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Electron ionization‐induced fragmentation of R2N2Fe2(CO)6 complexes with distinct geometries of the tetrahedral core: investigation of µ‐1,2‐(1,2‐diaza‐3‐methylcyclopentane)diylbis(tricarbonyliron) and bis(µ2‐acetophenoniminato)bis(tricarbonyliron)

Identifieur interne : 000D89 ( Istex/Corpus ); précédent : 000D88; suivant : 000D90

Electron ionization‐induced fragmentation of R2N2Fe2(CO)6 complexes with distinct geometries of the tetrahedral core: investigation of µ‐1,2‐(1,2‐diaza‐3‐methylcyclopentane)diylbis(tricarbonyliron) and bis(µ2‐acetophenoniminato)bis(tricarbonyliron)

Auteurs : Andrzej Zimniak

Source :

RBID : ISTEX:7407AAD080B93BBF6401E6D9769014AA1E7662F0

English descriptors

Abstract

Two binuclear bis(tricarbonyliron) title complexes with N2Fe2 tetrahedral cores, 1 and 2, respectively, which show different molecular folding resulting from the appearance (in 1), and absence (in 2) of the NN σ‐bond, were compared in terms of mass spectral fragmentation routes. A multipath fragmentation noted for the molecule 1 revealing internal stress contrasts with the single‐route fragmentation of 2. The fragmentation paths resulting from the admixtures were defined and analyzed from the fragment ion B/E and parent ion B2/E linked scan spectra. Copyright © 2002 John Wiley & Sons, Ltd.

Url:
DOI: 10.1002/jms.377

Links to Exploration step

ISTEX:7407AAD080B93BBF6401E6D9769014AA1E7662F0

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<correspondenceTo>Department of Physical Chemistry, Faculty of Pharmacy, Medical University of Warsaw, Banacha 1, 02‐097 Warsaw, Poland.===</correspondenceTo>
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<title type="main" xml:lang="en">Electron ionization‐induced fragmentation of R
<sub>2</sub>
N
<sub>2</sub>
Fe
<sub>2</sub>
(CO)
<sub>6</sub>
complexes with distinct geometries of the tetrahedral core: investigation of µ‐1,2‐(1,2‐diaza‐3‐methylcyclopentane)diylbis(tricarbonyliron) and bis(µ
<sub>2</sub>
‐acetophenoniminato)bis(tricarbonyliron)</title>
<title type="short" xml:lang="en">EI‐induced fragmentation R
<sub>2</sub>
N
<sub>2</sub>
Fe
<sub>2</sub>
(CO)
<sub>6</sub>
</title>
</titleGroup>
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<personName>
<givenNames>Andrzej</givenNames>
<familyName>Zimniak</familyName>
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<email>axzimni@farm.amwaw.edu.pl</email>
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<unparsedAffiliation>Department of Physical Chemistry, Faculty of Pharmacy, Medical University of Warsaw, 02‐097 Warsaw, Poland</unparsedAffiliation>
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<keyword xml:id="kwd1">iron</keyword>
<keyword xml:id="kwd2">bis(tricarbonyliron)</keyword>
<keyword xml:id="kwd3">complexes</keyword>
<keyword xml:id="kwd4">fragmentation</keyword>
<keyword xml:id="kwd5">electron ionization</keyword>
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<abstract type="main" xml:lang="en">
<title type="main">Abstract</title>
<p>Two binuclear bis(tricarbonyliron) title complexes with N
<sub>2</sub>
Fe
<sub>2</sub>
tetrahedral cores,
<b>1</b>
and
<b>2</b>
, respectively, which show different molecular folding resulting from the appearance (in
<b>1</b>
), and absence (in
<b>2</b>
) of the NN σ‐bond, were compared in terms of mass spectral fragmentation routes. A multipath fragmentation noted for the molecule
<b>1</b>
revealing internal stress contrasts with the single‐route fragmentation of
<b>2</b>
. The fragmentation paths resulting from the admixtures were defined and analyzed from the fragment ion
<i>B</i>
/
<i>E</i>
and parent ion
<i>B</i>
<sup>2</sup>
/
<i>E</i>
linked scan spectra. Copyright © 2002 John Wiley & Sons, Ltd.</p>
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<title>Electron ionization‐induced fragmentation of R2N2Fe2(CO)6 complexes with distinct geometries of the tetrahedral core: investigation of µ‐1,2‐(1,2‐diaza‐3‐methylcyclopentane)diylbis(tricarbonyliron) and bis(µ2‐acetophenoniminato)bis(tricarbonyliron)</title>
</titleInfo>
<titleInfo type="abbreviated" lang="en">
<title>EI‐induced fragmentation R2N2Fe2(CO)6</title>
</titleInfo>
<titleInfo type="alternative" contentType="CDATA" lang="en">
<title>Electron ionization‐induced fragmentation of R2N2Fe2(CO)6 complexes with distinct geometries of the tetrahedral core: investigation of µ‐1,2‐(1,2‐diaza‐3‐methylcyclopentane)diylbis(tricarbonyliron) and bis(µ2‐acetophenoniminato)bis(tricarbonyliron)</title>
</titleInfo>
<name type="personal">
<namePart type="given">Andrzej</namePart>
<namePart type="family">Zimniak</namePart>
<affiliation>Department of Physical Chemistry, Faculty of Pharmacy, Medical University of Warsaw, 02‐097 Warsaw, Poland</affiliation>
<affiliation>E-mail: axzimni@farm.amwaw.edu.pl</affiliation>
<affiliation>Correspondence address: Department of Physical Chemistry, Faculty of Pharmacy, Medical University of Warsaw, Banacha 1, 02‐097 Warsaw, Poland.===</affiliation>
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<abstract lang="en">Two binuclear bis(tricarbonyliron) title complexes with N2Fe2 tetrahedral cores, 1 and 2, respectively, which show different molecular folding resulting from the appearance (in 1), and absence (in 2) of the NN σ‐bond, were compared in terms of mass spectral fragmentation routes. A multipath fragmentation noted for the molecule 1 revealing internal stress contrasts with the single‐route fragmentation of 2. The fragmentation paths resulting from the admixtures were defined and analyzed from the fragment ion B/E and parent ion B2/E linked scan spectra. Copyright © 2002 John Wiley & Sons, Ltd.</abstract>
<subject lang="en">
<genre>keywords</genre>
<topic>iron</topic>
<topic>bis(tricarbonyliron)</topic>
<topic>complexes</topic>
<topic>fragmentation</topic>
<topic>electron ionization</topic>
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<title>Journal of Mass Spectrometry</title>
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<title>J. Mass Spectrom.</title>
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<topic>Research Articles</topic>
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<identifier type="ISSN">1076-5174</identifier>
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<identifier type="DOI">10.1002/(ISSN)1096-9888c</identifier>
<identifier type="PublisherID">JMS</identifier>
<part>
<date>2002</date>
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