The synthesis and characterisation of C -triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2
Identifieur interne : 001347 ( Istex/Corpus ); précédent : 001346; suivant : 001348The synthesis and characterisation of C -triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2
Auteurs : Michael S. Hill ; Mary F. Mahon ; John M. G. Mcginley ; Kieran C. MolloySource :
- Polyhedron [ 0277-5387 ] ; 2001.
English descriptors
- KwdEn :
- Teeft :
- Anal, Anion formation, Asymmetric unit, Bond angles, Bond lengths, Bond polarities, Buli, Calc, Chem, Chemical shifts, Colourless, Computer program, Crystal structure, Derivative, Diethyl, Diethyl ether, Elsevier science, Ether, Hexane, Lithiation, Mmol, Mossbauer, Organomet, Perkin trans, Petroleum ether, Phenyl groups, Phenyl rings, Polyhedron, Previous work, Pyrazole, Room temperature, Subsequent substitution, Tetrahedral geometry, Tributyltin chloride, Trimethylsilyl chloride, Trimethyltin chloride, Triphenyltin chloride, Unresolved, Vacuo, Vacuo removal, Vacuum distillation, White suspension, Yellow solution, Yellow suspension.
Abstract
Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.
C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised. Substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph3Sn)C3N2]2CH2.loc1
Url:
DOI: 10.1016/S0277-5387(01)00799-9
Links to Exploration step
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<front><div type="abstract" xml:lang="en">Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.</div>
<div type="abstract">C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised. Substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph3Sn)C3N2]2CH2.loc1 </div>
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<note type="content">Fig. 1: The asymmetric unit of 10 showing the labelling scheme used in the text. Thermal ellipsoids are at the 30% probability level.</note>
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<abstract xml:lang="en"><p>Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.</p>
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<abstract style="graphical"><p>C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised. Substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph3Sn)C3N2]2CH2.loc1</p>
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<item><term>Mössbauer</term>
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<head><ce:title>The synthesis and characterisation of <ce:italic>C</ce:italic>
-triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph<ce:inf>3</ce:inf>
Sn)C<ce:inf>3</ce:inf>
N<ce:inf>2</ce:inf>
]<ce:inf>2</ce:inf>
CH<ce:inf>2</ce:inf>
</ce:title>
<ce:author-group><ce:author><ce:given-name>Michael S.</ce:given-name>
<ce:surname>Hill</ce:surname>
</ce:author>
<ce:author><ce:given-name>Mary F.</ce:given-name>
<ce:surname>Mahon</ce:surname>
</ce:author>
<ce:author><ce:given-name>John M.G.</ce:given-name>
<ce:surname>McGinley</ce:surname>
</ce:author>
<ce:author><ce:given-name>Kieran C.</ce:given-name>
<ce:surname>Molloy</ce:surname>
<ce:cross-ref refid="COR1">*</ce:cross-ref>
<ce:e-address type="email">chskcm@bath.ac.uk</ce:e-address>
</ce:author>
<ce:affiliation><ce:textfn>Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK</ce:textfn>
</ce:affiliation>
<ce:correspondence id="COR1"><ce:label>*</ce:label>
<ce:text>Corresponding author. Tel.: +44-1225-826382; fax: +44-1225-826231</ce:text>
</ce:correspondence>
</ce:author-group>
<ce:date-received day="19" month="1" year="2001"></ce:date-received>
<ce:date-accepted day="26" month="3" year="2001"></ce:date-accepted>
<ce:abstract><ce:section-title>Abstract</ce:section-title>
<ce:abstract-sec><ce:simple-para><ce:italic>C</ce:italic>
-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1<ce:italic>H</ce:italic>
-pyrazol-1-yl)methyl]-1<ce:italic>H</ce:italic>
-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R<ce:inf>3</ce:inf>
M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph<ce:inf>3</ce:inf>
Sn)C<ce:inf>3</ce:inf>
N<ce:inf>2</ce:inf>
]<ce:inf>2</ce:inf>
CH<ce:inf>2</ce:inf>
.</ce:simple-para>
</ce:abstract-sec>
</ce:abstract>
<ce:abstract class="graphical"><ce:abstract-sec><ce:simple-para><ce:italic>C</ce:italic>
-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1<ce:italic>H</ce:italic>
-pyrazol-1-yl)methyl]-1<ce:italic>H</ce:italic>
-pyrazole have been synthesised. Substitution by R<ce:inf>3</ce:inf>
M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph<ce:inf>3</ce:inf>
Sn)C<ce:inf>3</ce:inf>
N<ce:inf>2</ce:inf>
]<ce:inf>2</ce:inf>
CH<ce:inf>2</ce:inf>
.</ce:simple-para>
</ce:abstract-sec>
<ce:figure><ce:link locator="loc1"></ce:link>
</ce:figure>
</ce:abstract>
<ce:keywords class="keyword"><ce:section-title>Keywords</ce:section-title>
<ce:keyword><ce:text>Orgaontin</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Organosilicon</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Thiophene</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Pyrazole</ce:text>
</ce:keyword>
<ce:keyword><ce:text>X-ray</ce:text>
</ce:keyword>
<ce:keyword><ce:text>Mössbauer</ce:text>
</ce:keyword>
</ce:keywords>
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<mods version="3.6"><titleInfo lang="en"><title>The synthesis and characterisation of C -triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2</title>
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<titleInfo type="alternative" lang="en" contentType="CDATA"><title>The synthesis and characterisation of</title>
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<name type="personal"><namePart type="given">Michael S.</namePart>
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<affiliation>Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK</affiliation>
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<name type="personal"><namePart type="given">Mary F.</namePart>
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<name type="personal"><namePart type="given">John M.G.</namePart>
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<name type="personal"><namePart type="given">Kieran C.</namePart>
<namePart type="family">Molloy</namePart>
<affiliation>Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK</affiliation>
<affiliation>E-mail: chskcm@bath.ac.uk</affiliation>
<description>Corresponding author. Tel.: +44-1225-826382; fax: +44-1225-826231</description>
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<abstract lang="en">Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.</abstract>
<abstract type="graphical">C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised. Substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph3Sn)C3N2]2CH2.loc1 </abstract>
<note type="content">Fig. 1: The asymmetric unit of 10 showing the labelling scheme used in the text. Thermal ellipsoids are at the 30% probability level.</note>
<note type="content">Table 1: Crystallographic data for 10</note>
<note type="content">Table 2: Selected bond lengths (Å) and bond angles (°) for 10</note>
<subject lang="en"><genre>Keywords</genre>
<topic>Orgaontin</topic>
<topic>Organosilicon</topic>
<topic>Thiophene</topic>
<topic>Pyrazole</topic>
<topic>X-ray</topic>
<topic>Mössbauer</topic>
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<caption>vol.</caption>
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<detail type="issue"><number>15–16</number>
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<extent unit="pages"><start>1995</start>
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