Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate
Identifieur interne : 001097 ( Istex/Corpus ); précédent : 001096; suivant : 001098Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate
Auteurs : G. G. Sadikov ; T. V. Koksharova ; A. S. Antsyshkina ; I. S. Gritsenko ; V. S. SergienkoSource :
- Crystallography Reports [ 1063-7745 ] ; 2008-07-01.
English descriptors
- KwdEn :
Abstract
Abstract: The copper(II) phthalate complex with nicotinamide [CuL 2(μ-Pht)(H2O)] · 0.5H2O(I) (where L is nicotinamide and Pht 2− is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) Å, b = 7.891(3) Å, c = 20.480(2) Å, β = 108.69(2)°, Z = 4, and space group P21/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H2 O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.
Url:
DOI: 10.1134/S1063774508040135
Links to Exploration step
ISTEX:FE0BE430D769A1DAEB580D1551696A812CA26697Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title><author><name sortKey="Sadikov, G G" sort="Sadikov, G G" uniqKey="Sadikov G" first="G. G." last="Sadikov">G. G. Sadikov</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: sadgg@igic.ras.ru</mods:affiliation></affiliation></author><author><name sortKey="Koksharova, T V" sort="Koksharova, T V" uniqKey="Koksharova T" first="T. V." last="Koksharova">T. V. Koksharova</name><affiliation><mods:affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Antsyshkina, A S" sort="Antsyshkina, A S" uniqKey="Antsyshkina A" first="A. S." last="Antsyshkina">A. S. Antsyshkina</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation></author><author><name sortKey="Gritsenko, I S" sort="Gritsenko, I S" uniqKey="Gritsenko I" first="I. S." last="Gritsenko">I. S. Gritsenko</name><affiliation><mods:affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Sergienko, V S" sort="Sergienko, V S" uniqKey="Sergienko V" first="V. S." last="Sergienko">V. S. Sergienko</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:FE0BE430D769A1DAEB580D1551696A812CA26697</idno><date when="2008" year="2008">2008</date><idno type="doi">10.1134/S1063774508040135</idno><idno type="url">https://api.istex.fr/ark:/67375/VQC-XDKCNZGR-H/fulltext.pdf</idno><idno type="wicri:Area/Istex/Corpus">001097</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">001097</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title><author><name sortKey="Sadikov, G G" sort="Sadikov, G G" uniqKey="Sadikov G" first="G. G." last="Sadikov">G. G. Sadikov</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: sadgg@igic.ras.ru</mods:affiliation></affiliation></author><author><name sortKey="Koksharova, T V" sort="Koksharova, T V" uniqKey="Koksharova T" first="T. V." last="Koksharova">T. V. Koksharova</name><affiliation><mods:affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Antsyshkina, A S" sort="Antsyshkina, A S" uniqKey="Antsyshkina A" first="A. S." last="Antsyshkina">A. S. Antsyshkina</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation></author><author><name sortKey="Gritsenko, I S" sort="Gritsenko, I S" uniqKey="Gritsenko I" first="I. S." last="Gritsenko">I. S. Gritsenko</name><affiliation><mods:affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Sergienko, V S" sort="Sergienko, V S" uniqKey="Sergienko V" first="V. S." last="Sergienko">V. S. Sergienko</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Crystallography Reports</title><title level="j" type="abbrev">Crystallogr. Rep.</title><idno type="ISSN">1063-7745</idno><idno type="eISSN">1562-689X</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2008-07-01">2008-07-01</date><biblScope unit="volume">53</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="631">631</biblScope><biblScope unit="page" to="638">638</biblScope></imprint><idno type="ISSN">1063-7745</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1063-7745</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>61.66.Hq</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The copper(II) phthalate complex with nicotinamide [CuL 2(μ-Pht)(H2O)] · 0.5H2O(I) (where L is nicotinamide and Pht 2− is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) Å, b = 7.891(3) Å, c = 20.480(2) Å, β = 108.69(2)°, Z = 4, and space group P21/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H2 O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.</div></front></TEI><istex><corpusName>springer-journals</corpusName><author><json:item><name>G. G. Sadikov</name><affiliations><json:string>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</json:string><json:string>E-mail: sadgg@igic.ras.ru</json:string></affiliations></json:item><json:item><name>T. V. Koksharova</name><affiliations><json:string>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</json:string></affiliations></json:item><json:item><name>A. S. Antsyshkina</name><affiliations><json:string>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</json:string></affiliations></json:item><json:item><name>I. S. Gritsenko</name><affiliations><json:string>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</json:string></affiliations></json:item><json:item><name>V. S. Sergienko</name><affiliations><json:string>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</json:string></affiliations></json:item></author><subject><json:item><lang><json:string>eng</json:string></lang><value>61.66.Hq</value></json:item></subject><articleId><json:string>4013</json:string><json:string>S1063774508040135</json:string></articleId><arkIstex>ark:/67375/VQC-XDKCNZGR-H</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>OriginalPaper</json:string></originalGenre><abstract>Abstract: The copper(II) phthalate complex with nicotinamide [CuL 2(μ-Pht)(H2O)] · 0.5H2O(I) (where L is nicotinamide and Pht 2− is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) Å, b = 7.891(3) Å, c = 20.480(2) Å, β = 108.69(2)°, Z = 4, and space group P21/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H2 O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.</abstract><qualityIndicators><score>8.733</score><pdfWordCount>4381</pdfWordCount><pdfCharCount>28684</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>8</pdfPageCount><pdfPageSize>612 x 792 pts (letter)</pdfPageSize><refBibsNative>false</refBibsNative><abstractWordCount>196</abstractWordCount><abstractCharCount>1201</abstractCharCount><keywordCount>1</keywordCount></qualityIndicators><title>Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title><genre><json:string>research-article</json:string></genre><host><title>Crystallography Reports</title><language><json:string>unknown</json:string></language><publicationDate>2008</publicationDate><copyrightDate>2008</copyrightDate><issn><json:string>1063-7745</json:string></issn><eissn><json:string>1562-689X</json:string></eissn><journalId><json:string>11445</json:string></journalId><volume>53</volume><issue>4</issue><pages><first>631</first><last>638</last></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Crystallography</value></json:item></subject></host><ark><json:string>ark:/67375/VQC-XDKCNZGR-H</json:string></ark><publicationDate>2008</publicationDate><copyrightDate>2008</copyrightDate><doi><json:string>10.1134/S1063774508040135</json:string></doi><id>FE0BE430D769A1DAEB580D1551696A812CA26697</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-XDKCNZGR-H/fulltext.pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-XDKCNZGR-H/bundle.zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/ark:/67375/VQC-XDKCNZGR-H/fulltext.tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher scheme="https://scientific-publisher.data.istex.fr">SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><availability><licence><p>Pleiades Publishing, Ltd., 2008</p></licence><p scheme="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</p></availability><date>2007-05-25</date></publicationStmt><notesStmt><note type="research-article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</note><note type="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note><note>Structure of Organic Compounds</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title><author xml:id="author-0000" corresp="yes"><persName><forename type="first">G.</forename><surname>Sadikov</surname></persName><email>sadgg@igic.ras.ru</email><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</affiliation></author><author xml:id="author-0001"><persName><forename type="first">T.</forename><surname>Koksharova</surname></persName><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation></author><author xml:id="author-0002"><persName><forename type="first">A.</forename><surname>Antsyshkina</surname></persName><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</affiliation></author><author xml:id="author-0003"><persName><forename type="first">I.</forename><surname>Gritsenko</surname></persName><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation></author><author xml:id="author-0004"><persName><forename type="first">V.</forename><surname>Sergienko</surname></persName><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</affiliation></author><idno type="istex">FE0BE430D769A1DAEB580D1551696A812CA26697</idno><idno type="ark">ark:/67375/VQC-XDKCNZGR-H</idno><idno type="DOI">10.1134/S1063774508040135</idno><idno type="article-id">4013</idno><idno type="article-id">S1063774508040135</idno></analytic><monogr><title level="j">Crystallography Reports</title><title level="j" type="abbrev">Crystallogr. Rep.</title><idno type="pISSN">1063-7745</idno><idno type="eISSN">1562-689X</idno><idno type="journal-ID">true</idno><idno type="issue-article-count">30</idno><idno type="volume-issue-count">6</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2008-07-01"></date><biblScope unit="volume">53</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="631">631</biblScope><biblScope unit="page" to="638">638</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2007-05-25</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Abstract: The copper(II) phthalate complex with nicotinamide [CuL 2(μ-Pht)(H2O)] · 0.5H2O(I) (where L is nicotinamide and Pht 2− is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) Å, b = 7.891(3) Å, c = 20.480(2) Å, β = 108.69(2)°, Z = 4, and space group P21/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H2 O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.</p></abstract><textClass xml:lang="en"><keywords scheme="keyword"><list><head>PACS numbers</head><item><term>61.66.Hq</term></item></list></keywords></textClass><textClass><keywords scheme="Journal Subject"><list><head>Physics</head><item><term>Crystallography</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2007-05-25">Created</change><change when="2008-07-01">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-XDKCNZGR-H/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="corpus springer-journals not found" wicri:toSee="no header"><istex:xmlDeclaration>version="1.0" encoding="UTF-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//Springer-Verlag//DTD A++ V2.4//EN" URI="http://devel.springer.de/A++/V2.4/DTD/A++V2.4.dtd" name="istex:docType"></istex:docType><istex:document><Publisher><PublisherInfo><PublisherName>SP MAIK Nauka/Interperiodica</PublisherName><PublisherLocation>Dordrecht</PublisherLocation></PublisherInfo><Journal OutputMedium="All"><JournalInfo JournalProductType="ArchiveJournal" NumberingStyle="Unnumbered"><JournalID>11445</JournalID><JournalPrintISSN>1063-7745</JournalPrintISSN><JournalElectronicISSN>1562-689X</JournalElectronicISSN><JournalTitle>Crystallography Reports</JournalTitle><JournalAbbreviatedTitle>Crystallogr. Rep.</JournalAbbreviatedTitle><JournalSubjectGroup><JournalSubject Type="Primary">Physics</JournalSubject><JournalSubject Type="Secondary">Crystallography </JournalSubject></JournalSubjectGroup></JournalInfo><Volume OutputMedium="All"><VolumeInfo TocLevels="0" VolumeType="Regular"><VolumeIDStart>53</VolumeIDStart><VolumeIDEnd>53</VolumeIDEnd><VolumeIssueCount>6</VolumeIssueCount></VolumeInfo><Issue IssueType="Regular" OutputMedium="All"><IssueInfo IssueType="Regular" TocLevels="0"><IssueIDStart>4</IssueIDStart><IssueIDEnd>4</IssueIDEnd><IssueArticleCount>30</IssueArticleCount><IssueHistory><OnlineDate><Year>2008</Year><Month>7</Month><Day>28</Day></OnlineDate><CoverDate><Year>2008</Year><Month>7</Month></CoverDate></IssueHistory><IssueCopyright><CopyrightHolderName>Pleiades Publishing, Ltd.</CopyrightHolderName><CopyrightYear>2008</CopyrightYear></IssueCopyright></IssueInfo><Article ID="S1063774508040135" OutputMedium="All"><ArticleInfo ArticleType="OriginalPaper" ContainsESM="No" Language="En" NumberingStyle="Unnumbered" TocLevels="0"><ArticleID>4013</ArticleID><ArticleDOI>10.1134/S1063774508040135</ArticleDOI><ArticleSequenceNumber>13</ArticleSequenceNumber><ArticleTitle Language="En">Synthesis and crystal structure of <Emphasis Type="Italic">catena</Emphasis>-bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</ArticleTitle><ArticleCategory>Structure of Organic Compounds</ArticleCategory><ArticleFirstPage>631</ArticleFirstPage><ArticleLastPage>638</ArticleLastPage><ArticleHistory><RegistrationDate><Year>2008</Year><Month>7</Month><Day>25</Day></RegistrationDate><Received><Year>2007</Year><Month>5</Month><Day>25</Day></Received><OnlineDate><Year>2008</Year><Month>7</Month><Day>29</Day></OnlineDate></ArticleHistory><ArticleCopyright><CopyrightHolderName>Pleiades Publishing, Ltd.</CopyrightHolderName><CopyrightYear>2008</CopyrightYear></ArticleCopyright><ArticleGrants Type="Regular"><MetadataGrant Grant="OpenAccess"></MetadataGrant><AbstractGrant Grant="OpenAccess"></AbstractGrant><BodyPDFGrant Grant="Restricted"></BodyPDFGrant><BodyHTMLGrant Grant="Restricted"></BodyHTMLGrant><BibliographyGrant Grant="Restricted"></BibliographyGrant><ESMGrant Grant="Restricted"></ESMGrant></ArticleGrants></ArticleInfo><ArticleHeader><AuthorGroup><Author AffiliationIDS="Aff1" CorrespondingAffiliationID="Aff1"><AuthorName DisplayOrder="Western"><GivenName>G.</GivenName><GivenName>G.</GivenName><FamilyName>Sadikov</FamilyName></AuthorName><Contact><Email>sadgg@igic.ras.ru</Email></Contact></Author><Author AffiliationIDS="Aff2"><AuthorName DisplayOrder="Western"><GivenName>T.</GivenName><GivenName>V.</GivenName><FamilyName>Koksharova</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>A.</GivenName><GivenName>S.</GivenName><FamilyName>Antsyshkina</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff2"><AuthorName DisplayOrder="Western"><GivenName>I.</GivenName><GivenName>S.</GivenName><FamilyName>Gritsenko</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>V.</GivenName><GivenName>S.</GivenName><FamilyName>Sergienko</FamilyName></AuthorName></Author><Affiliation ID="Aff1"><OrgDivision>Kurnakov Institute of General and Inorganic Chemistry</OrgDivision><OrgName>Russian Academy of Sciences</OrgName><OrgAddress><Street>Leninskiĭ pr. 31</Street><City>Moscow</City><Postcode>119991</Postcode><Country Code="RU">Russia</Country></OrgAddress></Affiliation><Affiliation ID="Aff2"><OrgName>Odessa National University</OrgName><OrgAddress><Street>Dvoryanskaya ul. 2</Street><City>Odessa</City><Postcode>65026</Postcode><Country Code="UA">Ukraine</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Abstract</Heading><Para>The copper(II) phthalate complex with nicotinamide [Cu<Emphasis Type="Italic">L</Emphasis><Subscript>2</Subscript>(μ-<Emphasis Type="Italic">Pht</Emphasis>)(H<Subscript>2</Subscript>O)] · 0.5H<Subscript>2</Subscript>O(<Emphasis Type="Bold">I</Emphasis>) (where <Emphasis Type="Italic">L</Emphasis> is nicotinamide and <Emphasis Type="Italic">Pht</Emphasis><Superscript>2−</Superscript> is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound <Emphasis Type="Bold">I</Emphasis> are monoclinic, <Emphasis Type="Italic">a</Emphasis> = 13.368(2) Å, <Emphasis Type="Italic">b</Emphasis> = 7.891(3) Å, <Emphasis Type="Italic">c</Emphasis> = 20.480(2) Å, β = 108.69(2)°, <Emphasis Type="Italic">Z</Emphasis> = 4, and space group <Emphasis Type="Italic">P</Emphasis>2<Subscript>1</Subscript>/<Emphasis Type="Italic">c</Emphasis>. The structural units of crystal <Emphasis Type="Bold">I</Emphasis> are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H<Subscript>2</Subscript> O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.</Para></Abstract><KeywordGroup Language="En"><Heading>PACS numbers</Heading><Keyword>61.66.Hq</Keyword></KeywordGroup><ArticleNote Type="Misc"><SimplePara>Original Russian Text © G.G. Sadikov, T.V. Koksharova, A.S. Antsyshkina, I.S. Gritsenko, V.S. Sergienko, 2008, published in Kristallografiya, 2008, Vol. 53, No. 4, pp. 668–675.</SimplePara></ArticleNote></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate</title></titleInfo><name type="personal" displayLabel="corresp"><namePart type="given">G.</namePart><namePart type="given">G.</namePart><namePart type="family">Sadikov</namePart><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</affiliation><affiliation>E-mail: sadgg@igic.ras.ru</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">T.</namePart><namePart type="given">V.</namePart><namePart type="family">Koksharova</namePart><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.</namePart><namePart type="given">S.</namePart><namePart type="family">Antsyshkina</namePart><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">I.</namePart><namePart type="given">S.</namePart><namePart type="family">Gritsenko</namePart><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">V.</namePart><namePart type="given">S.</namePart><namePart type="family">Sergienko</namePart><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiĭ pr. 31, 119991, Moscow, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>SP MAIK Nauka/Interperiodica</publisher><place><placeTerm type="text">Dordrecht</placeTerm></place><dateCreated encoding="w3cdtf">2007-05-25</dateCreated><dateIssued encoding="w3cdtf">2008-07-01</dateIssued><copyrightDate encoding="w3cdtf">2008</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><abstract lang="en">Abstract: The copper(II) phthalate complex with nicotinamide [CuL 2(μ-Pht)(H2O)] · 0.5H2O(I) (where L is nicotinamide and Pht 2− is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) Å, b = 7.891(3) Å, c = 20.480(2) Å, β = 108.69(2)°, Z = 4, and space group P21/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 Å), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 Å), and the oxygen atom of the H2 O molecule (Cu-O, 2.014 Å). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 Å), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.</abstract><note>Structure of Organic Compounds</note><subject lang="en"><genre>PACS numbers</genre><topic>61.66.Hq</topic></subject><relatedItem type="host"><titleInfo><title>Crystallography Reports</title></titleInfo><titleInfo type="abbreviated"><title>Crystallogr. Rep.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>Springer</publisher><dateIssued encoding="w3cdtf">2008-07-28</dateIssued><copyrightDate encoding="w3cdtf">2008</copyrightDate></originInfo><subject><genre>Physics</genre><topic>Crystallography</topic></subject><identifier type="ISSN">1063-7745</identifier><identifier type="eISSN">1562-689X</identifier><identifier type="JournalID">11445</identifier><identifier type="IssueArticleCount">30</identifier><identifier type="VolumeIssueCount">6</identifier><part><date>2008</date><detail type="volume"><number>53</number><caption>vol.</caption></detail><detail type="issue"><number>4</number><caption>no.</caption></detail><extent unit="pages"><start>631</start><end>638</end></extent></part><recordInfo><recordOrigin>Pleiades Publishing, Ltd., 2008</recordOrigin></recordInfo></relatedItem><identifier type="istex">FE0BE430D769A1DAEB580D1551696A812CA26697</identifier><identifier type="ark">ark:/67375/VQC-XDKCNZGR-H</identifier><identifier type="DOI">10.1134/S1063774508040135</identifier><identifier type="ArticleID">4013</identifier><identifier type="ArticleID">S1063774508040135</identifier><accessCondition type="use and reproduction" contentType="copyright">Pleiades Publishing, Ltd., 2008</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</recordContentSource><recordOrigin>Pleiades Publishing, Ltd., 2008</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-XDKCNZGR-H/record.json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Sante/explor/H2N2V1/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001097 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 001097 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Sante
|area= H2N2V1
|flux= Istex
|étape= Corpus
|type= RBID
|clé= ISTEX:FE0BE430D769A1DAEB580D1551696A812CA26697
|texte= Synthesis and crystal structure of catena -bis(nicotinamide)aqua(μ-phthalato)copper(II) hemihydrate
}}
| This area was generated with Dilib version V0.6.33. |  |