Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3
Identifieur interne : 005822 ( Istex/Corpus ); précédent : 005821; suivant : 005823Dérivées des moments dipolaires des liaisons dans Ni(CO)3P(CH3)3
Auteurs : M. BigorgneSource :
- Spectrochimica Acta Part A: Molecular Spectroscopy [ 0584-8539 ] ; 1975.
Abstract
Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.
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DOI: 10.1016/0584-8539(75)80170-X
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<front><div type="abstract" xml:lang="en">Abstract: The i.r. band intensities of Ni(CO)3P(CH3)3 have been measured. These values, together with the Lkp eigenvectors of the GF matrix, allow the bond moment derivatives of this molecule to be calculated, without ambiguity in the signs. Moreover, the various vibrational couplings allow to determine the signs of the derivatives for Ni(CO)4 as well as for free P(CH3)3. Finally they account for the nearly zero-value of the NiP and NiC (A1) band intensities and for the considerable enhancement of PC (A1) et CPC (A1) band intensities compared to the free ligand. The numerical values of the bond moment derivatives as a function of the electron transfer are discussed.</div>
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