Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?
Identifieur interne : 000612 ( Main/Corpus ); précédent : 000611; suivant : 000613Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?
Auteurs : W. Roth ; M. Schmitt ; Ch Jacoby ; D. Spangenberg ; Ch Janzen ; K. KleinermannsSource :
- Chemical Physics [ 0301-0104 ] ; 1997.
Abstract
Phenol(H2O)n clusters have been studied in the electronic ground state by dispersed fluorescence spectroscopy and in the electronically excited state by means of two-color resonant two-photon ionization (R2PI), spectral hole burning and rotationally resolved laser-induced fluorescence. Resonant spectra up to a cluster size of n=12 have been obtained by two-color R2PI under `soft' ionization conditions. The analysis of spectral shifts and of the intermolecular vibrations in both electronic states is used to assign structures for these bi-, tri- and (partially) tetracoordinated hydrogen bonded systems, which may be comparable to H-bond-deficient water structures at the surface of liquid water and ice.
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DOI: 10.1016/S0301-0104(98)00252-3
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Schmitt</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Jacoby, Ch" sort="Jacoby, Ch" uniqKey="Jacoby C" first="Ch" last="Jacoby">Ch Jacoby</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Spangenberg, D" sort="Spangenberg, D" uniqKey="Spangenberg D" first="D" last="Spangenberg">D. Spangenberg</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Janzen, Ch" sort="Janzen, Ch" uniqKey="Janzen C" first="Ch" last="Janzen">Ch Janzen</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Kleinermanns, K" sort="Kleinermanns, K" uniqKey="Kleinermanns K" first="K" last="Kleinermanns">K. Kleinermanns</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:41032207D1E61185EFD713A1308C79320D9C4B67</idno><date when="1998" year="1998">1998</date><idno type="doi">10.1016/S0301-0104(98)00252-3</idno><idno type="url">https://api.istex.fr/document/41032207D1E61185EFD713A1308C79320D9C4B67/fulltext/pdf</idno><idno type="wicri:Area/Main/Corpus">000612</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a">Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?</title><author><name sortKey="Roth, W" sort="Roth, W" uniqKey="Roth W" first="W" last="Roth">W. Roth</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Schmitt, M" sort="Schmitt, M" uniqKey="Schmitt M" first="M" last="Schmitt">M. Schmitt</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Jacoby, Ch" sort="Jacoby, Ch" uniqKey="Jacoby C" first="Ch" last="Jacoby">Ch Jacoby</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Spangenberg, D" sort="Spangenberg, D" uniqKey="Spangenberg D" first="D" last="Spangenberg">D. Spangenberg</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Janzen, Ch" sort="Janzen, Ch" uniqKey="Janzen C" first="Ch" last="Janzen">Ch Janzen</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author><author><name sortKey="Kleinermanns, K" sort="Kleinermanns, K" uniqKey="Kleinermanns K" first="K" last="Kleinermanns">K. Kleinermanns</name><affiliation><mods:affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</mods:affiliation></affiliation></author></analytic><monogr></monogr><series><title level="j">Chemical Physics</title><title level="j" type="abbrev">CHEMPH</title><idno type="ISSN">0301-0104</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997">1997</date><biblScope unit="volume">239</biblScope><biblScope unit="issue">1–3</biblScope><biblScope unit="page" from="1">1</biblScope><biblScope unit="page" to="9">9</biblScope></imprint><idno type="ISSN">0301-0104</idno></series><idno type="istex">41032207D1E61185EFD713A1308C79320D9C4B67</idno><idno type="DOI">10.1016/S0301-0104(98)00252-3</idno><idno type="PII">S0301-0104(98)00252-3</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0301-0104</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Phenol(H2O)n clusters have been studied in the electronic ground state by dispersed fluorescence spectroscopy and in the electronically excited state by means of two-color resonant two-photon ionization (R2PI), spectral hole burning and rotationally resolved laser-induced fluorescence. Resonant spectra up to a cluster size of n=12 have been obtained by two-color R2PI under `soft' ionization conditions. The analysis of spectral shifts and of the intermolecular vibrations in both electronic states is used to assign structures for these bi-, tri- and (partially) tetracoordinated hydrogen bonded systems, which may be comparable to H-bond-deficient water structures at the surface of liquid water and ice.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>W Roth</name><affiliations><json:string>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</json:string></affiliations></json:item><json:item><name>M Schmitt</name><affiliations><json:string>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</json:string></affiliations></json:item><json:item><name>Ch Jacoby</name><affiliations><json:string>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</json:string></affiliations></json:item><json:item><name>D Spangenberg</name><affiliations><json:string>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</json:string></affiliations></json:item><json:item><name>Ch Janzen</name><affiliations><json:string>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</json:string></affiliations></json:item><json:item><name>K Kleinermanns</name><affiliations><json:string>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</json:string></affiliations></json:item></author><language><json:string>eng</json:string></language><abstract>Phenol(H2O)n clusters have been studied in the electronic ground state by dispersed fluorescence spectroscopy and in the electronically excited state by means of two-color resonant two-photon ionization (R2PI), spectral hole burning and rotationally resolved laser-induced fluorescence. Resonant spectra up to a cluster size of n=12 have been obtained by two-color R2PI under `soft' ionization conditions. The analysis of spectral shifts and of the intermolecular vibrations in both electronic states is used to assign structures for these bi-, tri- and (partially) tetracoordinated hydrogen bonded systems, which may be comparable to H-bond-deficient water structures at the surface of liquid water and ice.</abstract><qualityIndicators><score>4.39</score><pdfVersion>1.2</pdfVersion><pdfPageSize>540 x 712 pts</pdfPageSize><refBibsNative>true</refBibsNative><keywordCount>0</keywordCount><abstractCharCount>708</abstractCharCount><pdfWordCount>3190</pdfWordCount><pdfCharCount>18358</pdfCharCount><pdfPageCount>9</pdfPageCount><abstractWordCount>100</abstractWordCount></qualityIndicators><title>Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?</title><pii><json:string>S0301-0104(98)00252-3</json:string></pii><genre><json:string>research-article</json:string></genre><host><volume>239</volume><pii><json:string>S0301-0104(00)X0096-1</json:string></pii><pages><last>9</last><first>1</first></pages><issn><json:string>0301-0104</json:string></issn><issue>1–3</issue><genre></genre><language><json:string>unknown</json:string></language><title>Chemical Physics</title><publicationDate>1998</publicationDate></host><categories><wos><json:string>PHYSICS, ATOMIC, MOLECULAR & CHEMICAL</json:string><json:string>CHEMISTRY, PHYSICAL</json:string></wos></categories><publicationDate>1997</publicationDate><copyrightDate>1998</copyrightDate><doi><json:string>10.1016/S0301-0104(98)00252-3</json:string></doi><id>41032207D1E61185EFD713A1308C79320D9C4B67</id><fulltext><json:item><original>true</original><mimetype>application/pdf</mimetype><extension>pdf</extension><uri>https://api.istex.fr/document/41032207D1E61185EFD713A1308C79320D9C4B67/fulltext/pdf</uri></json:item><json:item><original>false</original><mimetype>application/zip</mimetype><extension>zip</extension><uri>https://api.istex.fr/document/41032207D1E61185EFD713A1308C79320D9C4B67/fulltext/zip</uri></json:item><istex:fulltextTEI uri="https://api.istex.fr/document/41032207D1E61185EFD713A1308C79320D9C4B67/fulltext/tei"><teiHeader><fileDesc><titleStmt><title level="a">Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?</title></titleStmt><publicationStmt><authority>ISTEX</authority><publisher>ELSEVIER</publisher><availability><p>ELSEVIER</p></availability><date>1998</date></publicationStmt><notesStmt><note type="content">Fig. 1: Part of HRLIF of phenol(H2O)1. The upper trace shows a portion of 50 GHz, with the origin at 35996.47 cm−1 (0 at the scale of the figure). The central part of this spectrum is expanded to 14 GHz in the second trace. The last two traces show the simulation for the two torsional components together with the rotational constants used in the fit of the spectrum.</note><note type="content">Fig. 2: The lower trace shows the R2PI spectrum of phenol(H2O)1, the solid line represents the SHB spectrum upon analysis of the (+) component at 126 cm−1, the dashed trace the SHB spectrum upon analysis of the (−) component at 121 cm−1.</note><note type="content">Fig. 3: Hole burning spectra of phenol(H2O)2–5. The arrows indicate the analysis positions and the insets show the calculated minimum energy structures.</note><note type="content">Fig. 4: DF spectra of phenol(H2O)3–5 between the electronic origin and 230 cm−1. Accuracy of the band positions is ±1 cm−1.</note><note type="content">Fig. 5: Two-color R2PI spectra of phenol(H2O)5–8,12. The dashed lines connecting neighbored mass traces show the fragmentation paths. None of the stronger n=8 transitions could be traced back to fragmentation of n≥9 clusters upon ionization with 355 nm. The inset shows two tentative structures of phenol(H2O)8.</note><note type="content">Table 1: Intermolecular vibrational frequencies of the phenol–water cluster in the S1 state</note><note type="content">Table 2: Assigned intermolecular fundamental vibrations of phenol(H2O)2–5</note></notesStmt><sourceDesc><biblStruct type="inbook"><analytic><title level="a">Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?</title><author><persName><forename type="first">W</forename><surname>Roth</surname></persName><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation></author><author><persName><forename type="first">M</forename><surname>Schmitt</surname></persName><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation></author><author><persName><forename type="first">Ch</forename><surname>Jacoby</surname></persName><note type="biography">Present address: Institut für Lasermedizin, Heinrich-Heine-Universität, Düsseldorf.</note><affiliation>Present address: Institut für Lasermedizin, Heinrich-Heine-Universität, Düsseldorf.</affiliation><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation></author><author><persName><forename type="first">D</forename><surname>Spangenberg</surname></persName><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation></author><author><persName><forename type="first">Ch</forename><surname>Janzen</surname></persName><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation></author><author><persName><forename type="first">K</forename><surname>Kleinermanns</surname></persName><note type="correspondence"><p>Corresponding author. Fax: +49-211-81-15195.</p></note><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation></author></analytic><monogr><title level="j">Chemical Physics</title><title level="j" type="abbrev">CHEMPH</title><idno type="pISSN">0301-0104</idno><idno type="PII">S0301-0104(00)X0096-1</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997"></date><biblScope unit="volume">239</biblScope><biblScope unit="issue">1–3</biblScope><biblScope unit="page" from="1">1</biblScope><biblScope unit="page" to="9">9</biblScope></imprint></monogr><idno type="istex">41032207D1E61185EFD713A1308C79320D9C4B67</idno><idno type="DOI">10.1016/S0301-0104(98)00252-3</idno><idno type="PII">S0301-0104(98)00252-3</idno></biblStruct></sourceDesc></fileDesc><profileDesc><creation><date>1998</date></creation><langUsage><language ident="en">en</language></langUsage><abstract xml:lang="en"><p>Phenol(H2O)n clusters have been studied in the electronic ground state by dispersed fluorescence spectroscopy and in the electronically excited state by means of two-color resonant two-photon ionization (R2PI), spectral hole burning and rotationally resolved laser-induced fluorescence. Resonant spectra up to a cluster size of n=12 have been obtained by two-color R2PI under `soft' ionization conditions. The analysis of spectral shifts and of the intermolecular vibrations in both electronic states is used to assign structures for these bi-, tri- and (partially) tetracoordinated hydrogen bonded systems, which may be comparable to H-bond-deficient water structures at the surface of liquid water and ice.</p></abstract></profileDesc><revisionDesc><change when="1997-11-10">Received</change><change when="1997">Published</change></revisionDesc></teiHeader></istex:fulltextTEI><json:item><original>false</original><mimetype>text/plain</mimetype><extension>txt</extension><uri>https://api.istex.fr/document/41032207D1E61185EFD713A1308C79320D9C4B67/fulltext/txt</uri></json:item></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier, elements deleted: ce:floats; body; tail"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 4.5.2//EN//XML" URI="art452.dtd" name="istex:docType"><istex:entity SYSTEM="gr1" NDATA="IMAGE" name="gr1"></istex:entity><istex:entity SYSTEM="gr2" NDATA="IMAGE" name="gr2"></istex:entity><istex:entity SYSTEM="gr3" NDATA="IMAGE" name="gr3"></istex:entity><istex:entity SYSTEM="gr4" NDATA="IMAGE" name="gr4"></istex:entity><istex:entity SYSTEM="gr5" NDATA="IMAGE" name="gr5"></istex:entity></istex:docType><istex:document><converted-article version="4.5.2" docsubtype="fla"><item-info><jid>CHEMPH</jid><aid>3310</aid><ce:pii>S0301-0104(98)00252-3</ce:pii><ce:doi>10.1016/S0301-0104(98)00252-3</ce:doi><ce:copyright year="1998" type="full-transfer">Elsevier Science B.V.</ce:copyright></item-info><head><ce:title>Double resonance spectroscopy of phenol(H<ce:inf>2</ce:inf>O)<ce:inf>1–12</ce:inf>: evidence for ice-like structures in aromate–water clusters?</ce:title><ce:author-group><ce:author><ce:given-name>W</ce:given-name><ce:surname>Roth</ce:surname></ce:author><ce:author><ce:given-name>M</ce:given-name><ce:surname>Schmitt</ce:surname></ce:author><ce:author><ce:given-name>Ch</ce:given-name><ce:surname>Jacoby</ce:surname><ce:cross-ref refid="FN1"><ce:sup>1</ce:sup></ce:cross-ref></ce:author><ce:author><ce:given-name>D</ce:given-name><ce:surname>Spangenberg</ce:surname></ce:author><ce:author><ce:given-name>Ch</ce:given-name><ce:surname>Janzen</ce:surname></ce:author><ce:author><ce:given-name>K</ce:given-name><ce:surname>Kleinermanns</ce:surname><ce:cross-ref refid="CORR1">*</ce:cross-ref></ce:author><ce:affiliation><ce:textfn>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</ce:textfn></ce:affiliation><ce:correspondence id="CORR1"><ce:label>*</ce:label><ce:text>Corresponding author. Fax: +49-211-81-15195.</ce:text></ce:correspondence><ce:footnote id="FN1"><ce:label>1</ce:label><ce:note-para>Present address: Institut für Lasermedizin, Heinrich-Heine-Universität, Düsseldorf.</ce:note-para></ce:footnote></ce:author-group><ce:date-received day="10" month="11" year="1997"></ce:date-received><ce:abstract><ce:section-title>Abstract</ce:section-title><ce:abstract-sec><ce:simple-para>Phenol(H<ce:inf>2</ce:inf>O)<ce:inf><ce:italic>n</ce:italic></ce:inf> clusters have been studied in the electronic ground state by dispersed fluorescence spectroscopy and in the electronically excited state by means of two-color resonant two-photon ionization (R2PI), spectral hole burning and rotationally resolved laser-induced fluorescence. Resonant spectra up to a cluster size of <ce:italic>n</ce:italic>=12 have been obtained by two-color R2PI under `soft' ionization conditions. The analysis of spectral shifts and of the intermolecular vibrations in both electronic states is used to assign structures for these bi-, tri- and (partially) tetracoordinated hydrogen bonded systems, which may be comparable to H-bond-deficient water structures at the surface of liquid water and ice.</ce:simple-para></ce:abstract-sec></ce:abstract></head></converted-article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo><title>Double resonance spectroscopy of phenol(H2O)1–12: evidence for ice-like structures in aromate–water clusters?</title></titleInfo><titleInfo type="alternative" contentType="CDATA"><title>Double resonance spectroscopy of phenol(H</title></titleInfo><name type="personal"><namePart type="given">W</namePart><namePart type="family">Roth</namePart><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">M</namePart><namePart type="family">Schmitt</namePart><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Ch</namePart><namePart type="family">Jacoby</namePart><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation><description>Present address: Institut für Lasermedizin, Heinrich-Heine-Universität, Düsseldorf.</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">D</namePart><namePart type="family">Spangenberg</namePart><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Ch</namePart><namePart type="family">Janzen</namePart><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">K</namePart><namePart type="family">Kleinermanns</namePart><affiliation>Heinrich-Heine-Universität Düsseldorf, Institut für Physikalische Chemie und Elektrochemie I, D-40225 Düsseldorf, Germany</affiliation><description>Corresponding author. Fax: +49-211-81-15195.</description><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1997</dateIssued><dateCaptured encoding="w3cdtf">1997-11-10</dateCaptured><copyrightDate encoding="w3cdtf">1998</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">Phenol(H2O)n clusters have been studied in the electronic ground state by dispersed fluorescence spectroscopy and in the electronically excited state by means of two-color resonant two-photon ionization (R2PI), spectral hole burning and rotationally resolved laser-induced fluorescence. Resonant spectra up to a cluster size of n=12 have been obtained by two-color R2PI under `soft' ionization conditions. The analysis of spectral shifts and of the intermolecular vibrations in both electronic states is used to assign structures for these bi-, tri- and (partially) tetracoordinated hydrogen bonded systems, which may be comparable to H-bond-deficient water structures at the surface of liquid water and ice.</abstract><note type="content">Fig. 1: Part of HRLIF of phenol(H2O)1. The upper trace shows a portion of 50 GHz, with the origin at 35996.47 cm−1 (0 at the scale of the figure). The central part of this spectrum is expanded to 14 GHz in the second trace. The last two traces show the simulation for the two torsional components together with the rotational constants used in the fit of the spectrum.</note><note type="content">Fig. 2: The lower trace shows the R2PI spectrum of phenol(H2O)1, the solid line represents the SHB spectrum upon analysis of the (+) component at 126 cm−1, the dashed trace the SHB spectrum upon analysis of the (−) component at 121 cm−1.</note><note type="content">Fig. 3: Hole burning spectra of phenol(H2O)2–5. The arrows indicate the analysis positions and the insets show the calculated minimum energy structures.</note><note type="content">Fig. 4: DF spectra of phenol(H2O)3–5 between the electronic origin and 230 cm−1. Accuracy of the band positions is ±1 cm−1.</note><note type="content">Fig. 5: Two-color R2PI spectra of phenol(H2O)5–8,12. The dashed lines connecting neighbored mass traces show the fragmentation paths. None of the stronger n=8 transitions could be traced back to fragmentation of n≥9 clusters upon ionization with 355 nm. The inset shows two tentative structures of phenol(H2O)8.</note><note type="content">Table 1: Intermolecular vibrational frequencies of the phenol–water cluster in the S1 state</note><note type="content">Table 2: Assigned intermolecular fundamental vibrations of phenol(H2O)2–5</note><relatedItem type="host"><titleInfo><title>Chemical Physics</title></titleInfo><titleInfo type="abbreviated"><title>CHEMPH</title></titleInfo><genre type="Journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">19981215</dateIssued></originInfo><identifier type="ISSN">0301-0104</identifier><identifier type="PII">S0301-0104(00)X0096-1</identifier><part><date>19981215</date><detail type="volume"><number>239</number><caption>vol.</caption></detail><detail type="issue"><number>1–3</number><caption>no.</caption></detail><extent unit="issue pages"><start>1</start><end>622</end></extent><extent unit="pages"><start>1</start><end>9</end></extent></part></relatedItem><identifier type="istex">41032207D1E61185EFD713A1308C79320D9C4B67</identifier><identifier type="DOI">10.1016/S0301-0104(98)00252-3</identifier><identifier type="PII">S0301-0104(98)00252-3</identifier><accessCondition type="use and reproduction" contentType="">© 1998Elsevier Science B.V.</accessCondition><recordInfo><recordContentSource>ELSEVIER</recordContentSource><recordOrigin>Elsevier Science B.V., ©1998</recordOrigin></recordInfo></mods></metadata><enrichments><istex:catWosTEI uri="https://api.istex.fr/document/41032207D1E61185EFD713A1308C79320D9C4B67/enrichments/catWos"><teiHeader><profileDesc><textClass><classCode scheme="WOS">PHYSICS, ATOMIC, MOLECULAR & CHEMICAL</classCode><classCode scheme="WOS">CHEMISTRY, PHYSICAL</classCode></textClass></profileDesc></teiHeader></istex:catWosTEI></enrichments><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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