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The synthesis and characterisation of C -triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2

Identifieur interne : 001347 ( Istex/Corpus ); précédent : 001346; suivant : 001348

The synthesis and characterisation of C -triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2

Auteurs : Michael S. Hill ; Mary F. Mahon ; John M. G. Mcginley ; Kieran C. Molloy

Source :

RBID : ISTEX:2C9D4E77B75296C010C26C236FE17F62B7ABA8EC

English descriptors

Abstract

Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.
C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised. Substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph3Sn)C3N2]2CH2.loc1

Url:
DOI: 10.1016/S0277-5387(01)00799-9

Links to Exploration step

ISTEX:2C9D4E77B75296C010C26C236FE17F62B7ABA8EC

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<div type="abstract" xml:lang="en">Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.</div>
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<p>Abstract: C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1′-[5,5′-(Ph3Sn)C3N2]2CH2.</p>
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<p>C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised. Substitution by R3M takes place at the 5,5′ positions for both bis-heterocycles and this is confirmed by the X-ray structure of 1,1′-(5,5′-(Ph3Sn)C3N2]2CH2.loc1</p>
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<note type="content">Fig. 1: The asymmetric unit of 10 showing the labelling scheme used in the text. Thermal ellipsoids are at the 30% probability level.</note>
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<topic>Mössbauer</topic>
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