Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate
Identifieur interne : 000B06 ( Istex/Corpus ); précédent : 000B05; suivant : 000B07Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate
Auteurs : A. S. Antsyshkina ; G. G. Sadikov ; T. V. Koksharova ; I. S. Gritsenko ; V. S. SergienkoSource :
- Russian Journal of Inorganic Chemistry [ 0036-0236 ] ; 2009-08-01.
Abstract
Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.
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DOI: 10.1134/S003602360908021X
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S." last="Antsyshkina">A. S. Antsyshkina</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation><affiliation><mods:affiliation>E-mail: sadgg@igic.ras.ru</mods:affiliation></affiliation></author><author><name sortKey="Sadikov, G G" sort="Sadikov, G G" uniqKey="Sadikov G" first="G. G." last="Sadikov">G. G. Sadikov</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation></author><author><name sortKey="Koksharova, T V" sort="Koksharova, T V" uniqKey="Koksharova T" first="T. V." last="Koksharova">T. V. Koksharova</name><affiliation><mods:affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Gritsenko, I S" sort="Gritsenko, I S" uniqKey="Gritsenko I" first="I. S." last="Gritsenko">I. S. Gritsenko</name><affiliation><mods:affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</mods:affiliation></affiliation></author><author><name sortKey="Sergienko, V S" sort="Sergienko, V S" uniqKey="Sergienko V" first="V. S." last="Sergienko">V. S. Sergienko</name><affiliation><mods:affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Russian Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Russ. J. Inorg. Chem.</title><idno type="ISSN">0036-0236</idno><idno type="eISSN">1531-8613</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2009-08-01">2009-08-01</date><biblScope unit="volume">54</biblScope><biblScope unit="issue">8</biblScope><biblScope unit="page" from="1310">1310</biblScope><biblScope unit="page" to="1315">1315</biblScope></imprint><idno type="ISSN">0036-0236</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0036-0236</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.</div></front></TEI><istex><corpusName>springer-journals</corpusName><author><json:item><name>A. S. Antsyshkina</name><affiliations><json:string>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</json:string><json:string>E-mail: sadgg@igic.ras.ru</json:string></affiliations></json:item><json:item><name>G. G. Sadikov</name><affiliations><json:string>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</json:string></affiliations></json:item><json:item><name>T. V. Koksharova</name><affiliations><json:string>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</json:string></affiliations></json:item><json:item><name>I. S. Gritsenko</name><affiliations><json:string>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</json:string></affiliations></json:item><json:item><name>V. S. Sergienko</name><affiliations><json:string>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</json:string></affiliations></json:item></author><articleId><json:string>9101</json:string><json:string>S003602360908021X</json:string></articleId><arkIstex>ark:/67375/VQC-N2SN5R8W-R</arkIstex><language><json:string>eng</json:string></language><originalGenre><json:string>OriginalPaper</json:string></originalGenre><abstract>Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.</abstract><qualityIndicators><score>5.713</score><pdfWordCount>2297</pdfWordCount><pdfCharCount>16521</pdfCharCount><pdfVersion>1.3</pdfVersion><pdfPageCount>6</pdfPageCount><pdfPageSize>612 x 792 pts (letter)</pdfPageSize><refBibsNative>false</refBibsNative><abstractWordCount>118</abstractWordCount><abstractCharCount>801</abstractCharCount><keywordCount>0</keywordCount></qualityIndicators><title>Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title><genre><json:string>research-article</json:string></genre><host><title>Russian Journal of Inorganic Chemistry</title><language><json:string>unknown</json:string></language><publicationDate>2009</publicationDate><copyrightDate>2009</copyrightDate><issn><json:string>0036-0236</json:string></issn><eissn><json:string>1531-8613</json:string></eissn><journalId><json:string>11502</json:string></journalId><volume>54</volume><issue>8</issue><pages><first>1310</first><last>1315</last></pages><genre><json:string>journal</json:string></genre><subject><json:item><value>Inorganic Chemistry</value></json:item></subject></host><ark><json:string>ark:/67375/VQC-N2SN5R8W-R</json:string></ark><publicationDate>2009</publicationDate><copyrightDate>2009</copyrightDate><doi><json:string>10.1134/S003602360908021X</json:string></doi><id>0C6DD162FAA3DD8229C38F6B2E5D125D48DCE1A0</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-N2SN5R8W-R/fulltext.pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-N2SN5R8W-R/bundle.zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/ark:/67375/VQC-N2SN5R8W-R/fulltext.tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="en">Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher scheme="https://scientific-publisher.data.istex.fr">SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><availability><licence><p>Pleiades Publishing, Ltd., 2009</p></licence><p scheme="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</p></availability><date>2008-04-03</date></publicationStmt><notesStmt><note type="research-article" scheme="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</note><note type="journal" scheme="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</note><note>Physical Methods of Investigation</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="en">Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title><author xml:id="author-0000" corresp="yes"><persName><forename type="first">A.</forename><surname>Antsyshkina</surname></persName><email>sadgg@igic.ras.ru</email><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</affiliation></author><author xml:id="author-0001"><persName><forename type="first">G.</forename><surname>Sadikov</surname></persName><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</affiliation></author><author xml:id="author-0002"><persName><forename type="first">T.</forename><surname>Koksharova</surname></persName><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation></author><author xml:id="author-0003"><persName><forename type="first">I.</forename><surname>Gritsenko</surname></persName><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation></author><author xml:id="author-0004"><persName><forename type="first">V.</forename><surname>Sergienko</surname></persName><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</affiliation></author><idno type="istex">0C6DD162FAA3DD8229C38F6B2E5D125D48DCE1A0</idno><idno type="ark">ark:/67375/VQC-N2SN5R8W-R</idno><idno type="DOI">10.1134/S003602360908021X</idno><idno type="article-id">9101</idno><idno type="article-id">S003602360908021X</idno></analytic><monogr><title level="j">Russian Journal of Inorganic Chemistry</title><title level="j" type="abbrev">Russ. J. Inorg. Chem.</title><idno type="pISSN">0036-0236</idno><idno type="eISSN">1531-8613</idno><idno type="journal-ID">true</idno><idno type="issue-article-count">26</idno><idno type="volume-issue-count">14</idno><imprint><publisher>SP MAIK Nauka/Interperiodica</publisher><pubPlace>Dordrecht</pubPlace><date type="published" when="2009-08-01"></date><biblScope unit="volume">54</biblScope><biblScope unit="issue">8</biblScope><biblScope unit="page" from="1310">1310</biblScope><biblScope unit="page" to="1315">1315</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>2008-04-03</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.</p></abstract><textClass><keywords scheme="Journal Subject"><list><head>Chemistry</head><item><term>Inorganic Chemistry</term></item></list></keywords></textClass></profileDesc><revisionDesc><change when="2008-04-03">Created</change><change when="2009-08-01">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-N2SN5R8W-R/fulltext.txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="corpus springer-journals not found" wicri:toSee="no header"><istex:xmlDeclaration>version="1.0" encoding="UTF-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//Springer-Verlag//DTD A++ V2.4//EN" URI="http://devel.springer.de/A++/V2.4/DTD/A++V2.4.dtd" name="istex:docType"></istex:docType><istex:document><Publisher><PublisherInfo><PublisherName>SP MAIK Nauka/Interperiodica</PublisherName><PublisherLocation>Dordrecht</PublisherLocation></PublisherInfo><Journal OutputMedium="All"><JournalInfo JournalProductType="ArchiveJournal" NumberingStyle="Unnumbered"><JournalID>11502</JournalID><JournalPrintISSN>0036-0236</JournalPrintISSN><JournalElectronicISSN>1531-8613</JournalElectronicISSN><JournalTitle>Russian Journal of Inorganic Chemistry</JournalTitle><JournalAbbreviatedTitle>Russ. 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Chem.</JournalAbbreviatedTitle><JournalSubjectGroup><JournalSubject Type="Primary">Chemistry</JournalSubject><JournalSubject Type="Secondary">Inorganic Chemistry </JournalSubject></JournalSubjectGroup></JournalInfo><Volume OutputMedium="All"><VolumeInfo TocLevels="0" VolumeType="Regular"><VolumeIDStart>54</VolumeIDStart><VolumeIDEnd>54</VolumeIDEnd><VolumeIssueCount>14</VolumeIssueCount></VolumeInfo><Issue IssueType="Regular" OutputMedium="All"><IssueInfo IssueType="Regular" TocLevels="0"><IssueIDStart>8</IssueIDStart><IssueIDEnd>8</IssueIDEnd><IssueArticleCount>26</IssueArticleCount><IssueHistory><OnlineDate><Year>2009</Year><Month>8</Month><Day>11</Day></OnlineDate><CoverDate><Year>2009</Year><Month>8</Month></CoverDate><PricelistYear>2009</PricelistYear></IssueHistory><IssueCopyright><CopyrightHolderName>Pleiades Publishing, Ltd.</CopyrightHolderName><CopyrightYear>2009</CopyrightYear></IssueCopyright></IssueInfo><Article ID="S003602360908021X" OutputMedium="All"><ArticleInfo ArticleType="OriginalPaper" ContainsESM="No" Language="En" NumberingStyle="Unnumbered" TocLevels="0"><ArticleID>9101</ArticleID><ArticleDOI>10.1134/S003602360908021X</ArticleDOI><ArticleSequenceNumber>21</ArticleSequenceNumber><ArticleTitle Language="En">Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</ArticleTitle><ArticleCategory>Physical Methods of Investigation</ArticleCategory><ArticleFirstPage>1310</ArticleFirstPage><ArticleLastPage>1315</ArticleLastPage><ArticleHistory><RegistrationDate><Year>2009</Year><Month>8</Month><Day>7</Day></RegistrationDate><Received><Year>2008</Year><Month>4</Month><Day>3</Day></Received><OnlineDate><Year>2009</Year><Month>8</Month><Day>11</Day></OnlineDate></ArticleHistory><ArticleCopyright><CopyrightHolderName>Pleiades Publishing, Ltd.</CopyrightHolderName><CopyrightYear>2009</CopyrightYear></ArticleCopyright><ArticleGrants Type="Regular"><MetadataGrant Grant="OpenAccess"></MetadataGrant><AbstractGrant Grant="OpenAccess"></AbstractGrant><BodyPDFGrant Grant="Restricted"></BodyPDFGrant><BodyHTMLGrant Grant="Restricted"></BodyHTMLGrant><BibliographyGrant Grant="Restricted"></BibliographyGrant><ESMGrant Grant="Restricted"></ESMGrant></ArticleGrants></ArticleInfo><ArticleHeader><AuthorGroup><Author AffiliationIDS="Aff1" CorrespondingAffiliationID="Aff1"><AuthorName DisplayOrder="Western"><GivenName>A.</GivenName><GivenName>S.</GivenName><FamilyName>Antsyshkina</FamilyName></AuthorName><Contact><Email>sadgg@igic.ras.ru</Email></Contact></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>G.</GivenName><GivenName>G.</GivenName><FamilyName>Sadikov</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff2"><AuthorName DisplayOrder="Western"><GivenName>T.</GivenName><GivenName>V.</GivenName><FamilyName>Koksharova</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff2"><AuthorName DisplayOrder="Western"><GivenName>I.</GivenName><GivenName>S.</GivenName><FamilyName>Gritsenko</FamilyName></AuthorName></Author><Author AffiliationIDS="Aff1"><AuthorName DisplayOrder="Western"><GivenName>V.</GivenName><GivenName>S.</GivenName><FamilyName>Sergienko</FamilyName></AuthorName></Author><Affiliation ID="Aff1"><OrgDivision>Kurnakov Institute of General and Inorganic Chemistry</OrgDivision><OrgName>Russian Academy of Sciences</OrgName><OrgAddress><Street>Leninskii pr. 31</Street><City>Moscow</City><Postcode>119991</Postcode><Country Code="RU">Russia</Country></OrgAddress></Affiliation><Affiliation ID="Aff2"><OrgName>Odessa National University</OrgName><OrgAddress><Street>Dvoryanskaya ul. 2</Street><City>Odessa</City><Postcode>65026</Postcode><Country Code="UA">Ukraine</Country></OrgAddress></Affiliation></AuthorGroup><Abstract ID="Abs1" Language="En"><Heading>Abstract</Heading><Para>The coordination compound of cobalt(II) with nicotinamide [CoL<Subscript>2</Subscript>(H<Subscript>2</Subscript>O)<Subscript>4</Subscript>][C<Subscript>6</Subscript>H<Subscript>4</Subscript>(COO)<Subscript>2</Subscript>] · 2H<Subscript>2</Subscript>O (<Emphasis Type="Bold">I</Emphasis>) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex <Emphasis Type="Bold">I</Emphasis> was determined. Crystals are monoclinic: <Emphasis Type="Italic">a</Emphasis> = 15.630(2) Å, <Emphasis Type="Italic">b</Emphasis> = 7.550(2) Å, <Emphasis Type="Italic">c</Emphasis> = 21.035(4) Å, β = 100.90(5)°, <Emphasis Type="Italic">V</Emphasis> = 2437.4(4) Å<Superscript>3</Superscript>, <Emphasis Type="Italic">Z</Emphasis> = 4, space group <Emphasis Type="Italic">C</Emphasis>2/<Emphasis Type="Italic">c</Emphasis>. The structural units of complex <Emphasis Type="Bold">I</Emphasis> are centrosymmetrical cations [CoL<Subscript>2</Subscript>(H<Subscript>2</Subscript>O)<Subscript>4</Subscript>]<Superscript>2+</Superscript>, anions [C<Subscript>6</Subscript>H<Subscript>4</Subscript>(COO)<Subscript>2</Subscript>]<Superscript>2−</Superscript> (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H<Subscript>2</Subscript>O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.</Para></Abstract><ArticleNote Type="Misc"><SimplePara>Original Russian Text © A.S. Antsyshkina, G.G. Sadikov, T.V. Koksharova, I.S. Gritsenko, V.S. Sergienko, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 8, pp. 1379–1384.</SimplePara></ArticleNote></ArticleHeader><NoBody></NoBody></Article></Issue></Volume></Journal></Publisher></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Synthesis, crystal and molecular structure of tetraaquabis(nicotinamide)cobalt(II) phthalate dihydrate</title></titleInfo><name type="personal" displayLabel="corresp"><namePart type="given">A.</namePart><namePart type="given">S.</namePart><namePart type="family">Antsyshkina</namePart><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</affiliation><affiliation>E-mail: sadgg@igic.ras.ru</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">G.</namePart><namePart type="given">G.</namePart><namePart type="family">Sadikov</namePart><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">T.</namePart><namePart type="given">V.</namePart><namePart type="family">Koksharova</namePart><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">I.</namePart><namePart type="given">S.</namePart><namePart type="family">Gritsenko</namePart><affiliation>Odessa National University, Dvoryanskaya ul. 2, 65026, Odessa, Ukraine</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">V.</namePart><namePart type="given">S.</namePart><namePart type="family">Sergienko</namePart><affiliation>Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="OriginalPaper" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>SP MAIK Nauka/Interperiodica</publisher><place><placeTerm type="text">Dordrecht</placeTerm></place><dateCreated encoding="w3cdtf">2008-04-03</dateCreated><dateIssued encoding="w3cdtf">2009-08-01</dateIssued><copyrightDate encoding="w3cdtf">2009</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><abstract lang="en">Abstract: The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry. The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) Å, b = 7.550(2) Å, c = 21.035(4) Å, β = 100.90(5)°, V = 2437.4(4) Å3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.</abstract><note>Physical Methods of Investigation</note><relatedItem type="host"><titleInfo><title>Russian Journal of Inorganic Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>Russ. J. Inorg. Chem.</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>Springer</publisher><dateIssued encoding="w3cdtf">2009-08-11</dateIssued><copyrightDate encoding="w3cdtf">2009</copyrightDate></originInfo><subject><genre>Chemistry</genre><topic>Inorganic Chemistry</topic></subject><identifier type="ISSN">0036-0236</identifier><identifier type="eISSN">1531-8613</identifier><identifier type="JournalID">11502</identifier><identifier type="IssueArticleCount">26</identifier><identifier type="VolumeIssueCount">14</identifier><part><date>2009</date><detail type="volume"><number>54</number><caption>vol.</caption></detail><detail type="issue"><number>8</number><caption>no.</caption></detail><extent unit="pages"><start>1310</start><end>1315</end></extent></part><recordInfo><recordOrigin>Pleiades Publishing, Ltd., 2009</recordOrigin></recordInfo></relatedItem><identifier type="istex">0C6DD162FAA3DD8229C38F6B2E5D125D48DCE1A0</identifier><identifier type="ark">ark:/67375/VQC-N2SN5R8W-R</identifier><identifier type="DOI">10.1134/S003602360908021X</identifier><identifier type="ArticleID">9101</identifier><identifier type="ArticleID">S003602360908021X</identifier><accessCondition type="use and reproduction" contentType="copyright">Pleiades Publishing, Ltd., 2009</accessCondition><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-3XSW68JL-F">springer</recordContentSource><recordOrigin>Pleiades Publishing, Ltd., 2009</recordOrigin></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/ark:/67375/VQC-N2SN5R8W-R/record.json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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