Tannins: Prospectives and Actual Industrial Applications
Identifieur interne : 000226 ( Pmc/Checkpoint ); précédent : 000225; suivant : 000227Tannins: Prospectives and Actual Industrial Applications
Auteurs : Antonio PizziSource :
- Biomolecules [ 2218-273X ] ; 2019.
Abstract
The origin of tannins, their historical evolution, their different types, and their applications are described. Old and established applications are described, as well as the future applications which are being developed at present and that promise to have an industrial impact in the future. The chemistry of some of these applications is discussed where it is essential to understand the tannins and their derivates role. The essential points of each application, their drawbacks, and their chance of industrial application are briefly discussed. The article presents historical applications of tannins, such as leather, or traditional medicine, and more recent applications.
Url:
DOI: 10.3390/biom9080344
PubMed: 31387308
PubMed Central: 6723084
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Tannins: Prospectives and Actual Industrial Applications</title><author><name sortKey="Pizzi, Antonio" sort="Pizzi, Antonio" uniqKey="Pizzi A" first="Antonio" last="Pizzi">Antonio Pizzi</name></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">31387308</idno><idno type="pmc">6723084</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6723084</idno><idno type="RBID">PMC:6723084</idno><idno type="doi">10.3390/biom9080344</idno><date when="2019">2019</date><idno type="wicri:Area/Pmc/Corpus">000A76</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000A76</idno><idno type="wicri:Area/Pmc/Curation">000A76</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000A76</idno><idno type="wicri:Area/Pmc/Checkpoint">000226</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000226</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Tannins: Prospectives and Actual Industrial Applications</title><author><name sortKey="Pizzi, Antonio" sort="Pizzi, Antonio" uniqKey="Pizzi A" first="Antonio" last="Pizzi">Antonio Pizzi</name></author></analytic><series><title level="j">Biomolecules</title><idno type="eISSN">2218-273X</idno><imprint><date when="2019">2019</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>The origin of tannins, their historical evolution, their different types, and their applications are described. Old and established applications are described, as well as the future applications which are being developed at present and that promise to have an industrial impact in the future. The chemistry of some of these applications is discussed where it is essential to understand the tannins and their derivates role. The essential points of each application, their drawbacks, and their chance of industrial application are briefly discussed. The article presents historical applications of tannins, such as leather, or traditional medicine, and more recent applications.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Caller, L" uniqKey="Caller L">L. Caller</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Pizzi, A" uniqKey="Pizzi A">A. Pizzi</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Giovando, S" uniqKey="Giovando S">S. 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<front><journal-meta><journal-id journal-id-type="nlm-ta">Biomolecules</journal-id><journal-id journal-id-type="iso-abbrev">Biomolecules</journal-id><journal-id journal-id-type="publisher-id">biomolecules</journal-id><journal-title-group><journal-title>Biomolecules</journal-title></journal-title-group><issn pub-type="epub">2218-273X</issn><publisher><publisher-name>MDPI</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">31387308</article-id><article-id pub-id-type="pmc">6723084</article-id><article-id pub-id-type="doi">10.3390/biom9080344</article-id><article-id pub-id-type="publisher-id">biomolecules-09-00344</article-id><article-categories><subj-group subj-group-type="heading"><subject>Review</subject></subj-group></article-categories><title-group><article-title>Tannins: Prospectives and Actual Industrial Applications</article-title></title-group><contrib-group><contrib contrib-type="author"><contrib-id contrib-id-type="orcid" authenticated="true">https://orcid.org/0000-0002-9749-7185</contrib-id><name><surname>Pizzi</surname><given-names>Antonio</given-names></name></contrib></contrib-group><aff id="af1-biomolecules-09-00344">LERMAB-ENSTIB, University of Lorraine, 27 rue Philippe Seguin, 88000 Epinal, France;<email>antonio.pizzi@univ-lorraine.fr</email></aff><pub-date pub-type="epub"><day>05</day><month>8</month><year>2019</year></pub-date><pub-date pub-type="collection"><month>8</month><year>2019</year></pub-date><volume>9</volume><issue>8</issue><elocation-id>344</elocation-id><history><date date-type="received"><day>31</day><month>5</month><year>2019</year></date><date date-type="accepted"><day>03</day><month>8</month><year>2019</year></date></history><permissions><copyright-statement>© 2019 by the author.</copyright-statement><copyright-year>2019</copyright-year><license license-type="open-access"><license-p>Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (<ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/4.0/">http://creativecommons.org/licenses/by/4.0/</ext-link>).</license-p></license></permissions><abstract><p>The origin of tannins, their historical evolution, their different types, and their applications are described. Old and established applications are described, as well as the future applications which are being developed at present and that promise to have an industrial impact in the future. The chemistry of some of these applications is discussed where it is essential to understand the tannins and their derivates role. The essential points of each application, their drawbacks, and their chance of industrial application are briefly discussed. The article presents historical applications of tannins, such as leather, or traditional medicine, and more recent applications.</p></abstract><kwd-group><kwd>tannins</kwd><kwd>applications</kwd><kwd>new applications</kwd><kwd>drawbacks</kwd><kwd>advantages</kwd></kwd-group></article-meta></front><floats-group><fig id="biomolecules-09-00344-f001" orientation="portrait" position="float"><label>Figure 1</label><caption><p>Example of the structures of tara tannin [<xref rid="B3-biomolecules-09-00344" ref-type="bibr">3</xref>,<xref rid="B4-biomolecules-09-00344" ref-type="bibr">4</xref>] and caffe-tannins (quinic acid esterified with caffeic acids plus glucose compounds).</p></caption><graphic xlink:href="biomolecules-09-00344-g001"></graphic></fig><fig id="biomolecules-09-00344-f002" orientation="portrait" position="float"><label>Figure 2</label><caption><p>Schematic representation of the repeating unit of the ellagi-tannin of chestnut wood.</p></caption><graphic xlink:href="biomolecules-09-00344-g002"></graphic></fig><fig id="biomolecules-09-00344-f003" orientation="portrait" position="float"><label>Figure 3</label><caption><p>The structure of a flavonoid unit.</p></caption><graphic xlink:href="biomolecules-09-00344-g003"></graphic></fig><fig id="biomolecules-09-00344-f004" orientation="portrait" position="float"><label>Figure 4</label><caption><p>Development of strength visualized through the rapid increase in percentage wood failure of tannin-based fast-setting “honeymoon” separate application cold-setting adhesives for glulam and fingerjoints.</p></caption><graphic xlink:href="biomolecules-09-00344-g004"></graphic></fig><fig id="biomolecules-09-00344-f005" orientation="portrait" position="float"><label>Figure 5</label><caption><p>Examples of mixed species obtained by the reaction of tannin–furfuryl alcohol–glyoxal mixes with polymeric diphenyl methane isocyanate (PMDI).</p></caption><graphic xlink:href="biomolecules-09-00344-g005"></graphic></fig><fig id="biomolecules-09-00344-f006" orientation="portrait" position="float"><label>Figure 6</label><caption><p>Scanning electron microscope image of the structure of a first-generation tannin–furanic foam (<bold>left</bold>) and macro-appearance of the same (<bold>right</bold>).</p></caption><graphic xlink:href="biomolecules-09-00344-g006"></graphic></fig><fig id="biomolecules-09-00344-f007" orientation="portrait" position="float"><label>Figure 7</label><caption><p>Reaction of ethanolamine and formaldehyde with a flavonoid tannin unit to form anpho-tannins used as industrial flocculants.</p></caption><graphic xlink:href="biomolecules-09-00344-g007"></graphic></fig><fig id="biomolecules-09-00344-f008" orientation="portrait" position="float"><label>Figure 8</label><caption><p>Example of orthodiphenol iron complex of a flavonoid tannin.</p></caption><graphic xlink:href="biomolecules-09-00344-g008"></graphic></fig><fig id="biomolecules-09-00344-f009" orientation="portrait" position="float"><label>Figure 9</label><caption><p>Example of cross-linking product of a flavonoid tannin by reaction with triethyl phosphate [<xref rid="B109-biomolecules-09-00344" ref-type="bibr">109</xref>].</p></caption><graphic xlink:href="biomolecules-09-00344-g009"></graphic></fig><fig id="biomolecules-09-00344-f010" orientation="portrait" position="float"><label>Figure 10</label><caption><p>Appearance of cut flowers (Transvaal daisies, <italic>Gerbera</italic> spp) on a tannin–furanic foam (black) compared to a synthetic phenol–formaldehyde/furanic foam (green).</p></caption><graphic xlink:href="biomolecules-09-00344-g010"></graphic></fig><fig id="biomolecules-09-00344-f011" orientation="portrait" position="float"><label>Figure 11</label><caption><p>Non-isocyanate polyurethane-based (NIPU) wood surface coatings based on condensed tannins (<bold>left</bold>) and sessile water drop contact angle on the NIPU coating surface (<bold>right</bold>).</p></caption><graphic xlink:href="biomolecules-09-00344-g011"></graphic></fig><fig id="biomolecules-09-00344-f012" orientation="portrait" position="float"><label>Figure 12</label><caption><p>Examples of compounds presenting urethane linkages formed by the reaction of a pre-aminated flavonoid tannin with a flavonoid tannin pre-reacted with dimethyl carbonate.</p></caption><graphic xlink:href="biomolecules-09-00344-g012"></graphic></fig><fig id="biomolecules-09-00344-f013" orientation="portrait" position="float"><label>Figure 13</label><caption><p>Examples of linear and branched glucose-based non-isocyanate polyurethane oligomers [<xref rid="B121-biomolecules-09-00344" ref-type="bibr">121</xref>].</p></caption><graphic xlink:href="biomolecules-09-00344-g013"></graphic></fig><fig id="biomolecules-09-00344-f014" orientation="portrait" position="float"><label>Figure 14</label><caption><p>Reaction of a flavonoid tannin modified by benzoylation with an isocyanate.</p></caption><graphic xlink:href="biomolecules-09-00344-g014"></graphic></fig><fig id="biomolecules-09-00344-f015" orientation="portrait" position="float"><label>Figure 15</label><caption><p>Example of an angle grinder disk using a tannin–furfuryl alcohol resin as a matrix, and example of cuts in a steel bar with it when using different abrasives.</p></caption><graphic xlink:href="biomolecules-09-00344-g015"></graphic></fig><fig id="biomolecules-09-00344-f016" orientation="portrait" position="float"><label>Figure 16</label><caption><p>Scheme of the sequence of reactions to prepare the epoxy acrylate resin. The reaction proceeds in two steps: first, the epoxidization of the flavonoid tannin, and second, its reaction with acrylic acid catalyzed by hydroquinone [<xref rid="B129-biomolecules-09-00344" ref-type="bibr">129</xref>].</p></caption><graphic xlink:href="biomolecules-09-00344-g016"></graphic></fig><fig id="biomolecules-09-00344-f017" orientation="portrait" position="float"><label>Figure 17</label><caption><p>A nonwoven web of hemp fibers and the composite obtained by impregnation with a tannin–furanic resin.</p></caption><graphic xlink:href="biomolecules-09-00344-g017"></graphic></fig><fig id="biomolecules-09-00344-f018" orientation="portrait" position="float"><label>Figure 18</label><caption><p>Examples of compounds prepared by amination of a flavonoid tannin, and simultaneous reaction of the tannin with furfuryl alcohol.</p></caption><graphic xlink:href="biomolecules-09-00344-g018a"></graphic><graphic xlink:href="biomolecules-09-00344-g018b"></graphic></fig></floats-group></pmc><affiliations><list></list><tree><noCountry><name sortKey="Pizzi, Antonio" sort="Pizzi, Antonio" uniqKey="Pizzi A" first="Antonio" last="Pizzi">Antonio Pizzi</name></noCountry></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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