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Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation

Identifieur interne : 000298 ( Istex/Corpus ); précédent : 000297; suivant : 000299

Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation

Auteurs : Sheng H. Lin ; Chi M. Lin ; Horng G. Leu

Source :

RBID : ISTEX:FC671518B665BA4EA5FFC55C2515865D58806FFD

Abstract

The present study is to investigate the treatment of surfactant wastewater by the Fenton process. The surfactants considered here were anionic alkylbenzene sulfonate (ABS) and linear alkylbenzene sulfonate (LAS), both being widely used in the household and industrial detergents. Experiments were conducted to examine the effects of pH, amounts of ferrous sulfate (FeSO4) and hydrogen peroxide (H2O2) and temperature on the surfactant removal. Chemical coagulation was also considered as an addition in improving the turbidity and dissolved Fe removal after the Fenton process. A first-order kinetic model was adopted to represent the Fenton oxidation of surfactant wastewater. The relation between the reaction rate coefficient and the ferrous sulfate and hydrogen peroxide concentrations and operating temperature was experimentally established using the test data.

Url:
DOI: 10.1016/S0043-1354(98)00403-5

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ISTEX:FC671518B665BA4EA5FFC55C2515865D58806FFD

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<abstract lang="en">The present study is to investigate the treatment of surfactant wastewater by the Fenton process. The surfactants considered here were anionic alkylbenzene sulfonate (ABS) and linear alkylbenzene sulfonate (LAS), both being widely used in the household and industrial detergents. Experiments were conducted to examine the effects of pH, amounts of ferrous sulfate (FeSO4) and hydrogen peroxide (H2O2) and temperature on the surfactant removal. Chemical coagulation was also considered as an addition in improving the turbidity and dissolved Fe removal after the Fenton process. A first-order kinetic model was adopted to represent the Fenton oxidation of surfactant wastewater. The relation between the reaction rate coefficient and the ferrous sulfate and hydrogen peroxide concentrations and operating temperature was experimentally established using the test data.</abstract>
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<note type="content">Fig. 2: Changes in the residual H2O2 and surfactant concentrations as a function of time with 60mgl−1 [H2O2]0 and 60mgl−1 [FeSO4]0 at 30°C.</note>
<note type="content">Fig. 3: Effect of [FeSO4]0 on the surfactant removal with 60mgl−1 [H2O2]0 at 30°C without chemical coagulation.</note>
<note type="content">Fig. 4: Effect of [H2O2]0 on the surfactant removal with 90mgl−1 [FeSO4]0 at 30°C without chemical coagulation.</note>
<note type="content">Fig. 5: NTU of treated wastewater vs settling time after Fenton oxidation with 60mgl−1 [H2O2]0 and 90mgl−1 [FeSO4]0 at 30°C without chemical coagulation.</note>
<note type="content">Fig. 6: Effect of [H2O2]0 on the model fit of first-order kinetics with 90mgl−1 [FeSO4]0 without chemical coagulation.</note>
<note type="content">Fig. 7: Effect of [FeSO4]0 on the model fit of first-order kinetics with 60mgl−1 [H2O2]0 without chemical coagulation.</note>
<note type="content">Fig. 8: The rate coefficients of Fenton oxidation without chemical coagulation as a function of [H2O2]0 with 90mgl−1 [FeSO4]0 (a) and [FeSO4]0 with 60mgl−1 [H2O2]0 (b).</note>
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<note type="content">Table 1: The residual Fe concentration in the treated wastewater</note>
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