Allosterically Coupled Double Induced Fit for 1+1+1+1 Self‐Assembly of a Calix[6]trisamine, a Calix[6]trisacid, and Their Guests
Identifieur interne : 001158 ( Main/Merge ); précédent : 001157; suivant : 001159Allosterically Coupled Double Induced Fit for 1+1+1+1 Self‐Assembly of a Calix[6]trisamine, a Calix[6]trisacid, and Their Guests
Auteurs : Stéphane Le Gac ; Jérôme Marrot [France] ; Olivia Reinaud [France] ; Ivan Jabin [France]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2006-05-05.
English descriptors
Abstract
Besondere Gäste: Ein kooperativer doppelter Induced‐Fit‐Prozess führt zur 1+1+1+1‐Selbstorganisation quaternärer Komplexe aus zwei komplementären Calix[6]aren‐Wirten und ihren jeweiligen Gästen (siehe Bild). Die Gäste steuern die Selbstorganisation, indem sie die Wirte in ihre spezielle Form bringen. An einer solchen allosterischen Steuerung sind, ähnlich wie beim biologischen Vorgang, mehrere Erkennungsebenen beteiligt.
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DOI: 10.1002/ange.200503906
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<term>Calixarene</term>
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<front><div type="abstract">Besondere Gäste: Ein kooperativer doppelter Induced‐Fit‐Prozess führt zur 1+1+1+1‐Selbstorganisation quaternärer Komplexe aus zwei komplementären Calix[6]aren‐Wirten und ihren jeweiligen Gästen (siehe Bild). Die Gäste steuern die Selbstorganisation, indem sie die Wirte in ihre spezielle Form bringen. An einer solchen allosterischen Steuerung sind, ähnlich wie beim biologischen Vorgang, mehrere Erkennungsebenen beteiligt.</div>
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