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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Palladium-catalyzed, pyrrolidine-mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetates<sup><xref ref-type="fn" rid="FN1">†</xref></sup></title><author><name sortKey="Cattopadhyay, Kalicharan" sort="Cattopadhyay, Kalicharan" uniqKey="Cattopadhyay K" first="Kalicharan" last="Cattopadhyay">Kalicharan Cattopadhyay</name><affiliation><nlm:aff id="A1">Haldia Institute of Technology, West Bengal, India,<email>chatterjee_k80@yahoo.co.in</email></nlm:aff></affiliation></author><author><name sortKey="Recio, Antonio" sort="Recio, Antonio" uniqKey="Recio A" first="Antonio" last="Recio">Antonio Recio</name><affiliation><nlm:aff id="A2">2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, USA</nlm:aff></affiliation></author><author><name sortKey="Tunge, Jon A" sort="Tunge, Jon A" uniqKey="Tunge J" first="Jon A." last="Tunge">Jon A. Tunge</name><affiliation><nlm:aff id="A2">2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, USA</nlm:aff></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">22832549</idno><idno type="pmc">3443958</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3443958</idno><idno type="RBID">PMC:3443958</idno><idno type="doi">10.1039/c2ob25962a</idno><date when="2012">2012</date><idno type="wicri:Area/Pmc/Corpus">003471</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">003471</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Palladium-catalyzed, pyrrolidine-mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetates<sup><xref ref-type="fn" rid="FN1">†</xref></sup></title><author><name sortKey="Cattopadhyay, Kalicharan" sort="Cattopadhyay, Kalicharan" uniqKey="Cattopadhyay K" first="Kalicharan" last="Cattopadhyay">Kalicharan Cattopadhyay</name><affiliation><nlm:aff id="A1">Haldia Institute of Technology, West Bengal, India,<email>chatterjee_k80@yahoo.co.in</email></nlm:aff></affiliation></author><author><name sortKey="Recio, Antonio" sort="Recio, Antonio" uniqKey="Recio A" first="Antonio" last="Recio">Antonio Recio</name><affiliation><nlm:aff id="A2">2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, USA</nlm:aff></affiliation></author><author><name sortKey="Tunge, Jon A" sort="Tunge, Jon A" uniqKey="Tunge J" first="Jon A." last="Tunge">Jon A. Tunge</name><affiliation><nlm:aff id="A2">2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, USA</nlm:aff></affiliation></author></analytic><series><title level="j">Organic & biomolecular chemistry</title><idno type="ISSN">1477-0520</idno><idno type="eISSN">1477-0539</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p id="P1">We report the palladium-catalyzed, pyrrolidine-mediated α-benzylation of enamines generated from aldehydes and ketones. The method allows for direct coupling of medicinally relevant coumarin moieties with aldehydes and ketones in good yield under mild conditions. The reaction is believed to proceed via a Pd-π-benzyl complex generated from (coumarinyl)methyl acetates.</p></div></front></TEI><pmc article-type="research-article"><pmc-comment>The publisher of this article does not allow downloading of the full text in XML form.</pmc-comment>
<pmc-dir>properties manuscript</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-journal-id">101154995</journal-id><journal-id journal-id-type="pubmed-jr-id">30417</journal-id><journal-id journal-id-type="nlm-ta">Org Biomol Chem</journal-id><journal-id journal-id-type="iso-abbrev">Org. Biomol. Chem.</journal-id><journal-title-group><journal-title>Organic & biomolecular chemistry</journal-title></journal-title-group><issn pub-type="ppub">1477-0520</issn><issn pub-type="epub">1477-0539</issn></journal-meta><article-meta><article-id pub-id-type="pmid">22832549</article-id><article-id pub-id-type="pmc">3443958</article-id><article-id pub-id-type="doi">10.1039/c2ob25962a</article-id><article-id pub-id-type="manuscript">NIHMS399720</article-id><article-categories><subj-group subj-group-type="heading"><subject>Article</subject></subj-group></article-categories><title-group><article-title>Palladium-catalyzed, pyrrolidine-mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetates<sup><xref ref-type="fn" rid="FN1">†</xref></sup></article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Cattopadhyay</surname><given-names>Kalicharan</given-names></name><xref ref-type="aff" rid="A1">a</xref></contrib><contrib contrib-type="author"><name><surname>Recio</surname><given-names>Antonio</given-names><suffix>III</suffix></name><xref ref-type="aff" rid="A2">b</xref></contrib><contrib contrib-type="author"><name><surname>Tunge</surname><given-names>Jon A.</given-names></name><xref ref-type="corresp" rid="CR1">*</xref><xref ref-type="aff" rid="A2">b</xref></contrib></contrib-group><aff id="A1"><label>a</label>Haldia Institute of Technology, West Bengal, India,<email>chatterjee_k80@yahoo.co.in</email></aff><aff id="A2"><label>b</label>2010 Malott Hall, 1251 Wescoe Hall Dr., Lawrence, USA</aff><author-notes><corresp id="CR1"><label>*</label><email>tunge@ku.edu</email>; Fax: +1 (785) 864 5396; Tel: +1 (785) 864-4136
</corresp></author-notes><pub-date pub-type="nihms-submitted"><day>13</day><month>8</month><year>2012</year></pub-date><pub-date pub-type="epub"><day>25</day><month>7</month><year>2012</year></pub-date><pub-date pub-type="ppub"><day>14</day><month>9</month><year>2012</year></pub-date><pub-date pub-type="pmc-release"><day>14</day><month>9</month><year>2013</year></pub-date><volume>10</volume><issue>34</issue><fpage>6826</fpage><lpage>6829</lpage><permissions><copyright-statement>© The Royal Society of Chemistry 2012</copyright-statement><copyright-year>2012</copyright-year></permissions><abstract><p id="P1">We report the palladium-catalyzed, pyrrolidine-mediated α-benzylation of enamines generated from aldehydes and ketones. The method allows for direct coupling of medicinally relevant coumarin moieties with aldehydes and ketones in good yield under mild conditions. The reaction is believed to proceed via a Pd-π-benzyl complex generated from (coumarinyl)methyl acetates.</p></abstract><funding-group><award-group><funding-source country="United States">National Institute of General Medical Sciences : NIGMS</funding-source><award-id>R01 GM079644 || GM</award-id></award-group><award-group><funding-source country="United States">National Institute of General Medical Sciences : NIGMS</funding-source><award-id>P50 GM069663 || GM</award-id></award-group></funding-group></article-meta></front></pmc></record>Pour manipuler ce document sous Unix (Dilib)
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