X- and H-shape two dimensional conjugated oligomers with anthracene as the node.
Identifieur interne : 002625 ( Main/Merge ); précédent : 002624; suivant : 002626X- and H-shape two dimensional conjugated oligomers with anthracene as the node.
Auteurs : Weibin Cui [République populaire de Chine] ; Yingying Fu ; Yao Qu ; Hongkun Tian ; Jingping Zhang ; Zhiyuan Xie ; Yanhou Geng ; Fosong WangSource :
- Chemistry, an Asian journal [ 1861-471X ] ; 2010.
Abstract
X- and H-shape two-dimensional (2D) conjugated oligomers (X- and H-mers) and relevant model compounds have been synthesized through the introduction of different conjugated segments at the 9,10 and 2,6-positions of anthracene, and their properties were studied in detail. Comparing with the model compounds, the X- and H-mers are featured with broader absorption spectra and narrower energy bandgaps. Computational studies on the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) also indicate that these X- and H-mers are 2D conjugated. Solution processed bulk heterojunction (BHJ) solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the acceptor material exhibited the power conversion efficiency (PCE) up to 0.53 %.
DOI: 10.1002/asia.200900591
PubMed: 20198678
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last="Fu">Yingying Fu</name></author><author><name sortKey="Qu, Yao" sort="Qu, Yao" uniqKey="Qu Y" first="Yao" last="Qu">Yao Qu</name></author><author><name sortKey="Tian, Hongkun" sort="Tian, Hongkun" uniqKey="Tian H" first="Hongkun" last="Tian">Hongkun Tian</name></author><author><name sortKey="Zhang, Jingping" sort="Zhang, Jingping" uniqKey="Zhang J" first="Jingping" last="Zhang">Jingping Zhang</name></author><author><name sortKey="Xie, Zhiyuan" sort="Xie, Zhiyuan" uniqKey="Xie Z" first="Zhiyuan" last="Xie">Zhiyuan Xie</name></author><author><name sortKey="Geng, Yanhou" sort="Geng, Yanhou" uniqKey="Geng Y" first="Yanhou" last="Geng">Yanhou Geng</name></author><author><name sortKey="Wang, Fosong" sort="Wang, Fosong" uniqKey="Wang F" first="Fosong" last="Wang">Fosong Wang</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2010">2010</date><idno type="RBID">pubmed:20198678</idno><idno type="pmid">20198678</idno><idno 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wicri:level="1"><nlm:affiliation>State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, PR China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022</wicri:regionArea><placeName><settlement type="city">Changchun</settlement><region type="province">Jilin</region><region type="groupement">Dongbei</region></placeName></affiliation></author><author><name sortKey="Fu, Yingying" sort="Fu, Yingying" uniqKey="Fu Y" first="Yingying" last="Fu">Yingying Fu</name></author><author><name sortKey="Qu, Yao" sort="Qu, Yao" uniqKey="Qu Y" first="Yao" last="Qu">Yao Qu</name></author><author><name sortKey="Tian, Hongkun" sort="Tian, Hongkun" uniqKey="Tian H" first="Hongkun" last="Tian">Hongkun Tian</name></author><author><name sortKey="Zhang, Jingping" sort="Zhang, Jingping" uniqKey="Zhang J" first="Jingping" last="Zhang">Jingping Zhang</name></author><author><name sortKey="Xie, Zhiyuan" sort="Xie, Zhiyuan" uniqKey="Xie Z" first="Zhiyuan" last="Xie">Zhiyuan Xie</name></author><author><name sortKey="Geng, Yanhou" sort="Geng, Yanhou" uniqKey="Geng Y" first="Yanhou" last="Geng">Yanhou Geng</name></author><author><name sortKey="Wang, Fosong" sort="Wang, Fosong" uniqKey="Wang F" first="Fosong" last="Wang">Fosong Wang</name></author></analytic><series><title level="j">Chemistry, an Asian journal</title><idno type="eISSN">1861-471X</idno><imprint><date when="2010" type="published">2010</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">X- and H-shape two-dimensional (2D) conjugated oligomers (X- and H-mers) and relevant model compounds have been synthesized through the introduction of different conjugated segments at the 9,10 and 2,6-positions of anthracene, and their properties were studied in detail. Comparing with the model compounds, the X- and H-mers are featured with broader absorption spectra and narrower energy bandgaps. Computational studies on the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) also indicate that these X- and H-mers are 2D conjugated. Solution processed bulk heterojunction (BHJ) solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the acceptor material exhibited the power conversion efficiency (PCE) up to 0.53 %.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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