Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3
Identifieur interne : 005822 ( Istex/Corpus ); précédent : 005821; suivant : 005823Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3
Auteurs : M. BigorgneSource :
- Spectrochimica Acta Part A: Molecular Spectroscopy [ 0584-8539 ] ; 1975.
Abstract
Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.
Url:
DOI: 10.1016/0584-8539(75)80170-X
Links to Exploration step
ISTEX:B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="fr">Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3</title><author><name sortKey="Bigorgne, M" sort="Bigorgne, M" uniqKey="Bigorgne M" first="M." last="Bigorgne">M. Bigorgne</name><affiliation><mods:affiliation>Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure do Chimie, 11, rue P. et M. Curie, Paris 50 France</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2</idno><date when="1975" year="1975">1975</date><idno type="doi">10.1016/0584-8539(75)80170-X</idno><idno type="url">https://api.istex.fr/document/B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">005822</idno><idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">005822</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="fr">Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3</title><author><name sortKey="Bigorgne, M" sort="Bigorgne, M" uniqKey="Bigorgne M" first="M." last="Bigorgne">M. Bigorgne</name><affiliation><mods:affiliation>Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure do Chimie, 11, rue P. et M. Curie, Paris 50 France</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Spectrochimica Acta Part A: Molecular Spectroscopy</title><title level="j" type="abbrev">SAAOLD</title><idno type="ISSN">0584-8539</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1975">1975</date><biblScope unit="volume">31</biblScope><biblScope unit="issue">9–10</biblScope><biblScope unit="page" from="1151">1151</biblScope><biblScope unit="page" to="1158">1158</biblScope></imprint><idno type="ISSN">0584-8539</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0584-8539</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="fr">fr</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>M. Bigorgne</name><affiliations><json:string>Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure do Chimie, 11, rue P. et M. Curie, Paris 50 France</json:string></affiliations></json:item></author><arkIstex>ark:/67375/6H6-8TKKJKRK-7</arkIstex><language><json:string>fre</json:string></language><originalGenre><json:string>Full-length article</json:string></originalGenre><abstract>Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.</abstract><qualityIndicators><score>5.921</score><pdfWordCount>2625</pdfWordCount><pdfCharCount>22698</pdfCharCount><pdfVersion>1.2</pdfVersion><pdfPageCount>8</pdfPageCount><pdfPageSize>504 x 720 pts</pdfPageSize><refBibsNative>true</refBibsNative><abstractWordCount>108</abstractWordCount><abstractCharCount>679</abstractCharCount><keywordCount>0</keywordCount></qualityIndicators><title>Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3</title><pii><json:string>0584-8539(75)80170-X</json:string></pii><genre><json:string>research-article</json:string></genre><host><title>Spectrochimica Acta Part A: Molecular Spectroscopy</title><language><json:string>unknown</json:string></language><publicationDate>1975</publicationDate><issn><json:string>0584-8539</json:string></issn><pii><json:string>S0584-8539(00)X0068-2</json:string></pii><volume>31</volume><issue>9–10</issue><pages><first>1151</first><last>1158</last></pages><genre><json:string>journal</json:string></genre></host><ark><json:string>ark:/67375/6H6-8TKKJKRK-7</json:string></ark><categories><wos></wos><scienceMetrix></scienceMetrix><scopus><json:string>1 - Physical Sciences</json:string><json:string>2 - Engineering</json:string><json:string>3 - General Engineering</json:string></scopus><inist><json:string>1 - sciences appliquees, technologies et medecines</json:string><json:string>2 - sciences biologiques et medicales</json:string><json:string>3 - sciences biologiques fondamentales et appliquees. psychologie</json:string><json:string>4 - psychologie. psychophysiologie</json:string></inist></categories><publicationDate>1975</publicationDate><copyrightDate>1975</copyrightDate><doi><json:string>10.1016/0584-8539(75)80170-X</json:string></doi><id>B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2</id><score>1</score><fulltext><json:item><extension>pdf</extension><original>true</original><mimetype>application/pdf</mimetype><uri>https://api.istex.fr/document/B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2/fulltext/pdf</uri></json:item><json:item><extension>zip</extension><original>false</original><mimetype>application/zip</mimetype><uri>https://api.istex.fr/document/B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a" type="main" xml:lang="fr">Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>ELSEVIER</p></availability><date>1975</date></publicationStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a" type="main" xml:lang="fr">Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3</title><author xml:id="author-0000"><persName><forename type="first">M.</forename><surname>Bigorgne</surname></persName><affiliation>Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure do Chimie, 11, rue P. et M. Curie, Paris 50 France</affiliation></author><idno type="istex">B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2</idno><idno type="DOI">10.1016/0584-8539(75)80170-X</idno><idno type="PII">0584-8539(75)80170-X</idno></analytic><monogr><title level="j">Spectrochimica Acta Part A: Molecular Spectroscopy</title><title level="j" type="abbrev">SAAOLD</title><idno type="pISSN">0584-8539</idno><idno type="PII">S0584-8539(00)X0068-2</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1975"></date><biblScope unit="volume">31</biblScope><biblScope unit="issue">9–10</biblScope><biblScope unit="page" from="1151">1151</biblScope><biblScope unit="page" to="1158">1158</biblScope></imprint></monogr></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1975</date></creation><langUsage><language ident="fr">fr</language></langUsage><abstract xml:lang="en"><p>Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.</p></abstract></profileDesc><revisionDesc><change when="1975">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><extension>txt</extension><original>false</original><mimetype>text/plain</mimetype><uri>https://api.istex.fr/document/B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla" xml:lang="fr"><item-info><jid>SAAOLD</jid><aid>7580170X</aid><ce:pii>0584-8539(75)80170-X</ce:pii><ce:doi>10.1016/0584-8539(75)80170-X</ce:doi><ce:copyright type="unknown" year="1975"></ce:copyright></item-info><head><ce:title>Dérivées des moments dipolaires des liaisons dans Ni(CO)<ce:inf>3</ce:inf>P(CH<ce:inf>3</ce:inf>)<ce:inf>3</ce:inf></ce:title><ce:author-group><ce:author><ce:given-name>M.</ce:given-name><ce:surname>Bigorgne</ce:surname></ce:author><ce:affiliation><ce:textfn>Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure do Chimie, 11, rue P. et M. Curie, Paris 50 France</ce:textfn></ce:affiliation></ce:author-group><ce:date-received day="20" month="9" year="1974"></ce:date-received><ce:abstract xml:lang="en"><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>The i.r. band intensities of Ni(CO)<ce:inf>3</ce:inf>P(CH<ce:inf>3</ce:inf>)<ce:inf>3</ce:inf> have been measured. These values, together with the <ce:italic>L<ce:inf>kp</ce:inf></ce:italic> eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)<ce:inf>4</ce:inf> as well as for free P(CH<ce:inf>3</ce:inf>)<ce:inf>3</ce:inf>. Finally they account for the nearly zero-value of the NiP and NiC (<ce:italic>A</ce:italic><ce:inf>1</ce:inf>) band intensities and for the considerable enhancement of PC (<ce:italic>A</ce:italic><ce:inf>1</ce:inf>) et CPC (<ce:italic>A</ce:italic><ce:inf>1</ce:inf>) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="fr"><title>Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3</title></titleInfo><titleInfo type="alternative" lang="fr" contentType="CDATA"><title>Dérivées des moments dipolaires des liaisons dans Ni(CO)</title></titleInfo><name type="personal"><namePart type="given">M.</namePart><namePart type="family">Bigorgne</namePart><affiliation>Laboratoire de Chimie de Coordination, Ecole Nationale Supérieure do Chimie, 11, rue P. et M. Curie, Paris 50 France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article" authority="ISTEX" authorityURI="https://content-type.data.istex.fr" valueURI="https://content-type.data.istex.fr/ark:/67375/XTP-1JC4F85T-7">research-article</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1975</dateIssued><copyrightDate encoding="w3cdtf">1975</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">fre</languageTerm><languageTerm type="code" authority="rfc3066">fr</languageTerm></language><abstract lang="en">Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.</abstract><relatedItem type="host"><titleInfo><title>Spectrochimica Acta Part A: Molecular Spectroscopy</title></titleInfo><titleInfo type="abbreviated"><title>SAAOLD</title></titleInfo><genre type="journal" authority="ISTEX" authorityURI="https://publication-type.data.istex.fr" valueURI="https://publication-type.data.istex.fr/ark:/67375/JMC-0GLKJH51-B">journal</genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">197509</dateIssued></originInfo><identifier type="ISSN">0584-8539</identifier><identifier type="PII">S0584-8539(00)X0068-2</identifier><part><date>197509</date><detail type="volume"><number>31</number><caption>vol.</caption></detail><detail type="issue"><number>9–10</number><caption>no.</caption></detail><extent unit="issue-pages"><start>1105</start><end>1552</end></extent><extent unit="pages"><start>1151</start><end>1158</end></extent></part></relatedItem><identifier type="istex">B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2</identifier><identifier type="ark">ark:/67375/6H6-8TKKJKRK-7</identifier><identifier type="DOI">10.1016/0584-8539(75)80170-X</identifier><identifier type="PII">0584-8539(75)80170-X</identifier><recordInfo><recordContentSource authority="ISTEX" authorityURI="https://loaded-corpus.data.istex.fr" valueURI="https://loaded-corpus.data.istex.fr/ark:/67375/XBH-HKKZVM7B-M">elsevier</recordContentSource></recordInfo></mods><json:item><extension>json</extension><original>false</original><mimetype>application/json</mimetype><uri>https://api.istex.fr/document/B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2/metadata/json</uri></json:item></metadata><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Santé/explor/EdenteV2/Data/Istex/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 005822 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Istex/Corpus/biblio.hfd -nk 005822 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Santé
|area= EdenteV2
|flux= Istex
|étape= Corpus
|type= RBID
|clé= ISTEX:B09E1BFA992EF5A7E6D427431CF4A97AA986ADC2
|texte= Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3
}}
| This area was generated with Dilib version V0.6.32. |  |