Allosterically Coupled Double Induced Fit for 1+1+1+1 Self‐Assembly of a Calix[6]trisamine, a Calix[6]trisacid, and Their Guests
Identifieur interne : 000822 ( Istex/Corpus ); précédent : 000821; suivant : 000823Allosterically Coupled Double Induced Fit for 1+1+1+1 Self‐Assembly of a Calix[6]trisamine, a Calix[6]trisacid, and Their Guests
Auteurs : Stéphane Le Gac ; Jérôme Marrot ; Olivia Reinaud ; Ivan JabinSource :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2006-05-05.
English descriptors
Abstract
Special guests: A cooperative double induced‐fit process leads to the 1+1+1+1 self‐assembly of quaternary complexes comprising two complementary calix[6]arene‐based hosts and their specific guests (see picture). The guests direct self‐assembly by shaping their hosts. Such allosteric control involves multiple recognition levels reminiscent of those in biology.
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DOI: 10.1002/anie.200503906
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ISTEX:DE0C5FD73712839A6810B77280799549E388926DLe document en format XML
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KGaA, Weinheim</p></availability><date>2006</date></publicationStmt><notesStmt><note type="content">*We thank the French Ministry of Research and New Technologies and the CNRS for financial support. 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We also gratefully acknowledge Dr. Gildas Bertho and Prof. Jean‐Pierre Girault (UMR CNRS 8601) for fruitful discussions and help with the NMR studies.</p></note></noteGroup></header></component></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>Allosterically Coupled Double Induced Fit for 1+1+1+1 Self‐Assembly of a Calix[6]trisamine, a Calix[6]trisacid, and Their Guests</title></titleInfo><titleInfo type="alternative" contentType="CDATA" lang="en"><title>Allosterically Coupled Double Induced Fit for 1+1+1+1 Self‐Assembly of a Calix[6]trisamine, a Calix[6]trisacid, and Their Guests</title></titleInfo><name type="personal"><namePart type="given">Stéphane</namePart><namePart type="family">Le Gac</namePart><affiliation>URCOM, Université du Havre, 25 rue Philippe Lebon, BP 540, 76058 Le Havre cedex, France, Fax: (+33) 232‐744‐391</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Jérôme</namePart><namePart type="family">Marrot</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>Institut Lavoisier, UMR CNRS 8637, Université de Versailles St‐Quentin en Yvelines, 45 av. des Etats‐Unis, 78035 Versailles cedex, France</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Olivia</namePart><namePart type="family">Reinaud</namePart><namePart type="termsOfAddress">Prof.</namePart><affiliation>Laboratoire de Chimie et Biochimie Pharmacologique et Toxicologique, UMR CNRS 8601, Université René Descartes, 45 rue des Saints Pères, 75270 Paris cedex 06, France, Fax: (+33) 142‐868‐387</affiliation><affiliation>E-mail: Olivia.Reinaud@univ‐paris5.fr</affiliation><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">Ivan</namePart><namePart type="family">Jabin</namePart><namePart type="termsOfAddress">Dr.</namePart><affiliation>URCOM, Université du Havre, 25 rue Philippe Lebon, BP 540, 76058 Le Havre cedex, France, Fax: (+33) 232‐744‐391</affiliation><affiliation>E-mail: ivan.jabin@univ‐lehavre.fr</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="brief-communication" displayLabel="shortCommunication"></genre><originInfo><publisher>WILEY‐VCH Verlag</publisher><place><placeTerm type="text">Weinheim</placeTerm></place><dateIssued encoding="w3cdtf">2006-05-05</dateIssued><dateCaptured encoding="w3cdtf">2005-11-04</dateCaptured><copyrightDate encoding="w3cdtf">2006</copyrightDate></originInfo><language><languageTerm type="code" authority="rfc3066">en</languageTerm><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType><extent unit="figures">4</extent><extent unit="references">34</extent></physicalDescription><abstract>Special guests: A cooperative double induced‐fit process leads to the 1+1+1+1 self‐assembly of quaternary complexes comprising two complementary calix[6]arene‐based hosts and their specific guests (see picture). The guests direct self‐assembly by shaping their hosts. Such allosteric control involves multiple recognition levels reminiscent of those in biology.</abstract><note type="content">*We thank the French Ministry of Research and New Technologies and the CNRS for financial support. We also gratefully acknowledge Dr. Gildas Bertho and Prof. Jean‐Pierre Girault (UMR CNRS 8601) for fruitful discussions and help with the NMR studies.</note><subject lang="en"><genre>keywords</genre><topic>allosterism</topic><topic>calixarenes</topic><topic>host–guest systems</topic><topic>self‐assembly</topic><topic>supramolecular chemistry</topic></subject><relatedItem type="host"><titleInfo><title>Angewandte Chemie International Edition</title></titleInfo><titleInfo type="abbreviated"><title>Angewandte Chemie International Edition</title></titleInfo><genre type="journal">journal</genre><note type="content"> Supporting information for this article is available on the WWW under http://www.wiley‐vch.de/contents/jc_2002/2006/z503906_s.pdf or from the author.</note><subject><genre>article-category</genre><topic>Communication</topic></subject><identifier type="ISSN">1433-7851</identifier><identifier type="eISSN">1521-3773</identifier><identifier type="DOI">10.1002/(ISSN)1521-3773</identifier><identifier type="PublisherID">ANIE</identifier><part><date>2006</date><detail type="volume"><caption>vol.</caption><number>45</number></detail><detail type="issue"><caption>no.</caption><number>19</number></detail><extent unit="pages"><start>3123</start><end>3126</end><total>4</total></extent></part></relatedItem><identifier type="istex">DE0C5FD73712839A6810B77280799549E388926D</identifier><identifier type="DOI">10.1002/anie.200503906</identifier><identifier type="ArticleID">ANIE200503906</identifier><accessCondition type="use and reproduction" contentType="copyright">Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</accessCondition><recordInfo><recordContentSource>WILEY</recordContentSource><recordOrigin>WILEY‐VCH Verlag</recordOrigin></recordInfo></mods></metadata><enrichments><json:item><type>multicat</type><uri>https://api.istex.fr/document/DE0C5FD73712839A6810B77280799549E388926D/enrichments/multicat</uri></json:item></enrichments><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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