Fundamental harmonic a.c. polarography with irreversible dimerization following the charge transfer step
Identifieur interne : 001320 ( Istex/Curation ); précédent : 001319; suivant : 001321Fundamental harmonic a.c. polarography with irreversible dimerization following the charge transfer step
Auteurs : John W. Hayes [États-Unis] ; Ivica Rui [États-Unis] ; Donald E. Smith [États-Unis] ; Glenn L. Booman [États-Unis] ; Joseph R. Delmastro [États-Unis]Source :
- Journal of Electroanalytical Chemistry [ 0022-0728 ] ; 1973.
Abstract
A theoretical and experimental study is presented for the small amplitude fundamental harmonic a.c. polarographic response with systems involving dimerization following the charge transfer step. The theoretical derivation invokes the procedure recently presented for the disproportionation case, which combines numerical methods with conventional functional analysis procedures. Computer programs were developed which provide the option of calculating the a.c. polarographic response on the basis of various commonly-used models for the DME, including the expanding sphere model. The electrode reduction of benzaldehyde in alkaline aqueous ethanol is employed as a model system in an experimental evaluation of the theoretical equations. Excellent agreement is obtained between predictions of the theoretical a.c. polarographic rate law and experimental results.
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DOI: 10.1016/S0022-0728(74)80244-5
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John W. Hayes<affiliation><mods:affiliation>⋆On leave from the School of Chemistry, University of Sydney, Sydney, N.S.W., Australia, 1971–72.</mods:affiliation><wicri:noCountry code="subField">1971–72.</wicri:noCountry></affiliation><affiliation><mods:affiliation>⋆⋆On leave from the Center for Marine Research, Ruder Bošković Institute, Zagreb, Yugoslavia, 1972–74.</mods:affiliation><wicri:noCountry code="subField">1972–74.</wicri:noCountry></affiliation><affiliation><mods:affiliation>To whom correspondence should be addressed.</mods:affiliation><wicri:noCountry code="no comma">To whom correspondence should be addressed.</wicri:noCountry></affiliation><affiliation wicri:level="1"><mods:affiliation>Department of Chemistry, Northwestern University, Evanston, Ill. 60201 (U.S.A.)</mods:affiliation><country xml:lang="fr">États-Unis</country><wicri:regionArea>Department of Chemistry, Northwestern University, Evanston</wicri:regionArea></affiliation>Le document en format XML
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The theoretical derivation invokes the procedure recently presented for the disproportionation case, which combines numerical methods with conventional functional analysis procedures. Computer programs were developed which provide the option of calculating the a.c. polarographic response on the basis of various commonly-used models for the DME, including the expanding sphere model. The electrode reduction of benzaldehyde in alkaline aqueous ethanol is employed as a model system in an experimental evaluation of the theoretical equations. Excellent agreement is obtained between predictions of the theoretical a.c. polarographic rate law and experimental results.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
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