Synthesis and crystal structure of bis (2-phenylethylammonium) dihydrogendimphosphate, [C6H5(CH2)2NH3]2H2P2O7
Identifieur interne : 000274 ( France/Analysis ); précédent : 000273; suivant : 000275Synthesis and crystal structure of bis (2-phenylethylammonium) dihydrogendimphosphate, [C6H5(CH2)2NH3]2H2P2O7
Auteurs : F. Hlel [France] ; L. Smiri [France]Source :
- Solid State Sciences [ 1293-2558 ] ; 1999.
English descriptors
- Teeft :
- Anion, Aqueous solution, Aromatic ring, Bond angles, Cation, Chem, Crystal structure, Diphosphate, Diphosphate groups, Durif, Hlel, Hydrogen bonds, Intensity data collection, Jouini, Main interatomic distances, Organic cations, Phosphoric anions, Polar crystals, Room temperature, Smiri, Solid state chem, Solid state sciences, Space group, Strong hydrogen bonds, Tetrahedron, Title compound, Tome.
Abstract
Abstract: Chemical preparation, crystal structure and infrared absorption spectra are given for a new organic cation dihydrogendiphosphate. The new synthesized compound [C6H5(CH2)2NH3]2H2P2O7; crystallized in the monoclinic system (P21/c space group) with Z = 4 and with the following unit-cell dimensions: a = 19.006(3); b = 10.718(2), c = 10.996(3) Å and β = 98.99(2) °. Its crystal structure was determined and refined down to R = 0,056 by using 3278 independent reflections. As in all atomic arrangements including acidic diphosphate groups; we can observe the formation of an infinite network of anions connected by strong H-bonds.
Url:
DOI: 10.1016/S1293-2558(00)80086-2
Affiliations:
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