A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry
Identifieur interne : 001774 ( Istex/Corpus ); précédent : 001773; suivant : 001775A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry
Auteurs : Isabelle Bey ; Bernard Aumont ; Gérard ToupanceSource :
- Journal of Geophysical Research: Atmospheres [ 0148-0227 ] ; 2001-05-16.
English descriptors
- Teeft :
- Acyl, Alkane, Alkene, Alkyl, Anthropogenic, Anthropogenic emissions, Aschmann, Atkinson, Atmos, Biogenic, Calvert, Canttell, Carbonyl, Ch3cho, Chem, Chemical mechanism, Chemical operators, Chemistry, Compound, Degradation, Environ, Etal, Formationof, Functional group, Geophys, Glyox, Good agreement, Hcho, Hno3, Horie, Hydrocarbon, Isoprene, Jenkin, Kinetics, Lightfoot, Locol, Locol time, Modeling, Modeling study, Moortgat, Neeb, Nitrate, Nono2_p, Nono2_s, Ofthe, Organic compounds, Oxygenated, Ozone, Ozonolysis, Pathway, Paulson, Peroxy, Peroxy radicals, Peroxyradicals, Photolysis, Phys, Pinene, Pinonaldehyde, Propene, Radical, Radical chemistry, Radical cycle, Rateconstant, Rco3, Rco3h, Reaction rates, Reactionof, Reactionsof, Rno3, Ro2_p, Ro2_s, Rono2_p, Rooh, Scenario, Terpene, Thereaction, Tothe, Troposphere, Tropospheric, Vocs.
Abstract
We describe a detailed chemical mechanism (140 species, 440 reactions) representing atmospheric chemistry of the lower continental troposphere. We focus on chemical reactions potentially important for nighttime chemistry. The mechanism is based on the methods and concepts proposed by Carter [1990] for the development of the Statewide Air Pollution Research Center (SAPRC) mechanism to reduce the number of species and reactions. Peroxy radical chemistry is represented with chemical operators and secondary VOCs are lumped into a limited number of surrogate species. To account for new experimental data provided since the first formulation of the SAPRC mechanism, the whole set of reactions has been updated. Representation of peroxy radical chemistry has been modified to account for variability of organic peroxy radical‐peroxy radical reaction rates. New chemical operators and new secondary species have been added to the mechanism to introduce reactions of alkenes with NO3. Reactions of alkenes with O3 have been largely revised to represent largest radical yields suggested by recent experimental studies. Chemistry of three biogenic compounds (isoprene, α‐pinene and β‐pinene) has been included. The mechanism is coupled to a two‐layer box model (including anthropogenic and biogenic emissions of VOCs and NOx and dry deposition) in order to represent different chemical environments (from urban to rural cases). Comparisons with the SAPRC‐99 mechanism show good agreements especially for high NOx regime. Results from the model are evaluated with typical observed concentrations in the different environmental cases with a special focus on the representation of radical species concentations. For both daytime and nighttime, the calculated OH and peroxy radical concentrations are within the range of available observed values although the model tends to overestimate HO2 concentrations in daytime. At night, OH concentrations are found to vary from 1 to 6×106 molecules cm−3 in the urban environment, 5×104 to 2×105 molecules cm−3 in polluted rural environments and 4×104 molecules cm−3 in remote environments.
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DOI: 10.1029/2000JD900347
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ISTEX:96181AB8D6D20A45BBEFBC6DF4A5D801EC3225BDLe document en format XML
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We focus on chemical reactions potentially important for nighttime chemistry. The mechanism is based on the methods and concepts proposed by Carter [1990] for the development of the Statewide Air Pollution Research Center (SAPRC) mechanism to reduce the number of species and reactions. Peroxy radical chemistry is represented with chemical operators and secondary VOCs are lumped into a limited number of surrogate species. To account for new experimental data provided since the first formulation of the SAPRC mechanism, the whole set of reactions has been updated. Representation of peroxy radical chemistry has been modified to account for variability of organic peroxy radical‐peroxy radical reaction rates. New chemical operators and new secondary species have been added to the mechanism to introduce reactions of alkenes with NO3. Reactions of alkenes with O3 have been largely revised to represent largest radical yields suggested by recent experimental studies. Chemistry of three biogenic compounds (isoprene, α‐pinene and β‐pinene) has been included. The mechanism is coupled to a two‐layer box model (including anthropogenic and biogenic emissions of VOCs and NOx and dry deposition) in order to represent different chemical environments (from urban to rural cases). Comparisons with the SAPRC‐99 mechanism show good agreements especially for high NOx regime. Results from the model are evaluated with typical observed concentrations in the different environmental cases with a special focus on the representation of radical species concentations. For both daytime and nighttime, the calculated OH and peroxy radical concentrations are within the range of available observed values although the model tends to overestimate HO2 concentrations in daytime. At night, OH concentrations are found to vary from 1 to 6×106 molecules cm−3 in the urban environment, 5×104 to 2×105 molecules cm−3 in polluted rural environments and 4×104 molecules cm−3 in remote environments.</div></front></TEI><istex><corpusName>wiley</corpusName><keywords><teeft><json:string>peroxy</json:string><json:string>ro2_p</json:string><json:string>rco3</json:string><json:string>alkene</json:string><json:string>geophys</json:string><json:string>ro2_s</json:string><json:string>modeling 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We focus on chemical reactions potentially important for nighttime chemistry. The mechanism is based on the methods and concepts proposed by Carter [1990] for the development of the Statewide Air Pollution Research Center (SAPRC) mechanism to reduce the number of species and reactions. Peroxy radical chemistry is represented with chemical operators and secondary VOCs are lumped into a limited number of surrogate species. To account for new experimental data provided since the first formulation of the SAPRC mechanism, the whole set of reactions has been updated. Representation of peroxy radical chemistry has been modified to account for variability of organic peroxy radical‐peroxy radical reaction rates. New chemical operators and new secondary species have been added to the mechanism to introduce reactions of alkenes with NO3. Reactions of alkenes with O3 have been largely revised to represent largest radical yields suggested by recent experimental studies. Chemistry of three biogenic compounds (isoprene, α‐pinene and β‐pinene) has been included. The mechanism is coupled to a two‐layer box model (including anthropogenic and biogenic emissions of VOCs and NOx and dry deposition) in order to represent different chemical environments (from urban to rural cases). Comparisons with the SAPRC‐99 mechanism show good agreements especially for high NOx regime. Results from the model are evaluated with typical observed concentrations in the different environmental cases with a special focus on the representation of radical species concentations. For both daytime and nighttime, the calculated OH and peroxy radical concentrations are within the range of available observed values although the model tends to overestimate HO2 concentrations in daytime. At night, OH concentrations are found to vary from 1 to 6×106 molecules cm−3 in the urban environment, 5×104 to 2×105 molecules cm−3 in polluted rural environments and 4×104 molecules cm−3 in remote environments.</abstract><qualityIndicators><score>10</score><pdfWordCount>8097</pdfWordCount><pdfCharCount>123848</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>32</pdfPageCount><pdfPageSize>607 x 814 pts</pdfPageSize><pdfWordsPerPage>253</pdfWordsPerPage><pdfText>true</pdfText><refBibsNative>true</refBibsNative><abstractWordCount>310</abstractWordCount><abstractCharCount>2123</abstractCharCount><keywordCount>0</keywordCount></qualityIndicators><title>A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. 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[1997]</json:string><json:string>[1995]</json:string><json:string>[1990]</json:string><json:string>Hjorth et al., 1990</json:string><json:string>Aschmann and Atkinson, 1994</json:string><json:string>Gutbrod et al., 1997</json:string><json:string>[1994]</json:string><json:string>DeMote et al. 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Development of a detailed chemical mechanism including nighttime chemistry</title><idno type="istex">96181AB8D6D20A45BBEFBC6DF4A5D801EC3225BD</idno><idno type="ark">ark:/67375/WNG-4BVRKFL4-C</idno><idno type="DOI">10.1029/2000JD900347</idno><idno type="editorialOffice">2000JD900347</idno><idno type="unit">JGRD7927</idno><idno type="toTypesetVersion">file:JGRD.JGRD7927.pdf</idno></analytic><monogr><title level="j" type="main">Journal of Geophysical Research: Atmospheres</title><title level="j" type="alt">JOURNAL OF GEOPHYSICAL RESEARCH: ATMOSPHERES</title><idno type="pISSN">0148-0227</idno><idno type="eISSN">2156-2202</idno><idno type="book-DOI">10.1002/(ISSN)2156-2202d</idno><idno type="book-part-DOI">10.1002/jgrd.v106.D9</idno><idno type="product">JGRD</idno><idno type="coden">JGREA2</idno><imprint><biblScope unit="vol">106</biblScope><biblScope unit="issue">D9</biblScope><biblScope unit="page" from="9959">9959</biblScope><biblScope unit="page" to="9990">9990</biblScope><biblScope unit="page-count">32</biblScope><date type="published" when="2001-05-16"></date></imprint></monogr></biblStruct></sourceDesc></fileDesc><encodingDesc><schemaRef type="ODD" url="https://xml-schema.delivery.istex.fr/tei-istex.odd"></schemaRef><appInfo><application ident="pub2tei" version="1.0.10" when="2019-12-20"><label>pub2TEI-ISTEX</label><desc>A set of style sheets for converting XML documents encoded in various scientific publisher formats into a common TEI format.
<ref target="http://www.tei-c.org/">We use TEI</ref></desc></application></appInfo></encodingDesc><profileDesc><abstract style="main"><p xml:id="jgrd7927-para-0001">We describe a detailed chemical mechanism (140 species, 440 reactions) representing atmospheric chemistry of the lower continental troposphere. We focus on chemical reactions potentially important for nighttime chemistry. The mechanism is based on the methods and concepts proposed by <hi rend="italic">Carter</hi> [1990] for the development of the Statewide Air Pollution Research Center (SAPRC) mechanism to reduce the number of species and reactions. Peroxy radical chemistry is represented with chemical operators and secondary VOCs are lumped into a limited number of surrogate species. To account for new experimental data provided since the first formulation of the SAPRC mechanism, the whole set of reactions has been updated. Representation of peroxy radical chemistry has been modified to account for variability of organic peroxy radical‐peroxy radical reaction rates. New chemical operators and new secondary species have been added to the mechanism to introduce reactions of alkenes with NO<hi rend="subscript">3</hi>. Reactions of alkenes with O<hi rend="subscript">3</hi> have been largely revised to represent largest radical yields suggested by recent experimental studies. Chemistry of three biogenic compounds (isoprene, α‐pinene and β‐pinene) has been included. The mechanism is coupled to a two‐layer box model (including anthropogenic and biogenic emissions of VOCs and NO<hi rend="subscript"><hi rend="italic">x</hi></hi> and dry deposition) in order to represent different chemical environments (from urban to rural cases). Comparisons with the SAPRC‐99 mechanism show good agreements especially for high NO<hi rend="subscript"><hi rend="italic">x</hi></hi> regime. Results from the model are evaluated with typical observed concentrations in the different environmental cases with a special focus on the representation of radical species concentations. For both daytime and nighttime, the calculated OH and peroxy radical concentrations are within the range of available observed values although the model tends to overestimate HO<hi rend="subscript">2</hi> concentrations in daytime. At night, OH concentrations are found to vary from 1 to 6×10<hi rend="superscript">6</hi> molecules cm<hi rend="superscript">−3</hi> in the urban environment, 5×10<hi rend="superscript">4</hi> to 2×10<hi rend="superscript">5</hi> molecules cm<hi rend="superscript">−3</hi> in polluted rural environments and 4×10<hi rend="superscript">4</hi> molecules cm<hi rend="superscript">−3</hi> in remote environments.</p></abstract><textClass><keywords rend="articleCategory"><term>Papers on Composition and Chemistry</term></keywords><keywords rend="tocHeading1"><term>Papers on Composition and Chemistry</term></keywords></textClass><textClass><keywords ana="subject"><term ref="http://psi.agu.org/taxonomy5/0300">ATMOSPHERIC COMPOSITION AND STRUCTURE</term><term ref="http://psi.agu.org/taxonomy5/0315">Biosphere/atmosphere interactions</term><term ref="http://psi.agu.org/taxonomy5/0317">Chemical kinetic and photochemical properties</term><term ref="http://psi.agu.org/taxonomy5/0322">Constituent sources and sinks</term><term ref="http://psi.agu.org/taxonomy5/0365">Troposphere: composition and chemistry</term></keywords></textClass><langUsage><language ident="en"></language></langUsage></profileDesc><revisionDesc><change when="2019-12-20" who="#istex" xml:id="pub2tei">formatting</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/WNG-4BVRKFL4-C/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Wiley, elements deleted: body"><istex:xmlDeclaration>version="1.0" encoding="UTF-8" standalone="yes"</istex:xmlDeclaration><istex:document><component type="serialArticle" version="2.0" xml:lang="en" xml:id="jgrd7927"><header><publicationMeta level="product"><doi>10.1002/(ISSN)2156-2202d</doi><issn type="print">0148-0227</issn><issn type="electronic">2156-2202</issn><idGroup><id type="product" value="JGRD"></id><id type="coden" value="JGREA2"></id></idGroup><titleGroup><title type="main" xml:lang="en" sort="JOURNAL OF GEOPHYSICAL RESEARCH: ATMOSPHERES">Journal of Geophysical Research: Atmospheres</title><title type="short">J. Geophys. Res.</title></titleGroup></publicationMeta><publicationMeta level="part" position="90"><doi>10.1002/jgrd.v106.D9</doi><idGroup><id type="focusSection" value="4"></id></idGroup><titleGroup><title type="focusSection" xml:lang="en">Journal of Geophysical Research: Atmospheres</title></titleGroup><numberingGroup><numbering type="journalVolume" number="106">106</numbering><numbering type="journalIssue">D9</numbering></numberingGroup><coverDate startDate="2001-05-16">16 May 2001</coverDate></publicationMeta><publicationMeta level="unit" type="article" position="230" status="forIssue"><doi>10.1029/2000JD900347</doi><idGroup><id type="editorialOffice" value="2000JD900347"></id><id type="unit" value="JGRD7927"></id></idGroup><countGroup><count type="pageTotal" number="32"></count></countGroup><titleGroup><title type="articleCategory">Papers on Composition and Chemistry</title><title type="tocHeading1">Papers on Composition and Chemistry</title></titleGroup><copyright ownership="thirdParty">Copyright 2001 by the American Geophysical Union.</copyright><eventGroup><event type="manuscriptReceived" date="1999-11-05"></event><event type="manuscriptAccepted" date="2000-06-02"></event><event type="publishedPrint" date="2001-05-16"></event><event type="firstOnline" date="2012-09-21"></event><event type="publishedOnlineFinalForm" date="2012-09-21"></event><event type="xmlConverted" agent="SPi Global Converter:AGUv1.0_TO_WileyML3Gv1.0.3 version:1.2; WileyML 3G Packaging Tool v1.0" date="2012-11-26"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-01-30"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-10-30"></event></eventGroup><numberingGroup><numbering type="pageFirst">9959</numbering><numbering type="pageLast">9990</numbering></numberingGroup><subjectInfo><subject href="http://psi.agu.org/taxonomy5/0300">ATMOSPHERIC COMPOSITION AND STRUCTURE</subject><subjectInfo><subject href="http://psi.agu.org/taxonomy5/0315">Biosphere/atmosphere interactions</subject><subject href="http://psi.agu.org/taxonomy5/0317">Chemical kinetic and photochemical properties</subject><subject href="http://psi.agu.org/taxonomy5/0322">Constituent sources and sinks</subject><subject href="http://psi.agu.org/taxonomy5/0365">Troposphere: composition and chemistry</subject></subjectInfo></subjectInfo><selfCitationGroup><citation xml:id="jgrd7927-cit-0000" type="self"><author><familyName>Bey</familyName>, <givenNames>I.</givenNames></author>, <author><givenNames>B.</givenNames> <familyName>Aumont</familyName></author>, and <author><givenNames>G.</givenNames> <familyName>Toupance</familyName></author> (<pubYear year="2001">2001</pubYear>), <articleTitle>A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry</articleTitle>, <journalTitle>J. Geophys. Res.</journalTitle>, <vol>106</vol>(<issue>D9</issue>), <pageFirst>9959</pageFirst>–<pageLast>9990</pageLast>, doi:<accessionId ref="info:doi/10.1029/2000JD900347">10.1029/2000JD900347</accessionId>.</citation></selfCitationGroup><linkGroup><link type="toTypesetVersion" href="file:JGRD.JGRD7927.pdf"></link></linkGroup></publicationMeta><contentMeta><titleGroup><title type="main">A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry</title><title type="shortAuthors">Bey ET AL.</title></titleGroup><creators><creator xml:id="jgrd7927-cr-0001"><personName><givenNames>Isabelle</givenNames><familyName>Bey</familyName></personName></creator><creator xml:id="jgrd7927-cr-0002"><personName><givenNames>Bernard</givenNames><familyName>Aumont</familyName></personName></creator><creator xml:id="jgrd7927-cr-0003"><personName><givenNames>Gérard</givenNames><familyName>Toupance</familyName></personName></creator></creators><abstractGroup><abstract type="main"><p xml:id="jgrd7927-para-0001">We describe a detailed chemical mechanism (140 species, 440 reactions) representing atmospheric chemistry of the lower continental troposphere. We focus on chemical reactions potentially important for nighttime chemistry. The mechanism is based on the methods and concepts proposed by <i>Carter</i> [1990] for the development of the Statewide Air Pollution Research Center (SAPRC) mechanism to reduce the number of species and reactions. Peroxy radical chemistry is represented with chemical operators and secondary VOCs are lumped into a limited number of surrogate species. To account for new experimental data provided since the first formulation of the SAPRC mechanism, the whole set of reactions has been updated. Representation of peroxy radical chemistry has been modified to account for variability of organic peroxy radical‐peroxy radical reaction rates. New chemical operators and new secondary species have been added to the mechanism to introduce reactions of alkenes with NO<sub>3</sub>. Reactions of alkenes with O<sub>3</sub> have been largely revised to represent largest radical yields suggested by recent experimental studies. Chemistry of three biogenic compounds (isoprene, α‐pinene and β‐pinene) has been included. The mechanism is coupled to a two‐layer box model (including anthropogenic and biogenic emissions of VOCs and NO<sub><i>x</i></sub> and dry deposition) in order to represent different chemical environments (from urban to rural cases). Comparisons with the SAPRC‐99 mechanism show good agreements especially for high NO<sub><i>x</i></sub> regime. Results from the model are evaluated with typical observed concentrations in the different environmental cases with a special focus on the representation of radical species concentations. For both daytime and nighttime, the calculated OH and peroxy radical concentrations are within the range of available observed values although the model tends to overestimate HO<sub>2</sub> concentrations in daytime. At night, OH concentrations are found to vary from 1 to 6×10<sup>6</sup> molecules cm<sup>−3</sup> in the urban environment, 5×10<sup>4</sup> to 2×10<sup>5</sup> molecules cm<sup>−3</sup> in polluted rural environments and 4×10<sup>4</sup> molecules cm<sup>−3</sup> in remote environments.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry</title></titleInfo><name type="personal"><namePart type="given">Isabelle</namePart><namePart type="family">Bey</namePart></name><name type="personal"><namePart type="given">Bernard</namePart><namePart type="family">Aumont</namePart></name><name type="personal"><namePart type="given">Gérard</namePart><namePart type="family">Toupance</namePart></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>Blackwell Publishing Ltd</publisher><dateIssued encoding="w3cdtf">2001-05-16</dateIssued><dateCaptured encoding="w3cdtf">1999-11-05</dateCaptured><dateValid encoding="w3cdtf">2000-06-02</dateValid><edition>Bey, I., B. Aumont, and G. Toupance (2001), A modeling study of the nighttime radical chemistry in the lower continental troposphere: 1. Development of a detailed chemical mechanism including nighttime chemistry, J. Geophys. Res., 106(D9), 9959–9990, doi:10.1029/2000JD900347.</edition><copyrightDate encoding="w3cdtf">2001</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><abstract>We describe a detailed chemical mechanism (140 species, 440 reactions) representing atmospheric chemistry of the lower continental troposphere. We focus on chemical reactions potentially important for nighttime chemistry. The mechanism is based on the methods and concepts proposed by Carter [1990] for the development of the Statewide Air Pollution Research Center (SAPRC) mechanism to reduce the number of species and reactions. Peroxy radical chemistry is represented with chemical operators and secondary VOCs are lumped into a limited number of surrogate species. To account for new experimental data provided since the first formulation of the SAPRC mechanism, the whole set of reactions has been updated. Representation of peroxy radical chemistry has been modified to account for variability of organic peroxy radical‐peroxy radical reaction rates. New chemical operators and new secondary species have been added to the mechanism to introduce reactions of alkenes with NO3. Reactions of alkenes with O3 have been largely revised to represent largest radical yields suggested by recent experimental studies. Chemistry of three biogenic compounds (isoprene, α‐pinene and β‐pinene) has been included. The mechanism is coupled to a two‐layer box model (including anthropogenic and biogenic emissions of VOCs and NOx and dry deposition) in order to represent different chemical environments (from urban to rural cases). Comparisons with the SAPRC‐99 mechanism show good agreements especially for high NOx regime. Results from the model are evaluated with typical observed concentrations in the different environmental cases with a special focus on the representation of radical species concentations. For both daytime and nighttime, the calculated OH and peroxy radical concentrations are within the range of available observed values although the model tends to overestimate HO2 concentrations in daytime. At night, OH concentrations are found to vary from 1 to 6×106 molecules cm−3 in the urban environment, 5×104 to 2×105 molecules cm−3 in polluted rural environments and 4×104 molecules cm−3 in remote environments.</abstract><relatedItem type="host"><titleInfo><title>Journal of Geophysical Research: Atmospheres</title></titleInfo><titleInfo type="abbreviated"><title>J. Geophys. Res.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><subject><genre>index-terms</genre><topic authorityURI="http://psi.agu.org/taxonomy5/0300">ATMOSPHERIC COMPOSITION AND STRUCTURE</topic><topic authorityURI="http://psi.agu.org/taxonomy5/0315">Biosphere/atmosphere interactions</topic><topic authorityURI="http://psi.agu.org/taxonomy5/0317">Chemical kinetic and photochemical properties</topic><topic authorityURI="http://psi.agu.org/taxonomy5/0322">Constituent sources and sinks</topic><topic authorityURI="http://psi.agu.org/taxonomy5/0365">Troposphere: composition and chemistry</topic></subject><subject><genre>article-category</genre><topic>Papers on Composition and Chemistry</topic><topic>Papers on Composition and Chemistry</topic></subject><identifier type="ISSN">0148-0227</identifier><identifier type="eISSN">2156-2202</identifier><identifier type="DOI">10.1002/(ISSN)2156-2202d</identifier><identifier type="CODEN">JGREA2</identifier><identifier type="PublisherID">JGRD</identifier><part><date>2001</date><detail type="volume"><caption>vol.</caption><number>106</number></detail><detail type="issue"><caption>no.</caption><number>D9</number></detail><extent unit="pages"><start>9959</start><end>9990</end><total>32</total></extent></part></relatedItem><relatedItem type="references" displayLabel="jgrd7927-cit-0001"><titleInfo><title>Products of the gas‐phase reactions of O(3P) atoms and O3 with α‐pinene and 1,2‐dimethyl‐1‐cyclohexene</title></titleInfo><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Alvarado</namePart><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">E. 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