Bicyclic Host Cavities Derived from Triphenylamine—Guest Selectivity and Redox Properties
Identifieur interne : 001473 ( Main/Exploration ); précédent : 001472; suivant : 001474Bicyclic Host Cavities Derived from Triphenylamine—Guest Selectivity and Redox Properties
Auteurs : Schrage [Allemagne] ; Franke [Allemagne] ; Vögtle [Allemagne] ; Steckhan [Allemagne]Source :
- Angewandte Chemie International Edition in English [ 0570-0833 ] ; 1986-04.
Abstract
Large, substrate‐selective cavities are present in the new, water‐soluble macrobicyclic compounds 1, X, Y N, and 2, X N, Y C‐CH3. Because the triphenylamine nitrogen can be oxidized electrochemically to the radical cation, these host compounds may be electrochemically modified (“switched on and off”). Compounds such as 1 and 2 are also of interest as models for redox enzymes.
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DOI: 10.1002/anie.198603361
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Chem. Int. Ed. Engl.</title><idno type="ISSN">0570-0833</idno><idno type="eISSN">1521-3773</idno><imprint><publisher>Hüthig & Wepf Verlag</publisher><pubPlace>Zug</pubPlace><date type="published" when="1986-04">1986-04</date><biblScope unit="volume">25</biblScope><biblScope unit="issue">4</biblScope><biblScope unit="page" from="336">336</biblScope><biblScope unit="page" to="338">338</biblScope></imprint><idno type="ISSN">0570-0833</idno></series><idno type="istex">17A217B00F5C98F6CAFFD8C590AE99C702FEC197</idno><idno type="DOI">10.1002/anie.198603361</idno><idno type="ArticleID">ANIE198603361</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0570-0833</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Large, substrate‐selective cavities are present in the new, water‐soluble macrobicyclic compounds 1, X, Y N, and 2, X N, Y C‐CH3. 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