LeHavreV1, PascalFrancis, Curation, bibRecord, 000242

Study of Ni sorption onto Tio mine waste rock surfaces

Identifieur interne : 000242 ( PascalFrancis/Curation ); précédent : 000241; suivant : 000243

Study of Ni sorption onto Tio mine waste rock surfaces

Auteurs : B. Plante [Canada] ; M. Benzaazoua [Canada] ; B. Bussiere [Canada] ; M. C. Biesinger [Canada] ; A. R. Pratt [Canada]

Source :

Applied geochemistry [ 0883-2927 ] ; 2010.

RBID : Pascal:11-0050796

Descripteurs français

Pascal (Inist)
- Sorption, Mine, Elément métallique, Mobilité, Drainage minier, Exhaure mine, Concentration, Pieu, Hematite, Ilmenite, Fer, Titane, Altération, Extraction, Interprétation, Plagioclase, Gangue, Hydroxyde, Québec.
Wicri :
- topic : Fer, Titane, Interprétation.

English descriptors

KwdEn :
- Mine drainage, Quebec, alteration, concentration, extraction, gangue, hematite, hydroxides, ilmenite, interpretation, iron, metals, mine drainage, mines, mobility, piles, plagioclase, sorption, titanium.

Abstract

Sorption phenomena are known to play significant roles in metal mobility in mine drainage waters. The present study focuses on sorption phenomena controlling Ni concentrations in contaminated neutral drainage issued from the waste rock piles of the Tio mine, a hematite-ilmenite deposit near Havre-Saint-Pierre, Québec, Canada exploited by Rio Tinto Iron and Titanium. Batch sorption tests were conducted on waste rock samples of different composition and degree of alteration, as well as on the main mineral phases purified from the waste rocks. Sorbed phases were submitted to sequential extractions, XPS and DRIFT studies for further interpretation of sorption phenomena. The results from the present study confirm that sorption phenomena play a significant role in the Tio mine waste rocks, and that the main sorbent phases are the residual ilmenite ore in waste rocks, as well as plagioclase, the main gangue mineral. Sequential extractions suggest that most sorption sites are associated with reducible fractions, and XPS results indicate that Ni is sorbed as the hydroxide Ni(OH)₂. The results from the present study provide useful information on sorption phenomena involved in the Tio mine waste rocks and enable further interpretation of Ni geochemistry in contaminated neutral drainage.

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A02	`01`			`@0 APPGEY`
A03		`1`		`@0 Appl. geochem.`
A05				`@2 25`
A06				`@2 12`
A08	`01`	`1`	`ENG`	`@1 Study of Ni sorption onto Tio mine waste rock surfaces`
A11	`01`	`1`		`@1 PLANTE (B.)`
A11	`02`	`1`		`@1 BENZAAZOUA (M.)`
A11	`03`	`1`		`@1 BUSSIERE (B.)`
A11	`04`	`1`		`@1 BIESINGER (M. C.)`
A11	`05`	`1`		`@1 PRATT (A. R.)`
A14	`01`			`@1 Université du Québec en Abitibi-Témiscamingue (UQAT), 445 boul. de l'Université, Rouyn-Noranda @2 Québec, J9X 5E4 @3 CAN @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A14	`02`			`@1 Surface Science Western, Room G-1, Western Science Center, University of Western Ontario @2 London, Ontario, N6A 5B7 @3 CAN @Z 4 aut.`
A14	`03`			`@1 Natural Resources Canada, CANMET, 555 Booth Street @2 Ottawa, Ontario, K1A 0G1 @3 CAN @Z 5 aut.`
A20				`@1 1830-1844`
A21				`@1 2010`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 20984 @5 354000194070490050`
A44				`@0 0000 @1 © 2011 INIST-CNRS. All rights reserved.`
A45				`@0 1 p.1/4`
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A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Applied geochemistry`
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C01	`01`		`ENG`	@0 Sorption phenomena are known to play significant roles in metal mobility in mine drainage waters. The present study focuses on sorption phenomena controlling Ni concentrations in contaminated neutral drainage issued from the waste rock piles of the Tio mine, a hematite-ilmenite deposit near Havre-Saint-Pierre, Québec, Canada exploited by Rio Tinto Iron and Titanium. Batch sorption tests were conducted on waste rock samples of different composition and degree of alteration, as well as on the main mineral phases purified from the waste rocks. Sorbed phases were submitted to sequential extractions, XPS and DRIFT studies for further interpretation of sorption phenomena. The results from the present study confirm that sorption phenomena play a significant role in the Tio mine waste rocks, and that the main sorbent phases are the residual ilmenite ore in waste rocks, as well as plagioclase, the main gangue mineral. Sequential extractions suggest that most sorption sites are associated with reducible fractions, and XPS results indicate that Ni is sorbed as the hydroxide Ni(OH)₂. The results from the present study provide useful information on sorption phenomena involved in the Tio mine waste rocks and enable further interpretation of Ni geochemistry in contaminated neutral drainage.
C02	`01`	`2`		`@0 001E01B`
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C02	`03`	`2`		`@0 220B`
C02	`04`	`2`		`@0 226B04`
C03	`01`	`2`	`FRE`	`@0 Sorption @5 01`
C03	`01`	`2`	`ENG`	`@0 sorption @5 01`
C03	`01`	`2`	`SPA`	`@0 Sorción @5 01`
C03	`02`	`2`	`FRE`	`@0 Mine @5 02`
C03	`02`	`2`	`ENG`	`@0 mines @5 02`
C03	`02`	`2`	`SPA`	`@0 Mina @5 02`
C03	`03`	`2`	`FRE`	`@0 Elément métallique @5 03`
C03	`03`	`2`	`ENG`	`@0 metals @5 03`
C03	`03`	`2`	`SPA`	`@0 Elemento metálico @5 03`
C03	`04`	`2`	`FRE`	`@0 Mobilité @5 04`
C03	`04`	`2`	`ENG`	`@0 mobility @5 04`
C03	`04`	`2`	`SPA`	`@0 Movilidad @5 04`
C03	`05`	`2`	`FRE`	`@0 Drainage minier @5 05`
C03	`05`	`2`	`ENG`	`@0 mine drainage @5 05`
C03	`06`	`2`	`FRE`	`@0 Exhaure mine @5 06`
C03	`06`	`2`	`ENG`	`@0 Mine drainage @5 06`
C03	`06`	`2`	`SPA`	`@0 Desague mina @5 06`
C03	`07`	`2`	`FRE`	`@0 Concentration @5 07`
C03	`07`	`2`	`ENG`	`@0 concentration @5 07`
C03	`07`	`2`	`SPA`	`@0 Concentración @5 07`
C03	`08`	`2`	`FRE`	`@0 Pieu @5 08`
C03	`08`	`2`	`ENG`	`@0 piles @5 08`
C03	`08`	`2`	`SPA`	`@0 Estaca @5 08`
C03	`09`	`2`	`FRE`	`@0 Hematite @2 NZ @5 09`
C03	`09`	`2`	`ENG`	`@0 hematite @2 NZ @5 09`
C03	`09`	`2`	`SPA`	`@0 Hematites @2 NZ @5 09`
C03	`10`	`2`	`FRE`	`@0 Ilmenite @2 NZ @5 10`
C03	`10`	`2`	`ENG`	`@0 ilmenite @2 NZ @5 10`
C03	`10`	`2`	`SPA`	`@0 Ilmenita @2 NZ @5 10`
C03	`11`	`2`	`FRE`	`@0 Fer @5 11`
C03	`11`	`2`	`ENG`	`@0 iron @5 11`
C03	`11`	`2`	`SPA`	`@0 Hierro @5 11`
C03	`12`	`2`	`FRE`	`@0 Titane @5 12`
C03	`12`	`2`	`ENG`	`@0 titanium @5 12`
C03	`12`	`2`	`SPA`	`@0 Titanio @5 12`
C03	`13`	`2`	`FRE`	`@0 Altération @5 13`
C03	`13`	`2`	`ENG`	`@0 alteration @5 13`
C03	`13`	`2`	`SPA`	`@0 Alteración @5 13`
C03	`14`	`2`	`FRE`	`@0 Extraction @5 14`
C03	`14`	`2`	`ENG`	`@0 extraction @5 14`
C03	`15`	`2`	`FRE`	`@0 Interprétation @5 15`
C03	`15`	`2`	`ENG`	`@0 interpretation @5 15`
C03	`15`	`2`	`SPA`	`@0 Interpretación @5 15`
C03	`16`	`2`	`FRE`	`@0 Plagioclase @2 NZ @5 16`
C03	`16`	`2`	`ENG`	`@0 plagioclase @2 NZ @5 16`
C03	`16`	`2`	`SPA`	`@0 Plagioclasa @2 NZ @5 16`
C03	`17`	`2`	`FRE`	`@0 Gangue @5 17`
C03	`17`	`2`	`ENG`	`@0 gangue @5 17`
C03	`18`	`2`	`FRE`	`@0 Hydroxyde @2 NZ @5 18`
C03	`18`	`2`	`ENG`	`@0 hydroxides @2 NZ @5 18`
C03	`18`	`2`	`SPA`	`@0 Hidróxido @2 NZ @5 18`
C03	`19`	`2`	`FRE`	`@0 Québec @2 NG @5 61`
C03	`19`	`2`	`ENG`	`@0 Quebec @2 NG @5 61`
C03	`19`	`2`	`SPA`	`@0 Quebec @2 NG @5 61`
C07	`01`	`2`	`FRE`	`@0 Oxyde @2 NZ`
C07	`01`	`2`	`ENG`	`@0 oxides @2 NZ`
C07	`01`	`2`	`SPA`	`@0 Óxido @2 NZ`
C07	`02`	`2`	`FRE`	`@0 Feldspath @2 NZ`
C07	`02`	`2`	`ENG`	`@0 feldspar @2 NZ`
C07	`02`	`2`	`SPA`	`@0 Feldespato @2 NZ`
C07	`03`	`2`	`FRE`	`@0 Tectosilicate @2 NZ`
C07	`03`	`2`	`ENG`	`@0 framework silicates @2 NZ`
C07	`04`	`2`	`FRE`	`@0 Silicate @2 NZ`
C07	`04`	`2`	`ENG`	`@0 silicates @2 NZ`
C07	`04`	`2`	`SPA`	`@0 Silicato @2 NZ`
C07	`05`	`2`	`FRE`	`@0 Canada Est @2 NG`
C07	`05`	`2`	`ENG`	`@0 Eastern Canada @2 NG`
C07	`05`	`2`	`SPA`	`@0 Canadá Este @2 NG`
C07	`06`	`2`	`FRE`	`@0 Canada @2 NG`
C07	`06`	`2`	`ENG`	`@0 Canada @2 NG`
C07	`06`	`2`	`SPA`	`@0 Canada @2 NG`
C07	`07`	`2`	`FRE`	`@0 Amérique du Nord`
C07	`07`	`2`	`ENG`	`@0 North America`
C07	`07`	`2`	`SPA`	`@0 America del norte`
N21				`@1 031`
N44	`01`			`@1 OTO`
N82				`@1 OTO`

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Pascal:11-0050796

Le document en format XML

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<front><div type="abstract" xml:lang="en">Sorption phenomena are known to play significant roles in metal mobility in mine drainage waters. The present study focuses on sorption phenomena controlling Ni concentrations in contaminated neutral drainage issued from the waste rock piles of the Tio mine, a hematite-ilmenite deposit near Havre-Saint-Pierre, Québec, Canada exploited by Rio Tinto Iron and Titanium. Batch sorption tests were conducted on waste rock samples of different composition and degree of alteration, as well as on the main mineral phases purified from the waste rocks. Sorbed phases were submitted to sequential extractions, XPS and DRIFT studies for further interpretation of sorption phenomena. The results from the present study confirm that sorption phenomena play a significant role in the Tio mine waste rocks, and that the main sorbent phases are the residual ilmenite ore in waste rocks, as well as plagioclase, the main gangue mineral. Sequential extractions suggest that most sorption sites are associated with reducible fractions, and XPS results indicate that Ni is sorbed as the hydroxide Ni(OH)<sub>2</sub>
. The results from the present study provide useful information on sorption phenomena involved in the Tio mine waste rocks and enable further interpretation of Ni geochemistry in contaminated neutral drainage.</div>
</front>
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<fA11 i1="01" i2="1"><s1>PLANTE (B.)</s1>
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<fA14 i1="01"><s1>Université du Québec en Abitibi-Témiscamingue (UQAT), 445 boul. de l'Université, Rouyn-Noranda</s1>
<s2>Québec, J9X 5E4</s2>
<s3>CAN</s3>
<sZ>1 aut.</sZ>
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<fA14 i1="02"><s1>Surface Science Western, Room G-1, Western Science Center, University of Western Ontario</s1>
<s2>London, Ontario, N6A 5B7</s2>
<s3>CAN</s3>
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<s2>Ottawa, Ontario, K1A 0G1</s2>
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</fA66>
<fC01 i1="01" l="ENG"><s0>Sorption phenomena are known to play significant roles in metal mobility in mine drainage waters. The present study focuses on sorption phenomena controlling Ni concentrations in contaminated neutral drainage issued from the waste rock piles of the Tio mine, a hematite-ilmenite deposit near Havre-Saint-Pierre, Québec, Canada exploited by Rio Tinto Iron and Titanium. Batch sorption tests were conducted on waste rock samples of different composition and degree of alteration, as well as on the main mineral phases purified from the waste rocks. Sorbed phases were submitted to sequential extractions, XPS and DRIFT studies for further interpretation of sorption phenomena. The results from the present study confirm that sorption phenomena play a significant role in the Tio mine waste rocks, and that the main sorbent phases are the residual ilmenite ore in waste rocks, as well as plagioclase, the main gangue mineral. Sequential extractions suggest that most sorption sites are associated with reducible fractions, and XPS results indicate that Ni is sorbed as the hydroxide Ni(OH)<sub>2</sub>
. The results from the present study provide useful information on sorption phenomena involved in the Tio mine waste rocks and enable further interpretation of Ni geochemistry in contaminated neutral drainage.</s0>
</fC01>
<fC02 i1="01" i2="2"><s0>001E01B</s0>
</fC02>
<fC02 i1="02" i2="2"><s0>001E01O04</s0>
</fC02>
<fC02 i1="03" i2="2"><s0>220B</s0>
</fC02>
<fC02 i1="04" i2="2"><s0>226B04</s0>
</fC02>
<fC03 i1="01" i2="2" l="FRE"><s0>Sorption</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="2" l="ENG"><s0>sorption</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="2" l="SPA"><s0>Sorción</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="2" l="FRE"><s0>Mine</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="2" l="ENG"><s0>mines</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="2" l="SPA"><s0>Mina</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="2" l="FRE"><s0>Elément métallique</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="2" l="ENG"><s0>metals</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="2" l="SPA"><s0>Elemento metálico</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="2" l="FRE"><s0>Mobilité</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="2" l="ENG"><s0>mobility</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="2" l="SPA"><s0>Movilidad</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="2" l="FRE"><s0>Drainage minier</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="2" l="ENG"><s0>mine drainage</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="2" l="FRE"><s0>Exhaure mine</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="2" l="ENG"><s0>Mine drainage</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="2" l="SPA"><s0>Desague mina</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="2" l="FRE"><s0>Concentration</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="2" l="ENG"><s0>concentration</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="2" l="SPA"><s0>Concentración</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="2" l="FRE"><s0>Pieu</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="2" l="ENG"><s0>piles</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="2" l="SPA"><s0>Estaca</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="2" l="FRE"><s0>Hematite</s0>
<s2>NZ</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="2" l="ENG"><s0>hematite</s0>
<s2>NZ</s2>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="2" l="SPA"><s0>Hematites</s0>
<s2>NZ</s2>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="2" l="FRE"><s0>Ilmenite</s0>
<s2>NZ</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="2" l="ENG"><s0>ilmenite</s0>
<s2>NZ</s2>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="2" l="SPA"><s0>Ilmenita</s0>
<s2>NZ</s2>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="2" l="FRE"><s0>Fer</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="2" l="ENG"><s0>iron</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="2" l="SPA"><s0>Hierro</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="2" l="FRE"><s0>Titane</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="2" l="ENG"><s0>titanium</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="2" l="SPA"><s0>Titanio</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="2" l="FRE"><s0>Altération</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="2" l="ENG"><s0>alteration</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="2" l="SPA"><s0>Alteración</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="2" l="FRE"><s0>Extraction</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="2" l="ENG"><s0>extraction</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="2" l="FRE"><s0>Interprétation</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="2" l="ENG"><s0>interpretation</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="2" l="SPA"><s0>Interpretación</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="2" l="FRE"><s0>Plagioclase</s0>
<s2>NZ</s2>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="2" l="ENG"><s0>plagioclase</s0>
<s2>NZ</s2>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="2" l="SPA"><s0>Plagioclasa</s0>
<s2>NZ</s2>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="2" l="FRE"><s0>Gangue</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="2" l="ENG"><s0>gangue</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="2" l="FRE"><s0>Hydroxyde</s0>
<s2>NZ</s2>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="2" l="ENG"><s0>hydroxides</s0>
<s2>NZ</s2>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="2" l="SPA"><s0>Hidróxido</s0>
<s2>NZ</s2>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="2" l="FRE"><s0>Québec</s0>
<s2>NG</s2>
<s5>61</s5>
</fC03>
<fC03 i1="19" i2="2" l="ENG"><s0>Quebec</s0>
<s2>NG</s2>
<s5>61</s5>
</fC03>
<fC03 i1="19" i2="2" l="SPA"><s0>Quebec</s0>
<s2>NG</s2>
<s5>61</s5>
</fC03>
<fC07 i1="01" i2="2" l="FRE"><s0>Oxyde</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="01" i2="2" l="ENG"><s0>oxides</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="01" i2="2" l="SPA"><s0>Óxido</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="02" i2="2" l="FRE"><s0>Feldspath</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="02" i2="2" l="ENG"><s0>feldspar</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="02" i2="2" l="SPA"><s0>Feldespato</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="03" i2="2" l="FRE"><s0>Tectosilicate</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="03" i2="2" l="ENG"><s0>framework silicates</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="04" i2="2" l="FRE"><s0>Silicate</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="04" i2="2" l="ENG"><s0>silicates</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="04" i2="2" l="SPA"><s0>Silicato</s0>
<s2>NZ</s2>
</fC07>
<fC07 i1="05" i2="2" l="FRE"><s0>Canada Est</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="05" i2="2" l="ENG"><s0>Eastern Canada</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="05" i2="2" l="SPA"><s0>Canadá Este</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="06" i2="2" l="FRE"><s0>Canada</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="06" i2="2" l="ENG"><s0>Canada</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="06" i2="2" l="SPA"><s0>Canada</s0>
<s2>NG</s2>
</fC07>
<fC07 i1="07" i2="2" l="FRE"><s0>Amérique du Nord</s0>
</fC07>
<fC07 i1="07" i2="2" l="ENG"><s0>North America</s0>
</fC07>
<fC07 i1="07" i2="2" l="SPA"><s0>America del norte</s0>
</fC07>
<fN21><s1>031</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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Study of Ni sorption onto Tio mine waste rock surfaces

Study of Ni sorption onto Tio mine waste rock surfaces

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