Using Metallo‐Supramolecular Block Copolymers for the Synthesis of Higher Order Nanostructured Assemblies
Identifieur interne : 002434 ( Istex/Curation ); précédent : 002433; suivant : 002435Using Metallo‐Supramolecular Block Copolymers for the Synthesis of Higher Order Nanostructured Assemblies
Auteurs : Adam O. Moughton [Royaume-Uni] ; Rachel K. O'Reilly [Royaume-Uni]Source :
- Macromolecular Rapid Communications [ 1022-1336 ] ; 2010-01-04.
English descriptors
- Teeft :
- Amphiphilic, Aqueous solution, Block copolymer, Block copolymers, Catalysis, Chem, Commun, Complexation, Complexed, Coordination geometry, Copolymer, Core hollowing, Core removal, Covalent, Covalently, Diblock, External control, External stimuli, Feature article, Fraser, Functionality, Functionalized, Fustin, Gmbh, Gohy, Great promise, Homopolymer, Hoogenboom, Hydrophobic, Kgaa, Lcst, Lcst behavior, Ligand, Linkage, Lohmeijer, Macromol, Macromolecule, Metal center, Metal complexes, Micelle, Morphology, Moughton, Nanocage, Nanocages, Nanoparticles, Nanopores, Nanostructures, Oxidation state, Parent nanoparticles, Pincer, Pnipam, Polym, Polymer, Polymer architectures, Polymer chains, Preferred coordination geometry, Pyridine, Rapid commun, Recent years, Rowan, Ruthenium, Schematic representation, Schubert, Soft matter, Solid state, Spherical micelles, Structural changes, Supramolecular, Terpyridine, Terpyridine ligands, Thermoresponsive, Transition metal, Transition metal ions, Triblock, Triblock terpolymer, Tuneable, Unique properties, Various morphologies, Verlag, Verlag gmbh, Weck, Weinheim, Wooley.
Abstract
Many research groups have explored the properties and solution self‐assembly of main chain metallo‐supramolecular multiblock copolymers. Until recently, these metal complexes have been used to prepare mainly micelle type structures. However, the self‐assembly of such copolymers has been exploited further to create more advanced architectures which utilize the reversible supramolecular linkage of their building blocks as a key component in their synthesis. Furthermore, the incorporation of multiple orthogonal interactions and stimuli responsive polymers into their design, enables more precise external control of their properties. This feature article discusses recent developments and provides an insight into their potential exploitation and development for the creation of novel, smart, and responsive nanostructures.
Main chain metallo‐supramolecular di‐ and tri‐block copolymers have been utilized as building blocks which can be self‐assembled into advanced metal functionalized architectures. This feature article provides an overview on recent developments in these areas and provides an insight into their potential exploitation and future development in the creation of novel, smart, and responsive nanostructures for advanced nanoscience applications.
Url:
DOI: 10.1002/marc.200900496
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