipyrid­ine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetra­copper(II) dinitrate tetra­hydrate

Tetra­kis(2,2′-bipyrid­ine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetra­copper(II) dinitrate tetra­hydrate

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate

Tetrakis(2,2′-bipyridine)di-μ3-hydroxido-bis(μ-2-oxidobenzoato)tetracopper(II) dinitrate tetrahydrate