Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu)
Identifieur interne : 001938 ( Main/Exploration ); précédent : 001937; suivant : 001939Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu)
Auteurs : S. Abid [Tunisie] ; M. Rzaigui [Tunisie] ; M. Bagieu-Beucher [France]Source :
- Materials Research Bulletin [ 0025-5408 ] ; 2000.
English descriptors
- KwdEn :
- Teeft :
- Abid, Aqueous solution, Atomic arrangement, Average heating rate, Black circles, Bond angles, Carbon atoms, Cation, Cdo6 octahedra, Corresponding author, Crystal structure, Cyclohexaphosphates, Cyclohexaphosphoric acid, Dcal dobs, Disordered carbon atoms, Elsevier science, Endothermic peaks, General formula, Inversion center, Main interatomic distances, Materials research bulletin, Nitrogen atoms, Organic cations, Organic groups, Phosphoric ring anion, Room temperature, Scan time, Solid state inorg chem, Space group, Structure determination, Thermal behavior, Water molecules, Weight loss.
Abstract
Abstract: Four new cyclohexaphosphates with the general formula M(p-CH3C6H4NH3)4P6O18·8H2O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH3C6H4NH3)4P6O18·8H2O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β = 91.93(1), γ = 93.45(1)°, Z = 1, P1 ̄, V = 1193.9(6) Å3, and Dx = 1.618 g·cm−3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P6O186− ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.
Url:
DOI: 10.1016/S0025-5408(00)00394-9
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en">Abstract: Four new cyclohexaphosphates with the general formula M(p-CH3C6H4NH3)4P6O18·8H2O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH3C6H4NH3)4P6O18·8H2O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β = 91.93(1), γ = 93.45(1)°, Z = 1, P1 ̄, V = 1193.9(6) Å3, and Dx = 1.618 g·cm−3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P6O186− ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.</div>
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