Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3
Identifieur interne : 000046 ( Istex/Corpus ); précédent : 000045; suivant : 000047Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3
Auteurs : A. Kabadou ; R. Ben Hassen ; A. Ben Salah ; T. JouiniSource :
- physica status solidi (b) [ 0370-1972 ] ; 1998-08.
English descriptors
- Teeft :
- Activation energies delt, Chlorine atoms, Complex impedance method, Crystal structure, Cshgcl3, Dielectric, Dielectric measurements, Electrical properties, Equivalent coordination bonds, Frequency range, Hassen, Hgcl2, Hgcl2 libration, High temperatures, Hydrogen atoms, Impedance, Inverse temperature, Jouini, Kabadou, Lattice mode translation, Phase transition, Phase transitions, Raman, Raman spectra, Room temperature, Room temperature phase, Salah, Same structure, Slow increase, Space group, Temperature dependence, Temperature phase, Title compound crystallises, Translational mode.
Abstract
The title compound crystallises in the space group P32 and has the unit cell dimensions a = 13.295(11) Å, c = 9.419(8) Å, V = 1441.82(2), Z = 9, Dexp = 4.17, Dcalc = 4.153. The structure at room temperature is considered as distorted perovskite tentatively with R = 0.057 and WR2= 0.153 for 700 observed reflections. The dielectric permittivity measured in the frequency and temperatures ranges 103 to 106 Hz and 307 to 613 K, respectively, reveals a transition at T = 449 K. Transport properties in this material appear to be due to the high mobility of NH4+ in the tunnels.
Url:
DOI: 10.1002/(SICI)1521-3951(199808)208:2<387::AID-PSSB387>3.0.CO;2-Y
Links to Exploration step
ISTEX:BD08F83467736F2047C06253472C1E20575AE755Le document en format XML
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The dielectric permittivity measured in the frequency and temperatures ranges 10<hi rend="superscript">3</hi> to 10<hi rend="superscript">6</hi> Hz and 307 to 613 K, respectively, reveals a transition at <hi rend="italic">T</hi> = 449 K. 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Rep. of Germany</copyright><eventGroup><event type="manuscriptReceived" date="1998-02-20"></event><event type="manuscriptRevised" date="1998-04-28"></event><event type="firstOnline" date="1999-01-29"></event><event type="publishedOnlineFinalForm" date="1999-01-29"></event><event type="xmlConverted" agent="Converter:JWSART34_TO_WML3G version:2.3.2 mode:FullText source:HeaderRef result:HeaderRef" date="2010-03-04"></event><event type="xmlConverted" agent="Converter:WILEY_ML3G_TO_WILEY_ML3GV2 version:3.8.8" date="2014-02-07"></event><event type="xmlConverted" agent="Converter:WML3G_To_WML3G version:4.1.7 mode:FullText,remove_FC" date="2014-11-03"></event></eventGroup><numberingGroup><numbering type="pageFirst">387</numbering><numbering type="pageLast">395</numbering></numberingGroup><linkGroup><link type="toTypesetVersion" href="file:PSSB.PSSB387.pdf"></link></linkGroup></publicationMeta><contentMeta><countGroup><count type="figureTotal" number="6"></count><count type="tableTotal" number="4"></count><count type="referenceTotal" number="13"></count></countGroup><titleGroup><title type="main" xml:lang="en">Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs<sub>0.7</sub>(NH<sub>4</sub>)<sub>0.3</sub>HgCl<i>3</i></title><title type="short" xml:lang="en">Crystal Structure and Dielectric Measurements of Cs<sub>0.7</sub>(NH<sub>4</sub>)<sub>0.3</sub>HgCl<i>3</i></title></titleGroup><creators><creator xml:id="au1" creatorRole="author" affiliationRef="#a1"><personName><givenNames>A.</givenNames><familyName>Kabadou</familyName></personName></creator><creator xml:id="au2" creatorRole="author" affiliationRef="#a1"><personName><givenNames>R.</givenNames><familyName>Ben Hassen</familyName></personName></creator><creator xml:id="au3" creatorRole="author" affiliationRef="#a1"><personName><givenNames>A.</givenNames><familyName>Ben Salah</familyName></personName></creator><creator xml:id="au4" creatorRole="author" affiliationRef="#a2"><personName><givenNames>T.</givenNames><familyName>Jouini</familyName></personName></creator></creators><affiliationGroup><affiliation xml:id="a1" countryCode="TN" type="organization"><unparsedAffiliation>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038, Tunisia</unparsedAffiliation></affiliation><affiliation xml:id="a2" countryCode="TN" type="organization"><unparsedAffiliation>Laboratoire de Cristallochimie, Faculté des Sciences, Tunis‐1060 le Belvédère, Tunisia</unparsedAffiliation></affiliation></affiliationGroup><abstractGroup><abstract type="main" xml:lang="en"><title type="main">Abstract</title><p>The title compound crystallises in the space group P3<sub>2</sub> and has the unit cell dimensions <i>a</i> = 13.295(11) Å, <i>c</i> = 9.419(8) Å, <i>V</i> = 1441.82(2), <i>Z</i> = 9, <i>D</i><sub>exp</sub> = 4.17, <i>D</i><sub>calc</sub> = 4.153. The structure at room temperature is considered as distorted perovskite tentatively with <i>R</i> = 0.057 and W<i>R</i><sub>2</sub>= 0.153 for 700 observed reflections. The dielectric permittivity measured in the frequency and temperatures ranges 10<sup>3</sup> to 10<sup>6</sup> Hz and 307 to 613 K, respectively, reveals a transition at <i>T</i> = 449 K. Transport properties in this material appear to be due to the high mobility of NH<sub>4</sub><sup>+</sup> in the tunnels.</p></abstract></abstractGroup></contentMeta></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3</title></titleInfo><titleInfo type="abbreviated" lang="en"><title>Crystal Structure and Dielectric Measurements of Cs0.7(NH4)0.3HgCl3</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Crystal Structure and Dielectric Measurements of Mixed Caesium‐Ammonium Mercury Chloride: Cs0.7(NH4)0.3HgCl3</title></titleInfo><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Kabadou</namePart><affiliation>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">R.</namePart><namePart type="family">Ben Hassen</namePart><affiliation>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">A.</namePart><namePart type="family">Ben Salah</namePart><affiliation>Laboratoire de L'Etat Solide, Faculté des Sciences, Sfax‐3038, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">T.</namePart><namePart type="family">Jouini</namePart><affiliation>Laboratoire de Cristallochimie, Faculté des Sciences, Tunis‐1060 le Belvédère, Tunisia</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="article" displayLabel="article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-6N5SZHKN-D">article</genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Berlin</placeTerm></place><dateIssued encoding="w3cdtf">1998-08</dateIssued><dateCaptured encoding="w3cdtf">1998-02-20</dateCaptured><copyrightDate encoding="w3cdtf">1998</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><extent unit="figures">6</extent><extent unit="tables">4</extent><extent unit="references">13</extent></physicalDescription><abstract lang="en">The title compound crystallises in the space group P32 and has the unit cell dimensions a = 13.295(11) Å, c = 9.419(8) Å, V = 1441.82(2), Z = 9, Dexp = 4.17, Dcalc = 4.153. The structure at room temperature is considered as distorted perovskite tentatively with R = 0.057 and WR2= 0.153 for 700 observed reflections. The dielectric permittivity measured in the frequency and temperatures ranges 103 to 106 Hz and 307 to 613 K, respectively, reveals a transition at T = 449 K. Transport properties in this material appear to be due to the high mobility of NH4+ in the tunnels.</abstract><relatedItem type="host"><titleInfo><title>physica status solidi (b)</title></titleInfo><titleInfo type="abbreviated"><title>phys. stat. sol. 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