Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu)
Identifieur interne : 000558 ( Istex/Curation ); précédent : 000557; suivant : 000559Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu)
Auteurs : S. Abid [Tunisie] ; M. Rzaigui [Tunisie] ; M. Bagieu-Beucher [France]Source :
- Materials Research Bulletin [ 0025-5408 ] ; 2000.
English descriptors
- KwdEn :
- Teeft :
- Abid, Aqueous solution, Atomic arrangement, Average heating rate, Black circles, Bond angles, Carbon atoms, Cation, Cdo6 octahedra, Corresponding author, Crystal structure, Cyclohexaphosphates, Cyclohexaphosphoric acid, Dcal dobs, Disordered carbon atoms, Elsevier science, Endothermic peaks, General formula, Inversion center, Main interatomic distances, Materials research bulletin, Nitrogen atoms, Organic cations, Organic groups, Phosphoric ring anion, Room temperature, Scan time, Solid state inorg chem, Space group, Structure determination, Thermal behavior, Water molecules, Weight loss.
Abstract
Abstract: Four new cyclohexaphosphates with the general formula M(p-CH3C6H4NH3)4P6O18·8H2O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH3C6H4NH3)4P6O18·8H2O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β = 91.93(1), γ = 93.45(1)°, Z = 1, P1 ̄, V = 1193.9(6) Å3, and Dx = 1.618 g·cm−3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P6O186− ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.
Url:
DOI: 10.1016/S0025-5408(00)00394-9
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: Pour aller vers cette notice dans l'étape Curation :000558
Links to Exploration step
ISTEX:B355A4D8932DBBC1BDB258FADF1918F1C376E35ELe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu)</title>
<author><name sortKey="Abid, S" sort="Abid, S" uniqKey="Abid S" first="S." last="Abid">S. Abid</name>
<affiliation wicri:level="1"><mods:affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia</mods:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, M" sort="Rzaigui, M" uniqKey="Rzaigui M" first="M." last="Rzaigui">M. Rzaigui</name>
<affiliation wicri:level="1"><mods:affiliation>E-mail: Mohammed.rzaigui@fsb.rnu.tn</mods:affiliation>
<country wicri:rule="url">Tunisie</country>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia</mods:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Bagieu Beucher, M" sort="Bagieu Beucher, M" uniqKey="Bagieu Beucher M" first="M." last="Bagieu-Beucher">M. Bagieu-Beucher</name>
<affiliation wicri:level="1"><mods:affiliation>Laboratoire de Cristallographie associé à l’Université J. Fourier, C.N.R.S., BP. 166, 38042 Grenoble Cédex 09, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Cristallographie associé à l’Université J. Fourier, C.N.R.S., BP. 166, 38042 Grenoble Cédex 09</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:B355A4D8932DBBC1BDB258FADF1918F1C376E35E</idno>
<date when="2000" year="2000">2000</date>
<idno type="doi">10.1016/S0025-5408(00)00394-9</idno>
<idno type="url">https://api.istex.fr/ark:/67375/6H6-6BLX28Q3-5/fulltext.pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000558</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000558</idno>
<idno type="wicri:Area/Istex/Curation">000558</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu)</title>
<author><name sortKey="Abid, S" sort="Abid, S" uniqKey="Abid S" first="S." last="Abid">S. Abid</name>
<affiliation wicri:level="1"><mods:affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia</mods:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, M" sort="Rzaigui, M" uniqKey="Rzaigui M" first="M." last="Rzaigui">M. Rzaigui</name>
<affiliation wicri:level="1"><mods:affiliation>E-mail: Mohammed.rzaigui@fsb.rnu.tn</mods:affiliation>
<country wicri:rule="url">Tunisie</country>
</affiliation>
<affiliation wicri:level="1"><mods:affiliation>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia</mods:affiliation>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea>Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Bagieu Beucher, M" sort="Bagieu Beucher, M" uniqKey="Bagieu Beucher M" first="M." last="Bagieu-Beucher">M. Bagieu-Beucher</name>
<affiliation wicri:level="1"><mods:affiliation>Laboratoire de Cristallographie associé à l’Université J. Fourier, C.N.R.S., BP. 166, 38042 Grenoble Cédex 09, France</mods:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de Cristallographie associé à l’Université J. Fourier, C.N.R.S., BP. 166, 38042 Grenoble Cédex 09</wicri:regionArea>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Materials Research Bulletin</title>
<title level="j" type="abbrev">MRB</title>
<idno type="ISSN">0025-5408</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="2000">2000</date>
<biblScope unit="volume">35</biblScope>
<biblScope unit="issue">12</biblScope>
<biblScope unit="page" from="1933">1933</biblScope>
<biblScope unit="page" to="1944">1944</biblScope>
</imprint>
<idno type="ISSN">0025-5408</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0025-5408</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>B. Chemical synthesis</term>
<term>C. Infrared spectroscopy</term>
<term>C. Thermogravimetric analysis (TGA)</term>
<term>C. X-ray diffraction</term>
<term>D. Crystal structure</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Abid</term>
<term>Aqueous solution</term>
<term>Atomic arrangement</term>
<term>Average heating rate</term>
<term>Black circles</term>
<term>Bond angles</term>
<term>Carbon atoms</term>
<term>Cation</term>
<term>Cdo6 octahedra</term>
<term>Corresponding author</term>
<term>Crystal structure</term>
<term>Cyclohexaphosphates</term>
<term>Cyclohexaphosphoric acid</term>
<term>Dcal dobs</term>
<term>Disordered carbon atoms</term>
<term>Elsevier science</term>
<term>Endothermic peaks</term>
<term>General formula</term>
<term>Inversion center</term>
<term>Main interatomic distances</term>
<term>Materials research bulletin</term>
<term>Nitrogen atoms</term>
<term>Organic cations</term>
<term>Organic groups</term>
<term>Phosphoric ring anion</term>
<term>Room temperature</term>
<term>Scan time</term>
<term>Solid state inorg chem</term>
<term>Space group</term>
<term>Structure determination</term>
<term>Thermal behavior</term>
<term>Water molecules</term>
<term>Weight loss</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Abstract: Four new cyclohexaphosphates with the general formula M(p-CH3C6H4NH3)4P6O18·8H2O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH3C6H4NH3)4P6O18·8H2O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β = 91.93(1), γ = 93.45(1)°, Z = 1, P1 ̄, V = 1193.9(6) Å3, and Dx = 1.618 g·cm−3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P6O186− ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.</div>
</front>
</TEI>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Istex/Curation
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000558 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Curation/biblio.hfd -nk 000558 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Sante |area= H2N2V1 |flux= Istex |étape= Curation |type= RBID |clé= ISTEX:B355A4D8932DBBC1BDB258FADF1918F1C376E35E |texte= Preparation and structure of a series of cyclohexaphosphates: M(p-CH3C6H4NH3)4P6O18·8H2O (M = Cd, Co, Zn, and Cu) }}
This area was generated with Dilib version V0.6.33. |