Synthesis, Reactivity, X‐ray Crystal Structures and Electrochemical Behaviour of Water‐Soluble [Tris(pyrazolyl)borato]ruthenium(II) Complexes of 1,3,5‐Triaza‐7‐phosphaadamantane (PTA)
Identifieur interne : 001803 ( Istex/Checkpoint ); précédent : 001802; suivant : 001804Synthesis, Reactivity, X‐ray Crystal Structures and Electrochemical Behaviour of Water‐Soluble [Tris(pyrazolyl)borato]ruthenium(II) Complexes of 1,3,5‐Triaza‐7‐phosphaadamantane (PTA)
Auteurs : Sandra Bola O [Espagne] ; Jorge Bravo [Espagne] ; Jesus Castro [Espagne] ; M. Mar Rodríguez Ocha [Espagne] ; M. Fátima C. Guedes Da Silva [Portugal] ; Armando J. L. Pombeiro [Portugal] ; Luca Gonsalvi [Italie] ; Maurizio Peruzzini [Italie]Source :
- European Journal of Inorganic Chemistry [ 1434-1948 ] ; 2007-12.
Descripteurs français
- Wicri :
- topic : électrochimie.
English descriptors
Abstract
A series of chloridoruthenium(II) complexes bearing the tripodal ligand tris(pyrazolyl)borate (Tp), the water‐soluble cage phosphane 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and its N‐boranyl adduct PTA(BH3), together with PPh3, have been synthesised. The corresponding monohydrido complexes have also been obtained by treating the chlorides withNaOMe. The X‐ray crystal structures of [TpRuCl(PTA)(PPh3)] (2) and [TpRuCl(PTA)2] (3) are also described. Cyclic voltammetry (CV) studies in MeCN and dmso generally show reversible RuII/III oxidation waves and the values of E1/2ox reflect the electron‐donating character of the ligands [Tp (each arm) > PTA > PTA(BH3)], whose Lever electrochemical parameter (EL) has been estimated for the first time.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Url:
DOI: 10.1002/ejic.200700672
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The corresponding monohydrido complexes have also been obtained by treating the chlorides withNaOMe. The X‐ray crystal structures of [TpRuCl(PTA)(PPh3)] (2) and [TpRuCl(PTA)2] (3) are also described. Cyclic voltammetry (CV) studies in MeCN and dmso generally show reversible RuII/III oxidation waves and the values of E1/2ox reflect the electron‐donating character of the ligands [Tp (each arm) > PTA > PTA(BH3)], whose Lever electrochemical parameter (EL) has been estimated for the first time.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</div></front></TEI><affiliations><list><country><li>Espagne</li><li>Italie</li><li>Portugal</li></country><region><li>Galice</li></region></list><tree><country name="Espagne"><region name="Galice"><name sortKey="Bola O, Sandra" sort="Bola O, Sandra" uniqKey="Bola O S" first="Sandra" last="Bola O">Sandra Bola O</name></region><name sortKey="Bravo, Jorge" sort="Bravo, Jorge" uniqKey="Bravo J" first="Jorge" last="Bravo">Jorge Bravo</name><name sortKey="Bravo, Jorge" sort="Bravo, Jorge" uniqKey="Bravo J" first="Jorge" last="Bravo">Jorge Bravo</name><name sortKey="Castro, Jesus" sort="Castro, Jesus" uniqKey="Castro J" first="Jesus" last="Castro">Jesus Castro</name><name sortKey="Mar Rodriguez Ocha, M" sort="Mar Rodriguez Ocha, M" uniqKey="Mar Rodriguez Ocha M" first="M." last="Mar Rodríguez Ocha">M. 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