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The development of electrical treeing in LDPE and its nanocomposites with spherical silica and fibrous and laminar silicates

Identifieur interne : 001391 ( Main/Exploration ); précédent : 001390; suivant : 001392

The development of electrical treeing in LDPE and its nanocomposites with spherical silica and fibrous and laminar silicates

Auteurs : Pilar Tiemblo [Espagne] ; Mario Hoyos [Espagne] ; Jose Manuel Gmez-Elvira [Espagne] ; Julio Guzmn ; Nuria Garca [Espagne] ; Andrea Dardano [Italie] ; Francesco Guastavino [Italie]

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RBID : ISTEX:10BCE251378EC7420F92D58ACD86D2F8BBB5859E

Abstract

Electrical treeing in LDPE and three LDPE nanocomposites, with spherical silica and fibrous and laminar phyllosilicates, has been studied. Electrical tests were performed at a 50Hz frequency and voltages between 8 and 29kV, and the time to inception of the first electrical partial discharges (TTI) of the electrical trees and the time to breakdown (TBD), related to the electrical stability of the insulator, were determined. Above 15kV all the nanocomposites show longer inception times and shorter tree growth times than LDPE. It is proposed that both observations are caused by the modification of the polymer crystalline morphology induced by the presence of the fillers and by the development of a large number of interfacial structures, both organoinorganic and amorphouscrystalline. Below 15kV the TBD is increased in the nanocomposites with the laminar silicate because of tortuosity and the TTI is increased in the fibrous silicate containing a nanocomposite because of the LDPE crystalline morphology in the presence of the silicate. The nanosilica particles decrease the electrical stability in the whole voltage range by decreasing both TTI and TBD.

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<div type="abstract">Electrical treeing in LDPE and three LDPE nanocomposites, with spherical silica and fibrous and laminar phyllosilicates, has been studied. Electrical tests were performed at a 50Hz frequency and voltages between 8 and 29kV, and the time to inception of the first electrical partial discharges (TTI) of the electrical trees and the time to breakdown (TBD), related to the electrical stability of the insulator, were determined. Above 15kV all the nanocomposites show longer inception times and shorter tree growth times than LDPE. It is proposed that both observations are caused by the modification of the polymer crystalline morphology induced by the presence of the fillers and by the development of a large number of interfacial structures, both organoinorganic and amorphouscrystalline. Below 15kV the TBD is increased in the nanocomposites with the laminar silicate because of tortuosity and the TTI is increased in the fibrous silicate containing a nanocomposite because of the LDPE crystalline morphology in the presence of the silicate. The nanosilica particles decrease the electrical stability in the whole voltage range by decreasing both TTI and TBD.</div>
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